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Volume 101
Main Index

Issue 1


Chemical reactions in monolayer films. Chromatography, a multicompartment trough, and the hydrolysis of surfactant ester derivatives of tris(2,2'-bipyridine)ruthenium(II)2+
Steven J. Valenty
pp 1 - 8; DOI:
10.1021/ja00495a001
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Matrix photoionization and radiolysis of dichloromethane and dibromomethane. Infrared and ultraviolet absorption spectra and photolysis of CH2Cl2+ and CH2Br2+
Lester Andrews, Frank T. Prochaska, and Bruce S. Ault
pp 9 - 15; DOI:
10.1021/ja00495a002
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Stereochemically constrained linear peptides. Conformations of peptides containing .alpha.-aminoisobutyric acid
R. Nagaraj, N. Shamala, and P. Balaram
pp 16 - 20; DOI:
10.1021/ja00495a003
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Optical activity of oriented molecules. 5. .alpha.,.beta.-Unsaturated keto steroids
Hans Georg Kuball, Mahmut Acimis, and Joachim Altschuh
pp 20 - 27; DOI:
10.1021/ja00495a004
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Thermodynamical analysis of rotation of spin probes in a sodium dodecyl sulfate micelle
Hisashi Yoshioka
pp 28 - 32; DOI:
10.1021/ja00495a005
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Deviations from bond additivity in Compton profiles: the relation to strain energy in hydrocarbons
Lawrence C. Snyder and Thomas A. Weber
pp 32 - 36; DOI:
10.1021/ja00495a006
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Reinterpretation of the mechanisms of concerted cycloaddition and cyclodimerization of allenes
Daniel J. Pasto
pp 37 - 46; DOI:
10.1021/ja00495a007
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Theoretical evidence for nonplanar cyclopropylcarbinyl cations. Effect of orbital distortion on endo and exo solvolytic product ratios
Robert D. Bach and Paul E. Blanchette
pp 46 - 50; DOI:
10.1021/ja00495a008
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Equilibrium geometries and relative energies of the lowest singlet and triplet states of o-, m-, and p-benzyne
J. O. Noell and M. D. Newton
pp 51 - 57; DOI:
10.1021/ja00495a009
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Kinetics of the interaction of perhydroxyl and superoxide radicals with hydrogen peroxide. The Haber-Weiss reaction
Judith Weinstein and Benon H. J. Bielski
pp 58 - 62; DOI:
10.1021/ja00495a010
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A coordination chemistry study of a nickel surface. The chemistry of nickel (111) with triply bonded molecules
J. C. Hemminger, E. L. Muetterties, and G. A. Somorjai
pp 62 - 67; DOI:
10.1021/ja00495a011
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Structure of the iron-containing core in ferritin by the extended x-ray absorption fine structure technique
S. M. Heald, E. A. Stern, B. Bunker, E. M. Holt, and S. L. Holt
pp 67 - 73; DOI:
10.1021/ja00495a012
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Enthalpy changes in oxidative addition reactions of rhodium(I) and iridium(I) complexes
N. E. Burke, A. Singhal, M. J. Hintz, J. A. Ley, H. Hui, L. R. Smith, and D. M. Blake
pp 74 - 79; DOI:
10.1021/ja00495a013
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Theory and application of photoelectron spectroscopy. 77. Use of photoelectron spectroscopy in studying rotational isomerism in tetramethyldiphosphine
Armin Schweig, Nikolaus Thon, and Hans Vermeer
pp 80 - 83; DOI:
10.1021/ja00495a014
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Relatively stable silaethylenes. Photolysis of acylpolysilanes
Adrian G. Brook, John W. Harris, John Lennon, and Maher El Sheikh
pp 83 - 95; DOI:
10.1021/ja00495a015
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Hydroboration. 50. Hydroboration of representative alkynes with 9-borabicyclo[3.3.1]nonane - a simple synthesis of versatile vinyl bora and gem-dibora intermediates
Herbert C. Brown, Charles G. Scouten, and Ronald Liotta
pp 96 - 99; DOI:
10.1021/ja00495a016
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Vinyl cations. 30. Preparation and solvolysis of 1-cyclobutenyl nonaflates. Generation of stabilized vinyl cation species
Michael Hanack, Eileen J. Carnahan, Adam Krowczynski, Winfried Schoberth, L. R. Subramanian, and Karina Subramanian
pp 100 - 108; DOI:
10.1021/ja00495a017
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Hydrolysis of diethyl benzoylphosphonate in aqueous and hydrochloric acid solutions. Postulation of a stable pentavalent phosphorus-containing intermediate
K. S. Narayanan and K. D. Berlin
pp 109 - 116; DOI:
10.1021/ja00495a018
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Solid-phase cosolvents. Triphase catalytic hydrolysis of 1-bromoadamantane
Steven L. Regen, Jacques J. Besse, and Jerome McLick
pp 116 - 120; DOI:
10.1021/ja00495a019
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Exciplex photophysics. 6. Quenching of .alpha.-cyanonaphthalene by 1,2-dimethylcyclopentene in slightly polar solvents
Desmond V. O'Connor and William R. Ware
pp 121 - 128; DOI:
10.1021/ja00495a020
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High-pressure study of the effect of viscosity on fluorescence and photoisomerization of trans-stilbene
L. A. Brey, Gary B. Schuster, and H. G. Drickamer
pp 129 - 134; DOI:
10.1021/ja00495a021
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Excited state adduct formation between excited substituted quinolinium cations and specific inorganic anions
S. C. Chao, J. Tretzel, and F. W. Schneider
pp 134 - 139; DOI:
10.1021/ja00495a022
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Proton exchange in the lowest excited singlet state of 2-naphthol-6,8-disulfonate. Demonstration of the establishment of prototropic equilibrium in the excited state
Stephen G. Schulman, Leonard S. Rosenberg, and William R. Vincent
pp 139 - 142; DOI:
10.1021/ja00495a023
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Formation of isomeric benzylidenecyclobutenones and 5-phenylpent-2-en-4-ynals by the gas-phase pyrolysis of .alpha.-phenylfurfuryl acetate
Walter S. Trahanovsky and David Lynn Alexander
pp 142 - 147; DOI:
10.1021/ja00495a024
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Syntheses of trans doubly bridged ethylenes. (.+-.)-C2-bicyclo[10.8.0]eicos-1(12)-ene and (.+-.)-D2-bicyclo[8.8.0]octadec-1(10)-ene
Masao Nakazaki, Koji Yamamoto, and Junichiro Yanagi
pp 147 - 151; DOI:
10.1021/ja00495a025
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Effect of pressure on the [2 + 2 .fwdarw. 4] cycloaddition reaction of tetracyanoethylene to enol ethers
Joern Von Jouanne, Hartwig Kelm, and Rolf Huisgen
pp 151 - 158; DOI:
10.1021/ja00495a026
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Vanadium-catalyzed epoxidation of cyclic allylic alcohols. Stereoselectivity and stereocontrol mechanism
Takashi Itoh, Koichiro Jitsukawa, Kiyotomi Kaneda, and Shiichiro Teranishi
pp 159 - 169; DOI:
10.1021/ja00495a027
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Secondary deuterium isotope effects for certain acyl transfer reactions of phenyl formates
Luciano Do Amaral, Marilene P. Bastos, Herbert G. Bull, Juan J. Oritz, and E. H. Cordes
pp 169 - 173; DOI:
10.1021/ja00495a028
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Interaction of aquated cis-diammineplatinum(II) with homopolynucleotides
William M. Scovell and Ronald S. Reaoch
pp 174 - 180; DOI:
10.1021/ja00495a029
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Conformation of the cyclic pentapeptide Gly-L-Pro-L-Ser-D-Ala-L-Pro in the crystalline state and an example of rotational "isomerism" between analogs
Isabella L. Karle
pp 181 - 184; DOI:
10.1021/ja00495a030
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Solution conformation of cyclo-(Gly-Pro-Ser-D-Ala-Pro). Hydrogen-bonded reverse turns in cyclic pentapeptides
L. G. Pease, C. H. Niu, and G. Zimmermann
pp 184 - 191; DOI:
10.1021/ja00495a031
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Proton, carbon-13, and nitrogen-15 nuclear magnetic resonance and CNDO/2 studies on the tautomerism and conformation of amiloride, a novel acylguanidine
Robert L. Smith, David W. Cochran, Peter Gund, and Edward J. Cragoe
pp 191 - 201; DOI:
10.1021/ja00495a032
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Carbon-13 NMR studies of the Peptide hormones oxytocin, arginine vasopressin, isotocin, mesotocin, glumitocin, aspartocin, related analogs, and diastereoisomers. Use of specifically deuterated hormone derivatives for assignments and effects of structural changes on carbon-13 NMR chemical shifts in peptides
Victor J. Hruby, K. K. Deb, Arno F. Spatola, Donald A. Upson, and Diane Yamamoto
pp 202 - 212; DOI:
10.1021/ja00495a033
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Crystal lattice control of a unimolecular photorearrangement. Divergent behavior of a .beta.,.gamma.-unsaturated ketone in solution and the solid state
Wolfgang K. Appel, Trevor J. Greenhough, John R. Scheffer, and James Trotter
pp 213 - 215; DOI:
10.1021/ja00495a034
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The cobalt way to dl-estrone, a highly regiospecific functionalization of 2,3-bis(trimethylsilyl)estratrien-17-one
Raymond L. Funk and K. Peter C. Vollhardt
pp 215 - 217; DOI:
10.1021/ja00495a035
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Substituent effects in addition of carbanions to arenechromium tricarbonyl complexes: correlation with arene LUMO
M. F. Semmelhack, G. R. Clark, R. Farina, and M. Saeman
pp 217 - 218; DOI:
10.1021/ja00495a036
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Reduction of coordinated carbon monoxide to "zirconoxy" carbenes with permethylzirconocene dihydride
Peter T. Wolczanski, Richard S. Threlkel, and John E. Bercaw
pp 218 - 220; DOI:
10.1021/ja00495a037
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Intramolecular dibromo ketone-iron carbonyl reaction in terpene synthesis
R. Noyori, M. Nishizawa, F. Shimizu, Y. Hayakawa, Keiji Maruoka, Shinsaku Hashimoto, Hisashi Yamamoto, and Hitosi Nozaki
pp 220 - 222; DOI:
10.1021/ja00495a038
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Unexpected reactions of iron dimer (Fe2) and iron monomer (Fe) in low-temperature matrices
Paul H. Barrett, Moshe Pasternak, and Ralph G. Pearson
pp 222 - 223; DOI:
10.1021/ja00495a039
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Structure and electrochemistry of a stable enantiomeric metalloflavin complex
Michael J. Clarke, Michael G. Dowling, Alfred R. Garafalo, and Thomas F. Brennan
pp 223 - 225; DOI:
10.1021/ja00495a040
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Thermochemistry and generation of vinylketene
Johan K. Terlouw, Peter C. Burgers, and John L. Holmes
pp 225 - 226; DOI:
10.1021/ja00495a041
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Stereocontrolled synthesis of the Prelog-Djerassi lactone
James D. White and Yoshiyasu Fukuyama
pp 226 - 228; DOI:
10.1021/ja00495a042
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Dehydrohalogenation by complex base. Preferential loss of "poorer" halogen leaving groups
Jong Gun Lee and Richard A. Bartsch
pp 228 - 229; DOI:
10.1021/ja00495a043
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Relatively low-temperature thermochemical generation of molecular hydrogen from decomposition of water by platinum. Red-light photochemical origin of the chlorophyll a water splitting reaction
L. Galloway, D. R. Fruge, G. M. Haley, A. B. Coddington, and F. K. Fong
pp 229 - 231; DOI:
10.1021/ja00495a044
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Reactions of 1-chloro-2-alkylcyclohexenes with organolithium reagents. The intermediacy of cyclopropenes
Paul G. Gassman, Joseph J. Valcho, and Gary S. Proehl
pp 231 - 233; DOI:
10.1021/ja00495a045
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Interactions of small organic rings with transition metals. Formation of .eta.3-cyclobutenonyl complexes by the ring expansion of 2-cyclopropene-1-carbonyl metal species
Christopher E. Chidsey, William A. Donaldson, Russell P. Hughes, and Paul F. Sherwin
pp 233 - 235; DOI:
10.1021/ja00495a046
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Reaction of nitrosylpentaammineruthenium(II) ion with organic carbonyls containing an .alpha.-methylene group: facile oxidative cleavage of a carbon-carbon bond
Kenneth Schug and Charles P. Guengerich
pp 235 - 236; DOI:
10.1021/ja00495a047
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Luminescent photoelectrochemical cells. Use of tellurium-doped cadmium sulfide photoelectrodes to probe surface recombination during the conversion of optical energy to electricity
Arthur B. Ellis and Bradley R. Karas
pp 236 - 237; DOI:
10.1021/ja00495a048
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Potential proximate carcinogens of 7,12-dimethylbenz[a]anthracene: characterization of two metabolically formed trans-3,4-dihydrodiols
Shen K. Yang, Ming W. Chou, and Peter P. Roller
pp 237 - 239; DOI:
10.1021/ja00495a049
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New model visual pigments. Spectroscopy of poly(ethylene glycol)peptide Schiff bases of retinal
P. K. Das, Ralph S. Becker, Dieter Hannak, and Ernst Bayer
pp 239 - 240; DOI:
10.1021/ja00495a050
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Malyngamide A, a novel chlorinated metabolite of the marine cyanophyte Lyngbya majuscula
John H. Cardellina, Franz Josef Marner, and Richard E. Moore
pp 240 - 242; DOI:
10.1021/ja00495a051
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Preparation of [NP(p-OC6H4Li)2]3 by metal-halogen exchange, and its reactions with electrophiles
T. L. Evans, T. J. Fuller, and H. R. Allcock
pp 242 - 242; DOI:
10.1021/ja00495a052
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Synthesis and electron spin resonance chemistry of nitronyl labels for spin trapping. .alpha.-Phenyl N-[5-(5-methyl-2,2-dialkyl-1,3-dioxanyl)] nitrones and .alpha.-(N-alkylpyridinium) N-(tert-butyl) nitrones
Edward G. Janzen, Robert L. Dudley, and Raghav V. Shetty
pp 243 - 245; DOI:
10.1021/ja00495a053
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Gas-phase organometallic chemistry. Mechanism and energetics of methane formation resulting from protonation of pentacarbonylmethylmanganese
Amy E. Stevens and J. L. Beauchamp
pp 245 - 246; DOI:
10.1021/ja00495a054
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Preparation of .pi.-allyl metal complexes by direct reaction of highly reactive transition metal powders with allylic halides
Reuben D. Rieke, Arunas V. Kavaliunas, Lee D. Rhyne, and David J. J. Fraser
pp 246 - 248; DOI:
10.1021/ja00495a055
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Stereochemistry at the migration terminus in the base-induced rearrangement of .alpha.-haloorganoboranes
M. Mark Midland, Andrew R. Zolopa, and Ronald L. Halterman
pp 248 - 249; DOI:
10.1021/ja00495a056
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A new olefin synthesis: condensation of aldehyde tosylhydrazones with stabilized carbanions
E. Vedejs, J. M. Dolphin, and W. T. Stolle
pp 249 - 251; DOI:
10.1021/ja00495a057
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Efficient guaiazulene and chamazulene syntheses involving [6 + 4] cycloadditions
Debabrata Mukherjee, Lee C. Dunn, and K. N. Houk
pp 251 - 252; DOI:
10.1021/ja00495a058
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An oxygen-18 isotope shift upon carbon-13 NMR spectra and its application to the study of oxygen exchange kinetics
John M. Risley and Robert L. Van Etten
pp 252 - 253; DOI:
10.1021/ja00495a059
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Synthesis of thymosin .alpha.1
Su-Sun Wang, Irina Douvan Kulesha, and Donald P. Winter
pp 253 - 254; DOI:
10.1021/ja00495a060
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Synthesis and chemistry of cis- and trans-2,3-divinylthiirane
Manfred P. Schneider and Margit Schnaithmann
pp 254 - 256; DOI:
10.1021/ja00495a061
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Photolysis of aryldiazo compounds in rigid matrices. Temperature and matrix effects on the selectivities of insertion of arylcarbenes into carbon-hydrogen bonds
Hideo Tomioka
pp 256 - 257; DOI:
10.1021/ja00495a062
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Thionium ions as reactive carbonyl equivalents in cyclization reactions
Barry M. Trost, Manfred Reiffen, and Michael Crimmin
pp 257 - 259; DOI:
10.1021/ja00495a063
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Synthetic studies on polyether antibiotics. 4. Total synthesis of monensin. 1. Stereocontrolled synthesis of the left half of monensin
G. Schmid, T. Fukuyama, K. Akasaka, and Y. Kishi
pp 259 - 260; DOI:
10.1021/ja00495a064
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Synthetic studies on polyether antibiotics. 5. Total synthesis of monensin. 2. Stereocontrolled synthesis of the right half of monensin
T. Fukuyama, C. L. J. Wang, and Y. Kishi
pp 260 - 262; DOI:
10.1021/ja00495a065
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Synthetic studies on polyether antibiotics. 6. Total synthesis of monensin. 3. Stereocontrolled total synthesis of monensin
T. Fukuyama, K. Akasaka, D. S. Karanewsky, C. L. J. Wang, G. Schmid, and Y. Kishi
pp 262 - 263; DOI:
10.1021/ja00495a066
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Synthesis of monomeric niobium- and tantalum-benzyne complexes and the molecular structure of Ta(.eta.5-C5Me5)(C6H4)Me2
Stephan J. McLain, Richard R. Schrock, Paul R. Sharp, Melvyn Rowen Churchill, and Wiley J. Youngs
pp 263 - 265; DOI:
10.1021/ja00495a067
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Synthesis and structure of the imidazolate bridged dicopper(II) ion incorporated into a circular cryptate macrocycle
Peter K. Coughlin, John C. Dewan, Stephen J. Lippard, Eiichi Watanabe, and Jean Marie Lehn
pp 265 - 266; DOI:
10.1021/ja00495a068
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Carbon-14 kinetic isotope effects in the Menschutkin-type reaction of benzyl benzenesulfonates with N,N-dimethylanilines. Variation of the effects with substituents
Hiroshi Yamataka and Takashi Ando
pp 266 - 267; DOI:
10.1021/ja00495a069
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Direct tungsten-183 nuclear magnetic resonance: a powerful new structural tool for heteropoly- and isopolytungstate chemistry
Rafael Acerete, Charles F. Hammer, and Louis C. W. Baker
pp 267 - 269; DOI:
10.1021/ja00495a070
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Optical activity as a mixed parity phenomenon
L. D. Barron
pp 269 - 270; DOI:
10.1021/ja00495a071
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Oxygen transfer from ligands: cobalt nitro complexes as oxygenation catalysts
Benjamin S. Tovrog, Steven E. Diamond, and Frank Mares
pp 270 - 272; DOI:
10.1021/ja00495a072
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Experimental determination of the acidity and basicity of glycine in the gas phase
Michael J. Locke, Richard L. Hunter, and Robert T. McIver
pp 272 - 273; DOI:
10.1021/ja00495a073
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Photoactivation of cluster catalysis: a comparison of 1-pentene isomerization by tetracarbonyl(triphenylphosphine)ruthenium and 1,1,1,2,2,2,3,3,3-nonacarbonyl-1,2,3-tris(triphenylphosphine)-triangulo-triruthenium
James L. Graff, Robert D. Sanner, and Mark S. Wrighton
pp 273 - 275; DOI:
10.1021/ja00495a074
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Site specificity in the singlet oxygen-trisubstituted olefin reaction
Michael Orfanopoulos, Sister M. Bellarmine Grdina, and L. M. Stephenson
pp 275 - 276; DOI:
10.1021/ja00495a075
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Book Reviews

pp 276 - 278; DOI:
10.1021/ja00495a600
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Issue 2


Dynamic and static aspects of solubilization of neutral arenes in ionic micellar solutions
Mats Almgren, Franz Grieser, and J. Kerry Thomas
pp 279 - 291; DOI:
10.1021/ja00496a001
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Molecular and internal reorientation in 1,1,2,2-tetraphenylethane
F. M. Llort, K. Mislow, J. B. Wooten, A. L. Beyerlein, G. B. Savitsky, and J. Jacobus
pp 292 - 295; DOI:
10.1021/ja00496a002
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Equilibriums involving cation radical ion pairs
Ignacio J. Ocasio and Paul D. Sullivan
pp 295 - 298; DOI:
10.1021/ja00496a003
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Tunneling in collinear light-heavy-heavy reactions
Werner Jakubetz
pp 298 - 307; DOI:
10.1021/ja00496a004
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Sudden polarization: pyramidalization of twisted ethylene
Bernard R. Brooks and Henry F. Schaefer
pp 307 - 311; DOI:
10.1021/ja00496a005
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Conformations, stabilities, and charge distributions in 2- and 3-monosubstituted thiophenes. An ab initio molecular orbital study
James Kao and Leo Radom
pp 311 - 318; DOI:
10.1021/ja00496a006
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Theoretical exploration of the photochemical rearrangement of oxaziridines
Esther Oliveros, Monique Riviere, J. P. Malrieu, and Charles Teichteil
pp 318 - 322; DOI:
10.1021/ja00496a007
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An electrochemical and spectroscopic study of some aromatic hydrocarbons in the room temperature molten salt system aluminum chloride-n-butylpyridinium chloride
J. Robinson and R. A. Osteryoung
pp 323 - 327; DOI:
10.1021/ja00496a008
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Ion-solvent interaction. Effects of added polar compounds on the conductances of several alkali metal salts in 2-butanone at 25.degree.C
M. D. Jackson and W. R. Gilkerson
pp 328 - 333; DOI:
10.1021/ja00496a009
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Lanthanide ion probes of structure in biology. Laser-induced luminescence decay constants provide a direct measure of the number of metal-coordinated water molecules
William DeW. Horrocks and Daniel R. Sudnick
pp 334 - 340; DOI:
10.1021/ja00496a010
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Effect of halide complexation of cadmium(II) on cadmium-113 chemical shifts
Joseph J. H. Ackerman, Thomas V. Orr, Victor J. Bartuska, and Gary E. Maciel
pp 341 - 347; DOI:
10.1021/ja00496a011
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Trifluoromethanol (CF3OH) and trifluoromethylamine (CF3NH2)
Gerhard Kloeter and Konrad Seppelt
pp 347 - 349; DOI:
10.1021/ja00496a012
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Infrared photochemistry of halogenated ethylenes
Christopher Reiser, Frances M. Lussier, Craig C. Jensen, and Jeffrey I. Steinfeld
pp 350 - 357; DOI:
10.1021/ja00496a013
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Substituent effects of the trifluoromethyl group on electrophilic additions to alkenes. Solvolysis of the trifluoromethyl group. Protonation of alkenes less basic than ethylene, .rho.+ values of deactivated styrenes, and reactivity-selectivity effects
K. M. Koshy, Danielle Roy, and Thomas T. Tidwell
pp 357 - 363; DOI:
10.1021/ja00496a014
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Reactions and properties of some trimethyleneplatinum(IV) complexes. 6. Skeletal isomerization of platinacyclobutanes and its relevance to the mechanism of olefin metathesis
Razak J. Al-Essa, Richard J. Puddephatt, Mohammed A. Quyser, and Charles F. H. Tipper
pp 364 - 370; DOI:
10.1021/ja00496a015
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Phosphonamide stabilized allylic carbanions. New homoenolate anion equivalents
David A. Evans, James M. Takacs, and Kenneth M. Hurst
pp 371 - 378; DOI:
10.1021/ja00496a016
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Competing triplet reactions in azidoketones
Peter J. Wagner and B. J. Scheve
pp 378 - 383; DOI:
10.1021/ja00496a017
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Proton transfers of substituted ammonium salts. 14. The 1,cis-2,6-trimethylpiperidinium ion in anhydrous acidic dimethyl sulfoxide
Jean-Jacques Delpuech and Bernard Bianchin
pp 383 - 389; DOI:
10.1021/ja00496a018
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Diphenylthiirene 1-oxide. Synthesis, characterization, and reactivity
Louis A. Carpino and Hung-Wu Chen
pp 390 - 394; DOI:
10.1021/ja00496a019
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Manifestation of dual aromaticity in doubly charged annelated pentalenes
Itamar Willner, James Y. Becker, and Mordecai Rabinovitz
pp 395 - 401; DOI:
10.1021/ja00496a020
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Liquid crystalline solvents as mechanistic probes. 3. The influence of ordered media on the efficiency of the photodimerization of acenaphthylene
Jeanne M. Nerbonne and Richard G. Weiss
pp 402 - 407; DOI:
10.1021/ja00496a021
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Stereospecific acid-catalyzed rearrangements of 5,12-dimethylpentacyclo[6.4.0.02,5.03,12.04,9]dodecane-6,11-diones with their strain release to bisnordiamantane and diprotoadamantane ring systems
Kenichi Hirao, Mikio Taniguchi, Osamu Yonemitsu, Judith L. Flippen, and Bernhard Witkop
pp 408 - 414; DOI:
10.1021/ja00496a022
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Mechanistic aspects of the thermal equilibration of retinylidene imines and immonium salts
Patrick C. Mowery and Walther Stoeckenius
pp 414 - 417; DOI:
10.1021/ja00496a023
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Reactivity in methyl transfer reactions. 3. Equilibriums and rates in transfers between substituted thiophenoxides
Edward S. Lewis and Semyon Kukes
pp 417 - 419; DOI:
10.1021/ja00496a024
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The mechanism of alkaline hydrolysis of thiazolidines
Roberta Luhowy and Frank Meneghini
pp 420 - 426; DOI:
10.1021/ja00496a025
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Comments on the putative stereoselectivity in cysteine-aldehyde reactions. Selective C(2) inversion and C(4) epimerization in thiazolidine-4-carboxylic acids
Laszlo Szilagyi and Zoltan Gyorgydeak
pp 427 - 432; DOI:
10.1021/ja00496a026
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Use of polymers as protecting groups in organic synthesis. Application of polystyrylboronic acid to the one-pot synthesis of acylated carbohydrate derivatives
Jean M. J. Frechet, Lucy J. Nuyens, and Elizabeth Seymour
pp 432 - 436; DOI:
10.1021/ja00496a027
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Amino acid constituents of ristocetin A
Constance M. Harris, Jeffrey J. Kibby, James R. Fehlner, Austin B. Raabe, Thomas A. Barber, and Thomas M. Harris
pp 437 - 445; DOI:
10.1021/ja00496a028
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Crystal and molecular structure of the cyclic hexapeptide cyclo-(Gly-Pro-d-Phe)2
Joe N. Brown and C. H. Yang
pp 445 - 449; DOI:
10.1021/ja00496a029
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Conformations of poly(ethylene glycol) bound homooligo-L-alanines and -L-valines in aqueous solution
Claudio Toniolo, Gian Maria Bonora, and Manfred Mutter
pp 450 - 454; DOI:
10.1021/ja00496a030
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Studies of the thermodynamics of electron transfer reactions of blue copper proteins
Napapon Sailasuta, F. C. Anson, and Harry B. Gray
pp 455 - 458; DOI:
10.1021/ja00496a031
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Mechanism of alkaline hydrolysis of S-adenosyl-L-methionine and related sulfonium nucleosides
Ronald T. Borchardt
pp 458 - 463; DOI:
10.1021/ja00496a032
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Variation of the linear polarization across the emission band of nicotinamide 1,N6-ethenoadenine dinucleotide bound to dehydrogenases
A. Gafni, J. Schlessinger, and I. Z. Steinberg
pp 463 - 467; DOI:
10.1021/ja00496a033
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Electrochemistry of vitamin B-12. 4. Kinetics and mechanisms in B-12a-B-12r oxido-reduction
N. R. De Tacconi, D. Lexa, and J. M. Saveant
pp 467 - 473; DOI:
10.1021/ja00496a034
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A study of the peptide hormone oxytocin and of prolylleucylglycinamide by nitrogen-15 NMR
David H. Live, Herman R. Wyssbrod, Alan J. Fischman, William C. Agosta, Craig H. Bradley, and David Cowburn
pp 474 - 479; DOI:
10.1021/ja00496a035
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Intramolecular water bridge between the 2'-hydroxyl and phosphate groups of RNA. Cyclic nucleotides as a model system
Philip H. Bolton and David R. Kearns
pp 479 - 484; DOI:
10.1021/ja00496a036
PDF
Satellite structures in the ESCA spectra of (diphthalocyaninato)lanthanides(III) and -actinides(IV)
K. Tatsumi, K. Kasuga, and M. Tsutsui
pp 484 - 486; DOI:
10.1021/ja00496a037
PDF
Chemistry of organosilicon compounds. 108. Efficient trapping of silylenes through disilene intermediates
Yasuhiro Nakadaira, Toshiaki Kobayashi, Tatsuo Otsuka, and Hideki Sakurai
pp 486 - 487; DOI:
10.1021/ja00496a038
PDF
Chemistry of organosilicon compounds. 109. trans- and cis-1,2-Dimethyl-1,2-diphenyldisilene. Is Silicon:silicon a true double bond?
Hideki Sakurai, Yasuhiro Nakadaira, and Toshiaki Kobayashi
pp 487 - 488; DOI:
10.1021/ja00496a039
PDF
Activation of aldehyde carbon-hydrogen bonds to oxidative addition via formation of 3-methyl-2-aminopyridyl aldimines and related compounds: rhodium based catalytic hydroacylation
J. William Suggs
pp 489 - 489; DOI:
10.1021/ja00496a040
PDF
Reactions of aniline with olefins catalyzed by Group 8 metal complexes: N-alkylation and heterocycle formation
Steven E. Diamond, Andrew Szalkiewicz, and Frank Mares
pp 490 - 491; DOI:
10.1021/ja00496a041
PDF
Polyoxomolybdate-hydrocarbon interactions. Synthesis and structure of the CH2Mo4O15H3- anion and related methylenedioxymolybdates
V. W. Day, M. F. Fredrich, W. G. Klemperer, and R. S. Liu
pp 491 - 492; DOI:
10.1021/ja00496a042
PDF
An unusual rearrangement of ajaconine: an example of a "disfavored" 5-endo-trigonal ring closure
S. William Pelletier and Naresh V. Mody
pp 492 - 494; DOI:
10.1021/ja00496a043
PDF
Cyclization reactions via oxo-.pi.-allylpalladium(II) intermediates
Yoshihiko Ito, Hirokazu Aoyama, Toshikazu Hirao, Akira Mochizuki, and Takeo Saegusa
pp 494 - 496; DOI:
10.1021/ja00496a044
PDF
Fourier transform infrared vibrational circular dichroism
Laurence A. Nafie, Max Diem, and D. Warren Vidrine
pp 496 - 498; DOI:
10.1021/ja00496a045
PDF
The dynamic behavior of trans-dihalide-bishydrazone-palladium(II) complexes
Giovanni Natile, Lucio Cattalini, Francesco Gasparrini, and Luciano Caglioti
pp 498 - 499; DOI:
10.1021/ja00496a046
PDF
Formation of metal chelates in secondary ion mass spectrometry. Comparisons with solution chemistry
R. J. Day, S. E. Unger, and R. G. Cooks
pp 499 - 501; DOI:
10.1021/ja00496a047
PDF
Ionization of quaternary nitrogen compounds by secondary ion mass spectrometry
R. J. Day, S. E. Unger, and R. G. Cooks
pp 501 - 502; DOI:
10.1021/ja00496a048
PDF
Reactions in dry media. Cleavage of carbon-carbon single bonds by ozonation
Daniel Tal, Ehud Keinan, and Yehuda Mazur
pp 502 - 503; DOI:
10.1021/ja00496a049
PDF
Organometallic models for possible Fischer-Tropsch intermediates. Synthesis, structure, and reactions of a formaldehyde complex of osmium
Kevin L. Brown, George R. Clark, Christine E. L. Headford, Karen Marsden, and Warren R. Roper
pp 503 - 505; DOI:
10.1021/ja00496a050
PDF
Ipso nitration. Preparation of 4-methyl-4-nitrocyclohexadienols and detection of intramolecular hydrogen migration (NIH shift) upon solvolytic rearomatization
K. S. Feldman, Ann McDermott, and P. C. Myhre
pp 505 - 506; DOI:
10.1021/ja00496a051
PDF
Electrophilic aromatic protonation of stable .pi. carbocations
Richard M. Pagni and Robert J. Smith
pp 506 - 508; DOI:
10.1021/ja00496a052
PDF
Novel bridging sulfide anion complexes of the hexacarbonyldiiron unit: a new route to alkylthio complexes of iron
Dietmar Seyferth and Richard S. Henderson
pp 508 - 509; DOI:
10.1021/ja00496a053
PDF
The case for stereoelectronic axial migration of hydrogen in nonrigid cyclohexylidenes in chair conformation
Linda Seghers Press and Harold Shechter
pp 509 - 510; DOI:
10.1021/ja00496a054
PDF
Stereochemical course of glycerol kinase, pyruvate kinase, and hexokinase: phosphoryl transfer from chiral [.gamma.(S)-16O,17O,18O]ATP
Walter A. Blaettler and Jeremy R. Knowles
pp 510 - 511; DOI:
10.1021/ja00496a055
PDF
Additions and Corrections - Structure of Nogalamycin
Paul F. Wiley, Ronald B. Kelly, E. Louis Caron, Veronica H. Wiley, Jian H. Johnson, Forrest A. MacKellar, and Stephen A. Mizak
pp 512 - 512; DOI:
10.1021/ja00496a600
PDF
Additions and Corrections - The Microwave Spectrum, Structure, and Dipole Moment of 2-Mercaptoethanol: Evidence for an Intramolecualr OH···S Hydrogen Bond
Eun-Mo Sung, and Marlin D. Harmony
pp 512 - 512; DOI:
10.1021/ja00496a601
PDF
Additions and Corrections - Studies of Nitrogen Metabolism Using 13C NMR Spectroscopy. 1. Streptonigrin Biosynthesis
Steven J. Gould, and Chiu Chin Chang
pp 512 - 512; DOI:
10.1021/ja00496a602
PDF
Additions and Corrections - Experimental Evidence for Trapped Valences in the Mixed-Valence Complex μ-Pyrazine-bis(pentaammineruthenium) Tosylate. Electron Paramagnetic Resonance, Magnetic Susceptibility, and Nuclear Magnetic Resonance Results.
Bruce C. Bunker, Russell S. Drago, David N. Hendrickson, Robert M. Richman, and Stephen L. Kessell
pp 512 - 512; DOI:
10.1021/ja00496a603
PDF
Additions and Corrections - π,π-Biradicaloid Hydrocarbons. The Pleiadene Family. 3. A Facile Symmetry-Forbidden Thermal Conversion of a Polycyclic Butadiene Moiety to a Cyclobutene.
Richard P. Steiner, and Josef Michl
pp 512 - 512; DOI:
10.1021/ja00496a604
PDF
Additions and Corrections - Does a Methyl Substituent Stabilize or Destabilize Anions?
Addy Pross, and Leo Radom
pp 512 - 512; DOI:
10.1021/ja00496a605
PDF
Additions and Corrections - Characterization of the Asymmetric Nitric Oxide Dimer O==N==O==N by Resonance Raman and Infrared Spectroscopy
J. R. Ohlsen, and J. Laane
pp 512 - 512; DOI:
10.1021/ja00496a606
PDF
Additions and Corrections - Photchemistry of Bichromorphic Molecules. Photochemistry and Photophysics of 2-Methylenebenznorbornene and Related Nonconjugated Aryl Olefins in Nonprotic Media.
Frank Scully, Tom Nylund, Fred Palensky, and Harry Morrison
pp 512 - 512; DOI:
10.1021/ja00496a607
PDF
Book Reviews

pp 513 - 514; DOI:
10.1021/ja00496a608
PDF

Issue 3


The role of solvation and choice of anion in controlling the thermodynamic stability of the cyclooctatetraene and anthracene dianions
Gerald R. Stevenson, Jose Valentin, Elmer Williams, Gary Caldwell, and Antonio E. Alegria
pp 515 - 519; DOI:
10.1021/ja00497a001
PDF
Calorimetric disproportionation enthalpies
Gerald R. Stevenson, Elmer Williams, and Gary Caldwell
pp 520 - 522; DOI:
10.1021/ja00497a002
PDF
Carbonium ions in solution. 9. The relationship between carbocations in superacid and solvolysis transition states
Edward M. Arnett, Craig Petro, and Paul von R. Schleyer
pp 522 - 526; DOI:
10.1021/ja00497a003
PDF
Stabilization of D3h pentacoordinate carbonium ions. Linear three-center-two-electron bonds. Implications for aliphatic electrophilic substitution reactions
Eluvathingal D. Jemmis, Jayaraman Chandrasekhar, and Paul von R. Schleyer
pp 527 - 533; DOI:
10.1021/ja00497a004
PDF
Effect of carbon atom pyramidalization on the bonding in ethylene
Walter V. Volland, Ernest R. Davidson, and Weston Thatcher Borden
pp 533 - 537; DOI:
10.1021/ja00497a005
PDF
Effect of protonation of nitrogen-containing organic molecules on the reactivity toward positronium
Yoshinori Kobayashi, Tsutomu Nomizu, and Yusuke Ujihira
pp 537 - 540; DOI:
10.1021/ja00497a006
PDF
Conformational influences on electronic spectra and structure. Polymorphs of N-(p-chlorobenzylidene)-p-chloroaniline
J. Bernstein, T. E. Anderson, and C. J. Eckhardt
pp 541 - 545; DOI:
10.1021/ja00497a007
PDF
Proton exchange and temperature studies of pyrazole in dimethyl-d6 sulfoxide by carbon-13 NMR
William M. Litchman
pp 545 - 547; DOI:
10.1021/ja00497a008
PDF
Solid-state spectroelectrochemistry of crosslinked donor bound polymer films
Frank B. Kaufman and Edward M. Engler
pp 547 - 549; DOI:
10.1021/ja00497a009
PDF
Optical activity of saturated ketones. Ab initio localized orbital analysis of a model ketone in the random-phase approximation
Thomas D. Bouman, Bjoern Voigt, and Aage E. Hansen
pp 550 - 558; DOI:
10.1021/ja00497a010
PDF
Theoretical relationship between diamagnetic susceptibility exaltation and aromatic stabilization
Junichi Aihara
pp 558 - 560; DOI:
10.1021/ja00497a011
PDF
Theoretical studies of the reactions of the sulfur-sulfur bond. 2. Binding and reactions with Group 1A and 2A metals
Jan A. Pappas
pp 561 - 567; DOI:
10.1021/ja00497a012
PDF
Light-initiated electron transfer in functional surfactant assemblies. 1. Micelles with transition metal counterions
Yoshikiyo Moroi, Andre M. Braun, and Michael Graetzel
pp 567 - 572; DOI:
10.1021/ja00497a013
PDF
Light-initiated redox reactions in functional micellar assemblies. 2. Dynamics in europium(III) surfactant solutions
Yoshikiyo Moroi, Pierre P. Infelta, and Michael Graetzel
pp 573 - 579; DOI:
10.1021/ja00497a014
PDF
The .sigma. strength of ligands coordinated to transition metal ions
Jeremy K. Burdett
pp 580 - 583; DOI:
10.1021/ja00497a015
PDF
The proton chemical shift in polycrystalline decarbonyldihydrotriosmium, dodecacarbonyltetrahydrotetraruthenium, and dodecacarbonyltetrahydrotetraosmium
A. T. Nicol and R. W. Vaughan
pp 583 - 585; DOI:
10.1021/ja00497a016
PDF
CpM(CO)2(ligand) (Cp = cyclopentadienyl, M = metal) complexes
Birgitte E. R. Schilling, Roald Hoffmann, and Dennis L. Lichtenberger
pp 585 - 591; DOI:
10.1021/ja00497a017
PDF
Effect of ligand asymmetry on the structure and reactivity of CpMLL'(allyl) (Cp = cyclopentadienyl, M = metal, L = ligand) and -(ethylene) complexes
Birgitte E. R. Schilling, Roald Hoffmann, and J. W. Faller
pp 592 - 598; DOI:
10.1021/ja00497a018
PDF
Coordination chemistry of microbial iron transport compounds. 11. Solution equilibriums and electrochemistry of ferric rhodotorulate complexes
Carl J. Carrano, Stephen R. Cooper, and Kenneth N. Raymond
pp 599 - 604; DOI:
10.1021/ja00497a019
PDF
Preparation and characterization of organoiron secondary alkoxycarbene complexes
Alan R. Cutler
pp 604 - 606; DOI:
10.1021/ja00497a020
PDF
Water-soluble polyphosphazenes as carrier molecules for iron(III) and iron(II) porphyrins
Harry R. Allcock, Paul P. Greigger, James E. Gardner, and James L. Schmutz
pp 606 - 611; DOI:
10.1021/ja00497a021
PDF
Ligand exchange in TaX(.eta.4-naphthalene)(Me2PC2H4PMe2)2. The pentagonal bipyramid to monocapped trigonal prism traverse
J. O. Albright, S. Datta, B. Dezube, J. K. Kouba, D. S. Marynick, S. S. Wreford, and Bruce M. Foxman
pp 611 - 619; DOI:
10.1021/ja00497a022
PDF
A study of the stereochemistry at iron of electrophilic cleavage of the iron-carbon .sigma. bond in methyl(.eta.5-1-methyl-3-phenylcyclopentadienyl)carbonyl(triphenylphosphine)iron(II)
Thomas G. Attig, Raymond G. Teller, Su-Miau Wu, Robert Bau, and Andrew Wojcicki
pp 619 - 628; DOI:
10.1021/ja00497a023
PDF
Thermolysis of 2-methylazulene(1-carbon-13) and mechanism of the azulene to naphthalene rearrangement
Roger W. Alder, Robert W. Whiteside, Graham Whittaker, and Colin Wilshire
pp 629 - 632; DOI:
10.1021/ja00497a024
PDF
Solvation of alkali metal cations of arylmethyl anions by ethereal solvents
Daniel H. O'Brien, Charles R. Russell, and Alan J. Hart
pp 633 - 639; DOI:
10.1021/ja00497a025
PDF
Reactivity of superoxide ion with carbonyl compounds in aprotic solvents
Morton J. Gibian, Donald T. Sawyer, Timothy Ungermann, R. Tangpoonpholvivat, and Mark M. Morrison
pp 640 - 644; DOI:
10.1021/ja00497a026
PDF
Solute-solvent interactions in the ground state and in electronic excited states. The dipolar aprotic to polar protic solvent blue shift of nitroaromatics
Paul Haberfield, Michael S. Lux, Ira Jasser, and Douglas Rosen
pp 645 - 647; DOI:
10.1021/ja00497a027
PDF
Substitution reactions which proceed via radical anion intermediates. 20. Replacement of the nitro group by hydrogen
Nathan Kornblum, Stephen C. Carlson, and Ronald G. Smith
pp 647 - 657; DOI:
10.1021/ja00497a028
PDF
Substitution reactions which proceed via radical anion intermediates. 21. Rearrangements in the reaction of .beta.-arylated nitroparaffins with the sodium salt of methanethiol
Nathan Kornblum, Joerg Widmer, and Stephen C. Carlson
pp 658 - 664; DOI:
10.1021/ja00497a029
PDF
Dynamic stereochemistry and steric effects in overcrowded ethylenes. Conformational behavior of dixanthylenes
Israel Agranat and Yitzhak Tapuhi
pp 665 - 671; DOI:
10.1021/ja00497a030
PDF
Heats of hydrogenation and formation of linear alkynes and a molecular mechanics interpretation
Donald W. Rogers, Orlando A. Dagdagan, and Norman L. Allinger
pp 671 - 676; DOI:
10.1021/ja00497a031
PDF
Chemistry of polymer-bound o-benzyne. Frequency of encounter between substituents on crosslinked polystyrenes
Stephen Mazur and P. Jayalekshmy
pp 677 - 683; DOI:
10.1021/ja00497a032
PDF
Chemistry of singlet oxygen. 30. The unstable primary product of tocopherol photooxidation
R. L. Clough, B. G. Yee, and C. S. Foote
pp 683 - 686; DOI:
10.1021/ja00497a033
PDF
Ion thermochemistry of low-volatility compounds in the gas phase. 1. Intrinsic basicities of .alpha.-amino acids
Michael Meot-Ner, Edward P. Hunter, and Frank H. Field
pp 686 - 689; DOI:
10.1021/ja00497a034
PDF
Tetracyclines. 9. Total synthesis of dl-terramycin
Hans Muxfeldt, George Haas, Goetz Hardtmann, Faizulla Kathawala, Jared B. Mooberry, and Edwin Vedejs
pp 689 - 701; DOI:
10.1021/ja00497a035
PDF
Biosynthesis of the antibiotic granaticin
Carl E. Snipes, Ching-Jer Chang, and Heinz G. Floss
pp 701 - 706; DOI:
10.1021/ja00497a036
PDF
Biosynthesis of the C15 macrolide antibiotics. 1. Biochemical origin of the four oxygen atoms in brefeldin A
Clayton T. Mabuni, Luigi Garlaschelli, Robert A. Ellison, and C. Richard Hutchinson
pp 707 - 714; DOI:
10.1021/ja00497a037
PDF
Conformational analysis by nuclear magnetic resonance spectroscopy: Nitrogen-15 NMR of a cyclic pentapeptide
Kenneth L. Williamson, Lila G. Pease, and John D. Roberts
pp 714 - 716; DOI:
10.1021/ja00497a038
PDF
Electrophilic substitution at saturated carbon. 52. A model for the proton transfer steps of biological transamination and the effect of a 4-pyridyl group on the base-catalyzed racemization of a carbon acid
David A. Jaeger, Michael D. Broadhurst, and Donald J. Cram
pp 717 - 732; DOI:
10.1021/ja00497a039
PDF
Size and asymmetry of spatial distributions for unperturbed triglycerides
Wayne L. Mattice
pp 732 - 736; DOI:
10.1021/ja00497a040
PDF
The rate of site-site interactions in functionalized polystyrenes
Julius Rebek and John E. Trend
pp 737 - 737; DOI:
10.1021/ja00497a041
PDF
Synthesis and characterization of (pentafluorosulfur)acetylenes
A. D. Berry, R. A. De Marco, and W. B. Fox
pp 737 - 738; DOI:
10.1021/ja00497a042
PDF
Dynamic equilibrium between ion pairs of aromatic [9]annulene anion and of olefinic nonafulvene structure
Gernot Boche and Frank Heidenhain
pp 738 - 739; DOI:
10.1021/ja00497a043
PDF
Facile attachment of transition metal complexes to graphite electrodes coated with polymeric ligands. Observation and control of metal-ligand coordination among reactants confined to electrode surfaces
Noboru Oyama and Fred C. Anson
pp 739 - 741; DOI:
10.1021/ja00497a044
PDF
Rhenium formyl and carboxy complexes derived from the cyclopentadienyl(dicarbonyl)nitrosylrhenium(1+) cation: models for the Fischer-Tropsch and water gas shift reactions
Charles P. Casey, Mark A. Andrews, and James E. Rinz
pp 741 - 743; DOI:
10.1021/ja00497a045
PDF
Spectroscopic studies on model compounds of the phytochrome chromophore. Protonation and deprotonation of biliverdin dimethyl ester
Leon Margulies and Manfred Stockburger
pp 743 - 744; DOI:
10.1021/ja00497a046
PDF
The origin of the red shift of the absorption spectra of aggregated chlorophylls
Arieh Warshel
pp 744 - 746; DOI:
10.1021/ja00497a047
PDF
Picosecond studies of excited-state protonation and deprotonation kinetics. The laser pH jump
J. H. Clark, S. L. Shapiro, A. J. Campillo, and K. R. Winn
pp 746 - 748; DOI:
10.1021/ja00497a048
PDF
Preparation of new palladium dioxygen complexes using superoxide ion
Hiroharu Suzuki, Kyoichiro Mizutani, Yoshihiko Morooka, and Tsuneo Ikawa
pp 748 - 749; DOI:
10.1021/ja00497a049
PDF
(C2)-Dioxa-c20-octaquinane, a heterocyclic trisecododecahedrane
Douglas Balogh, William J. Begley, David Bremner, Matthew J. Wyvratt, and Leo A. Paquette
pp 749 - 751; DOI:
10.1021/ja00497a050
PDF
Enzyme-assisted semisynthesis of human insulin
Ken Inouye, Kunio Watanabe, Kazuyuki Morihara, Yoshihiro Tochino, Takashi Kanaya, Junji Emura, and Shumpei Sakakibara
pp 751 - 752; DOI:
10.1021/ja00497a051
PDF
Phosphoranes as intermediates in the acid hydrolysis of acyclic phosphonate esters: evidence from oxygen exchange
I. Sigal and F. H. Westheimer
pp 752 - 754; DOI:
10.1021/ja00497a052
PDF
A copper(I) derivative of a ferraborane: preparation, crystal, and molecular structure of Cu[P(C6H5)3]2B5H8Fe(CO)3
M. Mangion, J. D. Ragaini, T. A. Schmitkons, and S. G. Shore
pp 754 - 755; DOI:
10.1021/ja00497a053
PDF
Carbon monoxide exchange in 1,2-dimethyl-1,3,2-diazaphosphenium tetracarbonyliron cation
Dennis W. Bennett and Robert W. Parry
pp 755 - 757; DOI:
10.1021/ja00497a054
PDF
Conformational analysis of trans-1,2-dibromocyclohexane by low-temperature cyclic voltammetry
Andrew J. Klein and Dennis H. Evans
pp 757 - 758; DOI:
10.1021/ja00497a055
PDF
Two conformations of the pentadienyl radical
D. Griller, K. U. Ingold, and J. C. Walton
pp 758 - 759; DOI:
10.1021/ja00497a056
PDF
Derivatives of heteropolyanions. 1. Organic derivatives of W12SiO404-, W12PO403-, and Mo12SiO404-
W. H. Knoth
pp 759 - 760; DOI:
10.1021/ja00497a057
PDF
Enhancement of nuclear magnetic resonance signals by polarization transfer
Gareth A. Morris and Ray Freeman
pp 760 - 762; DOI:
10.1021/ja00497a058
PDF
Stereospecific synthesis of (.+-.)-trisporol B, a prohormone of Blakeslea trispora, and a facile synthesis of (.+-.)-trisporic acids
Michael P. Prisbylla, Kunihiko Takabe, and James D. White
pp 762 - 763; DOI:
10.1021/ja00497a059
PDF
Formation of the trihalide ion Cl3- in the gas phase
Richard Robbiani and J. L. Franklin
pp 764 - 765; DOI:
10.1021/ja00497a060
PDF
Anion complexes of ferrous porphyrins
Terry Mincey and T. G. Traylor
pp 765 - 766; DOI:
10.1021/ja00497a061
PDF
6,9-Pyridazaprostacyclin and derivatives: the first "aromatic" prostacyclins
K. C. Nicolaou, W. E. Barnette, and R. L. Magolda
pp 766 - 768; DOI:
10.1021/ja00497a062
PDF
Metalation of arenechromium tricarbonyl complexes and electrophilic trapping of the complexed phenyllithium intermediate
M. F. Semmelhack, J. Bisaha, and M. Czarny
pp 768 - 770; DOI:
10.1021/ja00497a063
PDF
Tricyclobutabenzene
Wutichai Nutakul, Randolph P. Thummel, and Austin D. Taggart
pp 770 - 771; DOI:
10.1021/ja00497a064
PDF
Intramolecular excimer-forming probes of aqueous micelles
Jack Emert, Carl Behrens, and Merrill Goldenberg
pp 771 - 772; DOI:
10.1021/ja00497a065
PDF
A comparison of intermolecular and intramolecular excimer formation in detergent solutions. Temperature effects and microviscosity measurements
Nicholas J. Turro, Masayuki Aikawa, and Ahmad Yekta
pp 772 - 774; DOI:
10.1021/ja00497a066
PDF
Sensitivity enhancement in natural abundance proton-coupled nitrogen-15 NMR spectra using the selective population transfer method
Hans J. Jakobsen and Wallace S. Brey
pp 774 - 775; DOI:
10.1021/ja00497a067
PDF
A time-dependent cyclodextrin induced perturbation of ionic equilibriums across a carbohydrate membrane
Brock Siegel, Diane Eberlein, Daniel Rifkin, and Kathleen A. Davis
pp 775 - 777; DOI:
10.1021/ja00497a068
PDF
Evidence for a radical-anion pathway of a phenylcyclopropyl ring cleavage in the presence of potassium tert-butoxide
Martin Newcomb, Terry Seidel, and Mary B. McPherson
pp 777 - 778; DOI:
10.1021/ja00497a069
PDF
Book Reviews

pp 779 - 782; DOI:
10.1021/ja00497a600
PDF

Issue 4


Relationship between olefinic .pi. complexes and three-membered rings
Michael J. S. Dewar and George P. Ford
pp 783 - 791; DOI:
10.1021/ja00498a001
PDF
Perturbation theory and the effects of substitution in square and bipyramidal .sigma.-bonded compounds
Evgeny Shustorovich
pp 792 - 796; DOI:
10.1021/ja00498a002
PDF
The role of Penning ionization of the minor species in a neon hollow cathode discharge
Kermit C. Smyth, B. L. Bentz, C. G. Bruhn, and W. W. Harrison
pp 797 - 799; DOI:
10.1021/ja00498a003
PDF
Raman optical activity. Computation of circular intensity differentials by the atom-dipole interaction model
P. L. Prasad and D. F. Burow
pp 800 - 805; DOI:
10.1021/ja00498a004
PDF
Raman optical activity. Computation of circular intensity differentials for bromochlorofluoromethane
P. L. Prasad and D. F. Burow
pp 806 - 812; DOI:
10.1021/ja00498a005
PDF
Urey-Bradley force field, valence force field, and ab initio study of intramolecular forces in tri-tert-butylmethane and isobutane
Arnold T. Hagler, Peter S. Stern, Shneior Lifson, and Sara Ariel
pp 813 - 819; DOI:
10.1021/ja00498a006
PDF
Application of ab initio molecular orbital calculations to the structural moieties of carbohydrates. 4
G. A. Jeffrey and J. H. Yates
pp 820 - 825; DOI:
10.1021/ja00498a007
PDF
Theoretical studies of drug-dinucleotide interactions. Empirical energy function calculations on the interaction of ethidium, 9-aminoacridine, and proflavin cations with the base-paired dinucleotides GpC and CpG
Merrill E. Nuss, Frederick J. Marsh, and Peter A. Kollman
pp 825 - 833; DOI:
10.1021/ja00498a008
PDF
Crystal structure and conformation of the cyclic hexapeptide cyclo-(Gly-L-Pro-D-Ala)2
E. C. Kostansek, W. N. Lipscomb, and W. E. Thiessen
pp 834 - 837; DOI:
10.1021/ja00498a009
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 33. Diazirinyl radicals
Y. Maeda and K. U. Ingold
pp 837 - 840; DOI:
10.1021/ja00498a010
PDF
Nuclear magnetic resonance study of the interaction of lanthanide shift reagent with tris(.beta.-diketonato)cobalt(III) complexes. Kinetics of adduct formation involving slow chemical exchange at ambient temperature
Leonard F. Lindoy and Hon Way Louie
pp 841 - 847; DOI:
10.1021/ja00498a011
PDF
Oxidation-reduction reactions of complexes with macrocyclic ligands. Halide-mediated electron transfer involving low-spin cobalt(III)-(II) couples
Bill Durham, John F. Endicott, Chung-Lai Wong, and D. Paul Rillema
pp 847 - 857; DOI:
10.1021/ja00498a012
PDF
Reaction of a tetraaza[14]annulene cobalt(III) complex with acetylene. Synthesis and structural characterization of a novel cobalt(III) complex containing a pentadentate macrocyclic ligand with a carbon .sigma.-donor atom
Marvin C. Weiss, Guy C. Gordon, and Virgil L. Goedken
pp 857 - 864; DOI:
10.1021/ja00498a013
PDF
Aspects of chirality retention in rearrangements of pseudooctahedral molybdenum and tungsten complexes
J. W. Faller, D. A. Haitko, R. D. Adams, and D. F. Chodosh
pp 865 - 876; DOI:
10.1021/ja00498a014
PDF
Lewis acid mediated reactions of organotransition metal complexes. A marked promotion of the sulfur dioxide insertion in alkyl(.eta.5-cyclopentadienyl)tricarbonyltungsten(II) by boron(III) and antimony(V) fluorides
Roland G. Severson and Andrew Wojcicki
pp 877 - 883; DOI:
10.1021/ja00498a015
PDF
A comparison of the rates of electron exchange reactions of ammine complexes of ruthenium(II) and -(III) with the predictions of adiabatic, outer-sphere electron transfer models
Gilbert M. Brown and Norman Sutin
pp 883 - 892; DOI:
10.1021/ja00498a016
PDF
Crystal and molecular structures of decamethylmanganocene and decamethylferrocene. Static Jahn-Teller distortion in a metallocene
Derek P. Freyberg, John L. Robbins, Kenneth N. Raymond, and James C. Smart
pp 892 - 897; DOI:
10.1021/ja00498a017
PDF
Pyrazine and 1,4-diazabicyclo[2.2.2]octane as magnetic exchange propagating bridges in binuclear copper(II) and vanadyl complexes
Muin S. Haddad, David N. Hendrickson, J. Patrick Cannady, Russell S. Drago, and David S. Bieksza
pp 898 - 906; DOI:
10.1021/ja00498a018
PDF
Preparations and properties of nitrosyl complexes of iron tetramethylcyclam. X-ray structures of [Fe(C14H32N4)NO](BF4)2, a S = 3/2-1/2 spin-equilibrium complex, and [Fe(C14H32N4)(NO)(OH)](ClO4)2.CH3CN
Keith D. Hodges, R. G. Wollmann, S. L. Kessel, D. N. Hendrickson, D. G. Van Derveer, and E. Kent Barefield
pp 906 - 917; DOI:
10.1021/ja00498a019
PDF
The chemical evolution of a nitrogenase model. 17. Simulation of steric and of inhibitory effects at the enzymic active site with acetylenes and nitriles as the substrates, and "molybdoinsulin" catalysts
Barbara J. Weathers, John H. Grate, and G. N. Schrauzer
pp 917 - 924; DOI:
10.1021/ja00498a020
PDF
Chemical evolution of a nitrogenase model. 18. Reduction of molecular nitrogen with molybdoinsulin catalysts
Barbara J. Weathers, John H. Grate, Norman A. Strampach, and Gerhard N. Schrauzer
pp 925 - 928; DOI:
10.1021/ja00498a021
PDF
Some reactions of the perbromate ion in aqueous solution
Evan H. Appelman, Ulrik K. Klaening, and Richard C. Thompson
pp 929 - 934; DOI:
10.1021/ja00498a022
PDF
A directing effect of neighboring aromatic groups on the regiochemistry of formation and stereochemistry of alkylation and bromination of ketone lithium enolates. Evidence for lithium-arene coordination and dramatic effect of copper(I) in controlling stereochemistry and limiting polyalkylation
Gary H. Posner and Carl M. Lentz
pp 934 - 946; DOI:
10.1021/ja00498a023
PDF
Hydrogen bonding in N-substituted amino acids. Crystal structure of the N,N-diethyl-.beta.-alanine-benzene inclusion compound
M. A. Peterson, H. Hope, and C. P. Nash
pp 946 - 950; DOI:
10.1021/ja00498a024
PDF
Low-temperature flow NMR investigation of the transient intermediate in the nucleophilic aromatic substitution of 2,4,6-trinitroanisole by n-butylamine
Colin A. Fyfe, Sadrudin W. H. Damji, and Alexander Koll
pp 951 - 955; DOI:
10.1021/ja00498a025
PDF
Low-temperature flow NMR investigation of the reaction of 2,4,6-trinitroanisole with secondary amines
Colin A. Fyfe, Sadrudin W. H. Damji, and Alexander Koll
pp 956 - 960; DOI:
10.1021/ja00498a026
PDF
Pyruvamides. 3. Involvement of the amide group in carbinolamine formation, gem-diamine formation, and transimination
William Lopatin, Paul R. Young, and Terence C. Owen
pp 960 - 969; DOI:
10.1021/ja00498a027
PDF
The reversibility of the ring-opening step in the hydrolysis of tropone ethylene ketal and tropone trimethylene ketal
Robert A. McClelland, Mahmood Ahmad, and George Mandrapilias
pp 970 - 974; DOI:
10.1021/ja00498a028
PDF
Acid-catalyzed hydrolysis of N-vinylacetamides (enamides). Substituent effects of the acetamido and amino groups and linear free energy correlations of cyclohexene reactivities
V. M. Csizmadia, K. M. Koshy, K. C. M. Lau, R. A. McClelland, V. J. Nowlan, and Thomas T. Tidwell
pp 974 - 979; DOI:
10.1021/ja00498a029
PDF
Structures and mass spectral behavior of the inositol cyclic boronic esters
Jacek Wiecko and William R. Sherman
pp 979 - 983; DOI:
10.1021/ja00498a030
PDF
Novel synthesis of .alpha.-methylene carbonyl compounds
Tatsuya Shono, Ikuzo Nishiguchi, Tawara Komamura, and Manji Sasaki
pp 984 - 987; DOI:
10.1021/ja00498a031
PDF
A total synthesis of dl-cerulenin
Robert K. Boeckman and Edward W. Thomas
pp 987 - 994; DOI:
10.1021/ja00498a032
PDF
Nitroxides. 73. Electron spin resonance study of chiral recognition by cyclodextrin
J. Michon and A. Rassat
pp 995 - 996; DOI:
10.1021/ja00498a033
PDF
Avidin-biotin interaction. Synthesis, oxidation, and spectroscopic properties of linked models
Fu-Tong Liu and Nelson J. Leonard
pp 996 - 1005; DOI:
10.1021/ja00498a034
PDF
Avidin-biotin interaction. Crystal and molecular structures of two linked models
William F. Paton, Fu-Tong Liu, and Iain C. Paul
pp 1005 - 1013; DOI:
10.1021/ja00498a035
PDF
Nonoxidative cyclization of squalene by Tetrahymena pyriformis. Incorporation of a 3.beta. hydrogen (deuterium) atom into tetrahymanol
D. John Aberhart and Eliahu Caspi
pp 1013 - 1019; DOI:
10.1021/ja00498a036
PDF
Specific inclusion catalysis by .beta.-cyclodextrin in the one-step preparation of vitamin K1 or K2 analogs
Iwao Tabushi, Kazuo Yamamura, Kahee Fujita, and Hiromu Kawakubo
pp 1019 - 1026; DOI:
10.1021/ja00498a037
PDF
Superoxide dismutase activities of an iron porphyrin and other iron complexes
Robert F. Pasternack and Barry Halliwell
pp 1026 - 1031; DOI:
10.1021/ja00498a038
PDF
Caution in using nitrogen-15-carbon-13 spin-spin coupling for determining (bio)synthetic pathways
Masatsune Kainosho
pp 1031 - 1032; DOI:
10.1021/ja00498a039
PDF
Hydroxylation and epoxidation catalyzed by iron-porphine complexes. Oxygen transfer from iodosylbenzene
John T. Groves, Thomas E. Nemo, and Richard S. Myers
pp 1032 - 1033; DOI:
10.1021/ja00498a040
PDF
Rapid amide hydrolysis mediated by copper and zinc
John T. Groves and Reginald M. Dias
pp 1033 - 1035; DOI:
10.1021/ja00498a041
PDF
Conversion of allylic carbamates into olefins with lithium dimethylcuprate. A new formal SN2' reaction
Carlo Gallina and Pier Giuseppe Ciattini
pp 1035 - 1036; DOI:
10.1021/ja00498a042
PDF
Infrared photochemistry of a volatile uranium compound with 10-.mu. absorption
Steven S. Miller, Donald D. DeFord, Tobin J. Marks, and Eric Weitz
pp 1036 - 1037; DOI:
10.1021/ja00498a043
PDF
Total synthesis of gibberellic acid. A new and effective route to a key tricyclic intermediate
E. J. Corey and Janice Gorzynski Smith
pp 1038 - 1039; DOI:
10.1021/ja00498a044
PDF
Stereochemistry of the reaction of chlorine(I) trifluoromethanesulfonate with alkenes and alkyl halides
Yutaka Katsuhara and Darryl D. DesMarteau
pp 1039 - 1040; DOI:
10.1021/ja00498a045
PDF
Electrochemical oxidation of some mesocyclic dithioethers and related compounds
George S. Wilson, Dale D. Swanson, Jacob T. Klug, Richard S. Glass, Michael D. Ryan, and W. Kenneth Musker
pp 1040 - 1042; DOI:
10.1021/ja00498a046
PDF
Electrochemical generation of [Rh(diphos)2]0 and its role in an electrocatalytic reduction of cyclohexyl halides
John A. Sofranko, Richard Eisenberg, and Jack A. Kampmeier
pp 1042 - 1044; DOI:
10.1021/ja00498a047
PDF
Coupling and hydroxylation of lithium and Grignard reagents by oxaziridines
Franklin A. Davis, Paul A. Mancinelli, Krishna Balasubramanian, and Upender K. Nadir
pp 1044 - 1045; DOI:
10.1021/ja00498a048
PDF
Transition metal activation of aldehydes: platinum metal derivatives of o-diphenylphosphinobenzaldehyde
Thomas B. Rauchfuss
pp 1045 - 1047; DOI:
10.1021/ja00498a049
PDF
Synthesis and x-ray structure of N[(CH2)2O(2,6-C6H3N)O(CH2)2]3N: a D3 macrobicyclic ligand capped by two sp2 nitrogen atoms
George R. Newkome, Veronica Majestic, Frank Fronczek, and Jerry L. Atwood
pp 1047 - 1048; DOI:
10.1021/ja00498a050
PDF
Ring-chain tautomerism in 1,3-dimethylimidazolidine on the NMR time scale
Joseph B. Lambert and Michal W. Majchrzak
pp 1048 - 1049; DOI:
10.1021/ja00498a051
PDF
Racemization of isovaline by .gamma.-radiation. Cosmological implications
William A. Bonner, Neal E. Blair, and Richard M. Lemmon
pp 1049 - 1050; DOI:
10.1021/ja00498a052
PDF
Raman scattering from glucagon-dimyristoyllecithin complexes. A model system for serum lipoproteins
T. Taraschi and R. Mendelsohn
pp 1050 - 1052; DOI:
10.1021/ja00498a053
PDF
Photochemical and thermal isomerizations of 1-methoxyallyl cations. A further photoisomerization pathway of protonated enones
Ronald F. Childs and Mark E. Hagar
pp 1052 - 1053; DOI:
10.1021/ja00498a054
PDF
Tertiary phosphine complexes of low-valent zirconium and their properties
S. Datta, S. S. Wreford, R. P. Beatty, and T. J. McNeese
pp 1053 - 1054; DOI:
10.1021/ja00498a055
PDF
Total synthesis of .alpha.-amino-3-chloro-4,5-dihydro-5-isoxazoleacetic acid (AT-125), an antitumor antibiotic
R. C. Kelly, I. Schletter, S. J. Stein, and W. Wierenga
pp 1054 - 1056; DOI:
10.1021/ja00498a056
PDF
Photodisaggregation of chlorophyll a and b dimers
N. Periasamy and H. Linschitz
pp 1056 - 1057; DOI:
10.1021/ja00498a057
PDF
Total synthesis of (RC)-sparsomycin
Paul Helquist and Mohammed Saleh Shekhani
pp 1057 - 1059; DOI:
10.1021/ja00498a058
PDF
Acid-catalyzed hydration of di-tert-butylketene
Shaikh Habibul Kabir, Hani R. Seikaly, and Thomas T. Tidwell
pp 1059 - 1060; DOI:
10.1021/ja00498a059
PDF
Book Reviews

pp 1060 - 1062; DOI:
10.1021/ja00498a600
PDF

Issue 5


The transition from phase waves to trigger waves in a model of the Zhabotinskii reaction
Edward J. Reusser and Richard J. Field
pp 1063 - 1071; DOI:
10.1021/ja00499a001
PDF
Effects of electron correlation on the geometrical structure of cyanomethylene
Melvin E. Zandler, John D. Goddard, and Henry F. Schaefer
pp 1072 - 1076; DOI:
10.1021/ja00499a002
PDF
Determination and analysis of the formic acid conformational hypersurface
Michael R. Peterson and Imre G. Csizmadia
pp 1076 - 1079; DOI:
10.1021/ja00499a003
PDF
Heteronuclear two-dimensional NMR as a conformational probe of cellular phosphates
Philip H. Bolton and Geoffrey Bodenhausen
pp 1080 - 1084; DOI:
10.1021/ja00499a004
PDF
Heat of formation of the 2-norbornyl cation in the gas phase
P. P. S. Saluja and P. Kebarle
pp 1084 - 1087; DOI:
10.1021/ja00499a005
PDF
Semiempirical molecular orbital calculation of atom-pair interactions in a molecule
Alice Chung-Phillips
pp 1087 - 1094; DOI:
10.1021/ja00499a006
PDF
Ab initio SCF calculations on the photochemical behavior of the three-membered rings. 3. Oxirane: ring opening
B. Bigot, A. Sevin, and A. Devaquet
pp 1095 - 1100; DOI:
10.1021/ja00499a007
PDF
Ab initio SCF calculations on the photochemical behavior of the three-membered rings. 4. Oxirane: fragmentation
B. Bigot, A. Sevin, and A. Devaquet
pp 1101 - 1106; DOI:
10.1021/ja00499a008
PDF
The mechanism for the oxidation of imines (Schiff bases) with peroxy acids. An ab initio molecular orbital study
Andrej Azman, Joze Koller, and Bozo Plesnicar
pp 1107 - 1109; DOI:
10.1021/ja00499a009
PDF
The 147-nm photolysis of monosilane
G. G. A. Perkins, E. R. Austin, and F. W. Lampe
pp 1109 - 1115; DOI:
10.1021/ja00499a010
PDF
Stereochemistry and stereochemical rearrangements of eight-coordinate tetrakis chelates. 1. Group 4B .beta.-diketonates
Robert C. Fay and John K. Howie
pp 1115 - 1122; DOI:
10.1021/ja00499a011
PDF
Cobalt metallocycles. 6. Preparation and structure of cobaltacyclopentene complexes and their reactions with olefins and acetylenes
Yasuo Wakatsuki, Katsuyuki Aoki, and Hiroshi Yamazaki
pp 1123 - 1130; DOI:
10.1021/ja00499a012
PDF
A survey of ligand effects upon the reaction entropies of some transition metal redox couples
Edmund L. Yee, Robert J. Cave, Kendall L. Guyer, Paul D. Tyma, and Michael J. Weaver
pp 1131 - 1137; DOI:
10.1021/ja00499a013
PDF
Transition metal cyanocarbon derivatives. 7. Formation of tricyanoethylene metal complexes from the reaction of a 1-chloro-2,2-dicyanovinylmolybdenum derivative with tert-butyl isocyanide
R. B. King, M. S. Saran, D. P. McDonald, and S. P. Diefenbach
pp 1138 - 1142; DOI:
10.1021/ja00499a014
PDF
Structural properties of a nearly stoichiometric diammineplatinum(II) complex with inosine 5'-monophosphate
Thomas J. Kistenmacher, Chian C. Chiang, Purush Chalilpoyil, and Luigi G. Marzilli
pp 1143 - 1148; DOI:
10.1021/ja00499a015
PDF
Rearrangements of organometallic compounds. 15. Structural factors in the facile carbomagnesiation of isolated carbon-carbon double bonds
John J. Eisch and Joseph H. Merkley
pp 1148 - 1155; DOI:
10.1021/ja00499a016
PDF
Sulfuranes. 38. Evidence from x-ray crystallography for the diequatorial disposition of a five-membered ring in a sulfurane
Edmund F. Perozzi and J. C. Martin
pp 1155 - 1159; DOI:
10.1021/ja00499a017
PDF
Desulfurization of epidithiodioxopiperazines. A mechanistic and chiroptical study
Jacobus D. M. Herscheid, Marian W. Tijhuis, Jan H. Noordik, and Harry C. J. Ottenheijm
pp 1159 - 1162; DOI:
10.1021/ja00499a018
PDF
Electrochemical reduction and intramolecular cyclization of 6-iodo-1-phenyl-1-hexyne and 6-bromo-1-phenyl-1-hexyne at mercury cathodes in dimethylformamide
Brian C. Willett, W. Michael Moore, Abdolreza Salajegheh, and Dennis G. Peters
pp 1162 - 1167; DOI:
10.1021/ja00499a019
PDF
Polar radicals. 12. A reinvestigation and reappraisal of the apparent polar effects observed during the reactions of tert-butyl radicals. Decomposition of 2,2'-azoisobutane and tert-butyl perpivalate in substituted toluenes
Dennis D. Tanner, Peter W. Samal, Tomoki C. S. Ruo, and Roberto Henriquez
pp 1168 - 1175; DOI:
10.1021/ja00499a020
PDF
Orientation in base-promoted 1,2-elimination reactions. Influence of .beta.-alkyl and leaving groups upon the threshold for base steric effects
Richard A. Bartsch, Rita A. Read, David T. Larsen, Debra K. Roberts, K. Jane Scott, and Bong Rae Cho
pp 1176 - 1181; DOI:
10.1021/ja00499a021
PDF
A study of substituent effects on nitrogen elimination from azo compounds via cationic intermediates. Acetolysis of (5-aryl-3,5-dimethyl-1-pyrazolin-3-yl)methyl trifluoromethanesulfonates
Evan L. Allred, Brian K. Stevenson, and Teh-Chang Chou
pp 1181 - 1187; DOI:
10.1021/ja00499a022
PDF
Infrared laser induced organic reactions. 2. Laser vs. thermal inducement of unimolecular and hydrogen bromide catalyzed bimolecular dehydration of alcohols
Wayne C. Danen
pp 1187 - 1190; DOI:
10.1021/ja00499a023
PDF
Infrared spectrum of the intramolecular hydrogen-bonded chloroform anion Cl--HCCl2 in solid argon at 15 K
Lester Andrews and Frank T. Prochaska
pp 1190 - 1196; DOI:
10.1021/ja00499a024
PDF
Cyclization by radical displacement on ester groups. Conversion of acetals to lactones by radical abstraction with stereoelectronic control of bond scission
Carolyn M. Rynard, Chacko Thankachan, and Thomas T. Tidwell
pp 1196 - 1201; DOI:
10.1021/ja00499a025
PDF
Intramolecular general acid catalysis in the hydrolysis of acetals with aliphatic alcohol leaving groups
Thomas H. Fife and Theodore J. Przystas
pp 1202 - 1210; DOI:
10.1021/ja00499a026
PDF
Applications of artificial intelligence for chemical inference. 28. The configuration symmetry group and its application to stereoisomer generation, specification, and enumeration
James G. Nourse
pp 1210 - 1216; DOI:
10.1021/ja00499a027
PDF
Applications of artificial intelligence for chemical inference. 29. Exhaustive generation of stereoisomers for structure elucidation
James G. Nourse, Raymond E. Carhart, Dennis H. Smith, and Carl Djerassi
pp 1216 - 1223; DOI:
10.1021/ja00499a028
PDF
The equilibrium constant and rate constant for allyl radical recombination in the gas phase
M. Rossi, K. D. King, and D. M. Golden
pp 1223 - 1230; DOI:
10.1021/ja00499a029
PDF
Absolute rate constants for metathesis reactions of allyl and benzyl radicals with hydriodic acid (hydriodic acid-d). Heat of formation of allyl and benzyl radicals
M. Rossi and D. M. Golden
pp 1230 - 1235; DOI:
10.1021/ja00499a030
PDF
Direct measurement of absolute rates of hydrogen abstraction by tert-butoxy radicals. A flash photolysis electron spin resonance study
S. King Wong
pp 1235 - 1239; DOI:
10.1021/ja00499a031
PDF
Stabilities of isomeric halonium ions C2H4X+ (X = chlorine, bromine) by photoionization mass spectrometry and ion cyclotron resonance spectroscopy. General considerations of the relative stabilities of cyclic and acyclic isomeric onium ions
D. W. Berman, V. Anicich, and J. L. Beauchamp
pp 1239 - 1248; DOI:
10.1021/ja00499a032
PDF
Matrix laser fluorescence spectra of several fluorobenzene radical cations
V. E. Bondybey, Terry A. Miller, and J. H. English
pp 1248 - 1253; DOI:
10.1021/ja00499a033
PDF
Tests of the pseudophase model of micellar catalysis: its partial failure
Clifford A. Bunton, Laurence S. Romsted, and Gianfranco Savelli
pp 1253 - 1259; DOI:
10.1021/ja00499a034
PDF
Synthesis of anatoxin a via intramolecular cyclization of iminium salts
Hans A. Bates and Henry Rapoport
pp 1259 - 1265; DOI:
10.1021/ja00499a035
PDF
Deuterium-induced differential isotope shift carbon-13 NMR. 1. Resonance reassignments of mono- and disaccharides
Philip E. Pfeffer, Kathleen M. Valentine, and Frederick W. Parrish
pp 1265 - 1274; DOI:
10.1021/ja00499a036
PDF
Crispatone, a metabolite of the opisthobranch mollusc Tridachia crispata
Chris Ireland, D. John Faulkner, Janet S. Finer, and Jon Clardy
pp 1275 - 1276; DOI:
10.1021/ja00499a037
PDF
Synthesis of dl-7,8-epialantolactone. A tandem SN2' dehydrobromination-organocuprate addition exemplified
Arthur G. Schultz, Jollie D. Godfrey, E. V. Arnold, and Jon Clardy
pp 1276 - 1277; DOI:
10.1021/ja00499a038
PDF
Kinetic isotope effects in the mechanisms of thermal allylic rearrangements
Harold Kwart and David A. Benko
pp 1277 - 1279; DOI:
10.1021/ja00499a039
PDF
Biomimetic polyene cyclizations. Participation of the phenylacetylenic group as a terminator and the formation of C/D cis steroidal products
William S. Johnson, Leslie R. Hughes, James A. Kloek, Tony Niem, and Ashok Shenvi
pp 1279 - 1281; DOI:
10.1021/ja00499a040
PDF
Biomimetic polyene cyclizations. A comparison of the phenylacetylenic and styryl terminators in influencing the stereoselectivity of processes leading to steroidal products
William S. Johnson, Leslie R. Hughes, and Janet L. Carlson
pp 1281 - 1282; DOI:
10.1021/ja00499a041
PDF
Epoxidation of olefins with carbonyl oxides
T. A. Hinrichs, V. Ramachandran, and R. W. Murray
pp 1282 - 1284; DOI:
10.1021/ja00499a042
PDF
A stereocontrolled total synthesis of (.+-.)-hirsutic acid C
Barry M. Trost, Charles D. Shuey, and Frank DiNinno
pp 1284 - 1285; DOI:
10.1021/ja00499a043
PDF
Stereoselective energy transfer induced by circularly polarized light
Chieu D. Tran and Janos H. Fendler
pp 1285 - 1288; DOI:
10.1021/ja00499a044
PDF
Regiochemistry of the addition of hydrochloric acid-d to trans-1,3-pentadiene
J. Eric Nordlander, Philip O. Owuor, and Jerome E. Haky
pp 1288 - 1289; DOI:
10.1021/ja00499a045
PDF
Carbon-13 NMR assignment of the side-chain methyls of C27 steroids
P. Joseph-Nathan, G. Mejia, and D. Abramo-Bruno
pp 1289 - 1291; DOI:
10.1021/ja00499a046
PDF
The unlikelihood of an electron-transfer (Haber-Weiss) reaction between superoxide and peroxides
Morton J. Gibian and Timothy Ungermann
pp 1291 - 1293; DOI:
10.1021/ja00499a047
PDF
Polar substituent effects in triplet quenching. Excitation transfer and cycloaddition
Richard A. Caldwell, D. Creed, and T. S. Maw
pp 1293 - 1295; DOI:
10.1021/ja00499a048
PDF
The nitroalkane anomaly - solvent dependence
J. R. Keeffe, J. Morey, C. A. Palmer, and J. C. Lee
pp 1295 - 1297; DOI:
10.1021/ja00499a049
PDF
Excited-state photochemistry in the tris(2,2'-bipyridine)ruthenium(II)-sulfite system
Carol Creutz, Norman Sutin, and Bruce S. Brunschwig
pp 1297 - 1298; DOI:
10.1021/ja00499a050
PDF
Homogeneous catalysis of the photoreduction of water by visible light. Mediation by a tris(2,2'-bipyridine)ruthenium(II)-cobalt(II) macrocycle system
Gilbert M. Brown, Bruce S. Brunschwig, Carol Creutz, John F. Endicott, and Norman Sutin
pp 1298 - 1300; DOI:
10.1021/ja00499a051
PDF
Thermolysis of anthracene endoperoxides. Concerted vs. diradical mechanisms. Microscopic reversibility in endothermic chemiluminescent reactions
Nicholas J. Turro, Ming-Fea Chow, and Jean Rigaudy
pp 1300 - 1302; DOI:
10.1021/ja00499a052
PDF
Nucleophilic substitution at sulfur. Kinetic evidence for inversion of configuration at sulfinyl sulfur in acid-catalyzed transesterification of sulfinates
Marian Mikolajczyk, Jozef Drabowicz, and Henryka Slebocka-Tilk
pp 1302 - 1303; DOI:
10.1021/ja00499a053
PDF
A novel rearrangement in the reaction of carbon atoms with furan
Scott F. Dyer and Philip B. Shevlin
pp 1303 - 1304; DOI:
10.1021/ja00499a054
PDF
Ferricenyl(III) tris(ferrocenyl (II)borate. Synthesis, Electrochemistry, and Molecular Structure of an Unusual Mixed-Valence Zwitterion
Dwaine O. Cowan, Paul Shu, Frederick L. Hedberg, Miriam Rossi, and Thomas J. Kistenmacher
pp 1304 - 1306; DOI:
10.1021/ja00499a600
PDF
Hydrogenation of small molecules by transition metal cluster hydrides. Reaction of decacarbonyldihydrotriosmium with carbon disulfide
Richard D. Adams and Nancy M. Golembeski
pp 1306 - 1307; DOI:
10.1021/ja00499a055
PDF
Selenium stabilized carbanions. Ylide formation during alkylation of selenium and sulfur substituted enolates
Hans J. Reich and Martin L. Cohen
pp 1307 - 1308; DOI:
10.1021/ja00499a056
PDF
Electrochemical oxidation of strained hydrocarbons
Paul G. Gassman and Ryohei Yamaguchi
pp 1308 - 1310; DOI:
10.1021/ja00499a057
PDF
Carbon-carbon bond formation via directed 2-azonia-[3,3]-sigmatropic rearrangements. A new pyrrolidine synthesis
Larry E. Overman and Masa-Aki Kakimoto
pp 1310 - 1312; DOI:
10.1021/ja00499a058
PDF
Nucleophilic substitution in organomercury halides by a free-radical chain process (SRN1)
Glen A. Russell, J. Hershberger, and Karen Owens
pp 1312 - 1313; DOI:
10.1021/ja00499a059
PDF
Reductive decyclization of organosulfur compounds. Preparation and crystal structure of .mu.,.mu.'-dithiolato-methanehexacarbonyldiiron(I)
Alan Shaver, Paul J. Fitzpatrick, Kosta Steliou, and Ian S. Butler
pp 1313 - 1315; DOI:
10.1021/ja00499a060
PDF
A stereocontrolled synthesis of the (.+-.) Djerassi-Prelog lactonic acid
Gilbert Stork and Vijay Nair
pp 1315 - 1316; DOI:
10.1021/ja00499a061
PDF
1,4-Addition reactions of lithium enolates to .alpha.,.beta.-unsaturated thioamides
Yoshinao Tamaru, Toshiro Harada, and Zenichi Yoshida
pp 1316 - 1318; DOI:
10.1021/ja00499a062
PDF
Stereoselective synthesis of (.+-.)-dihydroantirhine
Jacqueline Ficini, Andre Guingant, and Jean D'Angelo
pp 1318 - 1319; DOI:
10.1021/ja00499a063
PDF
Benzenesulfonylnitrile oxide: a useful intermediate for the syn-cyanohydroxylation of alkenes
Peter A. Wade and Harry R. Hinney
pp 1319 - 1320; DOI:
10.1021/ja00499a064
PDF
Reactions of zirconium atoms with alkanes: oxidative additions to carbon-hydrogen and carbon-carbon bonds
Robert J. Remick, Tuula A. Asunta, and Philip S. Skell
pp 1320 - 1322; DOI:
10.1021/ja00499a065
PDF
Pentacoordinate intermediates in displacement at sterically hindered phosphorus. A correction
Jubrail Rahil, Robert D. Cook, and Paul Haake
pp 1322 - 1323; DOI:
10.1021/ja00499a066
PDF
Fragmentation reaction of ylide. 6. A new type of fragmentation reaction of aziridinones
Yoshiteru Hata and Masamichi Watanabe
pp 1323 - 1324; DOI:
10.1021/ja00499a067
PDF
Chemical titration of thermally generated triplets
Waldemar Adam, Chen-Chih Cheng, Omar Cueto, Katsumasa Sakanishi, and Klaus Zinner
pp 1324 - 1325; DOI:
10.1021/ja00499a068
PDF
Secondary deuterium kinetic isotope effects in the thermal stereomutations of 1-cyano-2-phenylcyclopropanes
John E. Baldwin and Charles G. Carter
pp 1325 - 1326; DOI:
10.1021/ja00499a069
PDF
Reduction of nitrate ion by (bpy)2pyRu(OH2)2+
Bruce A. Moyer and Thomas J. Meyer
pp 1326 - 1328; DOI:
10.1021/ja00499a070
PDF
A total synthesis of aphidicolin
Barry M. Trost, Yoshio Nishimura, and Kagetoshi Yamamoto
pp 1328 - 1330; DOI:
10.1021/ja00499a071
PDF
Stereospecific total synthesis of aphidicolin
John E. McMurry, Alex Andrus, Gary M. Ksander, John H. Musser, and Mark A. Johnson
pp 1330 - 1332; DOI:
10.1021/ja00499a072
PDF
Cleavage of alkanes by transition metal ions in the gas phase
J. Allison, R. B. Freas, and D. P. Ridge
pp 1332 - 1333; DOI:
10.1021/ja00499a073
PDF
Transport processes in organic chemistry. 5. Multicarrier transport: coupled transport of electrons and metal cations mediated by an electron carrier and a selective cation carrier
John J. Grimaldi and Jean-Marie Lehn
pp 1333 - 1334; DOI:
10.1021/ja00499a074
PDF
Synthesis of new, noncyclic ionophores exhibiting efficient calcium(2+) ion transport
Wendell Wierenga, Bruce R. Evans, and John A. Woltersom
pp 1334 - 1336; DOI:
10.1021/ja00499a075
PDF
Mechanism of Friedel-Crafts acylation and sulfonylation reactions
Franklin P. DeHaan, William D. Covey, Gerald L. Delker, Nancy J. Baker, Juli F. Feigon, Kurt D. Miller, and Eric D. Stelter
pp 1336 - 1337; DOI:
10.1021/ja00499a076
PDF
"Anomalous" selectivities in electrophilic aromatic substitutions
Cielo Santiago, K. N. Houk, and Charles L. Perrin
pp 1337 - 1340; DOI:
10.1021/ja00499a077
PDF
Influence of molecular distortions upon reactivity and stereochemistry in nucleophilic additions to acetylenes
R. W. Strozier, Pierluigi Caramella, and K. N. Houk
pp 1340 - 1343; DOI:
10.1021/ja00499a078
PDF
Vinylic cations from solvolysis. 27. Solvolysis of an optically active vinyl bromide
Zvi Rappoport and Jeremy Greenblatt
pp 1343 - 1344; DOI:
10.1021/ja00499a079
PDF
Reported selectivity of olefin bromination
R. M. Dessau
pp 1344 - 1345; DOI:
10.1021/ja00499a080
PDF
Rate-determining proton transfer to ketenimines
A. F. Hegarty and D. G. McCarthy
pp 1345 - 1346; DOI:
10.1021/ja00499a081
PDF
Nonvertical excitation transfer. Activation parameters for endothermic triplet energy transfer to the stilbenes
Jack Saltiel, James L. Charlton, and Warren B. Mueller
pp 1347 - 1348; DOI:
10.1021/ja00499a082
PDF
Photochemically generated silicon-carbon double-bonded intermediates. 9. Synthesis, reactions, and molecular structure of a 1,2-disilacyclobutane
Mitsuo Ishikawa, Takamasa Fuchikami, Makoto Kumada, Taiichi Higuchi, and Setsuro Miyamoto
pp 1348 - 1350; DOI:
10.1021/ja00499a083
PDF
Lanthanum-139 nuclear magnetic resonance chemical shifts
Peter L. Rinaldi, Shakil A. Khan, Gregory R. Choppin, and George C. Levy
pp 1350 - 1351; DOI:
10.1021/ja00499a084
PDF
High resolution carbon-13 NMR studies of chemical exchange processes in the solid state using magic angle spinning
C. A. Fyfe, J. R. Lyerla, and C. S. Yannoni
pp 1351 - 1353; DOI:
10.1021/ja00499a085
PDF
Synthesis of trans-3,4-dihydroxy-3,4-dihydro-7,12-dimethylbenz[a]anthracene, a highly carcinogenic metabolite of 7,12-dimethylbenz[a]anthracene
K. B. Sukumaran and Ronald G. Harvey
pp 1353 - 1354; DOI:
10.1021/ja00499a086
PDF
Stereochemistry of pantoate biosynthesis from 2-ketoisovalerate
D. John Aberhart
pp 1354 - 1355; DOI:
10.1021/ja00499a087
PDF
Vibrational spectroscopy of the electronically excited state: pulse radiolysis/time-resolved resonance Raman study of triplet .beta.-carotene
Richard F. Dallinger, Joseph J. Guanci, William H. Woodruff, and Michael A. J. Rodgers
pp 1355 - 1357; DOI:
10.1021/ja00499a088
PDF
Book Reviews

pp 1357 - 1360; DOI:
10.1021/ja00499a601
PDF

Issue 6


Gas-phase basicities of amides and imidates. Estimation of protomeric equilibrium constants by the basicity method in the gas phase
Donald H. Aue, L. D. Betowski, William R. Davidson, Michael T. Bowers, Peter Beak, and Jaekeun Lee
pp 1361 - 1368; DOI:
10.1021/ja00500a001
PDF
Rearrangements among gas-phase ions of C8H8 isomers. A photodissociation-spectroscopic investigation
Robert C. Dunbar, Myung S. Kim, and George A. Olah
pp 1368 - 1370; DOI:
10.1021/ja00500a002
PDF
A MINDO/3 study of the bridged pyramidal C8H9 cation and its congeners
Charles W. Jefford, Jiri Mareda, Jean Claude Perlberger, and Ulrich Burger
pp 1370 - 1378; DOI:
10.1021/ja00500a003
PDF
Chemically derivatized n-type silicon photoelectrodes. Stabilization to surface corrosion in aqueous electrolyte solutions and mediation of oxidation reactions by surface-attached electroactive ferrocene reagents
Jeffrey M. Bolts, Andrew B. Bocarsly, Michael C. Palazzotto, Erick G. Walton, Nathan S. Lewis, and Mark S. Wrighton
pp 1378 - 1385; DOI:
10.1021/ja00500a004
PDF
Mechanistic studies of arene oxide and diol epoxide rearrangement and hydrolysis reactions
J. E. Ferrell and G. H. Loew
pp 1385 - 1388; DOI:
10.1021/ja00500a005
PDF
Quantum topology of molecular charge distributions. 1
R. F. W. Bader, S. G. Anderson, and A. J. Duke
pp 1389 - 1395; DOI:
10.1021/ja00500a006
PDF
Vibrational circular dichroism of spirononadiene. Fixed partial charge calculations
Timothy A. Keiderling and Philip J. Stephens
pp 1396 - 1400; DOI:
10.1021/ja00500a007
PDF
A combination of empirical force field and extended Hueckel molecular orbital calculations as a computational approach to conformational analysis
Dennis A. Dougherty and Kurt Mislow
pp 1401 - 1405; DOI:
10.1021/ja00500a008
PDF
Excited-state spectroscopy of hexacyanocobaltate(III)
L. Viaene, J. D'Olieslager, A. Ceulemans, and L. G. Vanquickenborne
pp 1405 - 1409; DOI:
10.1021/ja00500a009
PDF
Intramolecular hydrolysis of glycinamide and glycine dipeptides coordinated to cobalt(III). 2. Reactions of the cis-[Co(en)2(OH2/OH)(glyNHR)]3+/2+ ions (R = H, CH2CO2C3H7, CH2CO2-) and the effect of buffer species
C. J. Boreham, D. A. Buckingham, and F. R. Keene
pp 1409 - 1421; DOI:
10.1021/ja00500a010
PDF
Metal-metal bonding in dirhodium tetracarboxylates. Trans influence and dependence of the rhodium-rhodium bond distance upon the nature of the axial ligands
G. G. Christoph and Y. B. Koh
pp 1422 - 1434; DOI:
10.1021/ja00500a011
PDF
Solid state structure, magnetic susceptibility, and single crystal ESR properties of cis-diammineplatinum .alpha.-pyridone blue
Jacqueline K. Barton, David J. Szalda, Harold N. Rabinowitz, Joseph V. Waszczak, and Stephen J. Lippard
pp 1434 - 1441; DOI:
10.1021/ja00500a012
PDF
Methylation of platinum complexes by methylcobalamin
Y. T. Fanchiang, W. P. Ridley, and J. M. Wood
pp 1442 - 1447; DOI:
10.1021/ja00500a013
PDF
Photochemistry and spectroscopy of monosubstituted derivatives of tungsten hexacarbonyl which exhibit low-efficiency photoreactivities
R. Marc Dahlgren and Jeffrey I. Zink
pp 1448 - 1454; DOI:
10.1021/ja00500a014
PDF
Enantioface-differentiating (asymmetric) addition of alkyllithium and dialkylmagnesium to aldehydes by using (2S,2'S)-2-hydroxymethyl-1-[(1-alkylpyrrolidin-2-yl)methyl]pyrrolidines as chiral ligands
Teruaki Mukaiyama, Kenso Soai, Toshio Sato, Hisashi Shimizu, and Keisuke Suzuki
pp 1455 - 1460; DOI:
10.1021/ja00500a015
PDF
Oxyphosphorane and monomeric metaphosphate ion intermediates in phosphoryl transfer from 2,4-dinitrophenyl phosphate in aprotic and protic solvents
Fausto Ramirez and James F. Marecek
pp 1460 - 1465; DOI:
10.1021/ja00500a016
PDF
A mechanistic study of the reactions of methylallyl chlorides with silver nitrate in acetonitrile
Dennis N. Kevill and Charles R. Degenhardt
pp 1465 - 1470; DOI:
10.1021/ja00500a017
PDF
High pressure nuclear magnetic resonance kinetics. 3. Proton nuclear magnetic resonance study of the effect of temperature and pressure on the exchange of acetonitrile on nickel(II)
Kenneth E. Newman, Felix K. Meyer, and Andre E. Merbach
pp 1470 - 1476; DOI:
10.1021/ja00500a018
PDF
Hydrolysis of benzaldehyde O,S-acetals
James L. Jensen and William P. Jencks
pp 1476 - 1488; DOI:
10.1021/ja00500a019
PDF
Kinetic .alpha. secondary deuterium isotope effects for O-ethyl S-phenyl benzaldehyde acetal hydrolysis
Julio P. Ferraz and E. H. Cordes
pp 1488 - 1491; DOI:
10.1021/ja00500a020
PDF
Application of ESR spectroscopy to problems of structure and conformation. 32. Aliphatic semidiones. 38. Conversion of polymeric peroxides and hydroperoxides to 1,2- and 1,4-semidiones in basic solution
Glen A. Russell, T. Takano, and Y. Kosugi
pp 1491 - 1495; DOI:
10.1021/ja00500a021
PDF
Competition between reactive sites in the reactions of oxygen atoms and hydroxyl radicals with phenylacetylene and styrene
Thompson M. Sloane and Richard J. Brudzynski
pp 1495 - 1499; DOI:
10.1021/ja00500a022
PDF
Consideration of the mechanism of the transition metal catalyzed olefin metathesis reaction. Metathesis of cis,cis-2,8-decadiene
Robert H. Grubbs and Charles R. Hoppin
pp 1499 - 1508; DOI:
10.1021/ja00500a023
PDF
Thermal decomposition of labeled cyclohexene. A complex reaction involving a forbidden 1,2-hydrogen elimination
D. C. Tardy, R. Ireton, and A. S. Gordon
pp 1508 - 1514; DOI:
10.1021/ja00500a024
PDF
Synthesis and reactivity of coordinated imines derived from 2-keto acids
J. M. Harrowfield and A. M. Sargeson
pp 1514 - 1520; DOI:
10.1021/ja00500a025
PDF
Ring opening and closing rates for thiosugars
C. E. Grimshaw, R. L. Whistler, and W. W. Cleland
pp 1521 - 1532; DOI:
10.1021/ja00500a026
PDF
The prostaglandin endoperoxide nucleus and related bicyclic peroxides. Synthetic and spectroscopic studies
Daniel J. Coughlin, R. S. Brown, and Robert G. Salomon
pp 1533 - 1539; DOI:
10.1021/ja00500a027
PDF
Total synthesis of the indole alkaloids dl-eburnamonine and dl-vincamine
J. L. Herrmann, R. J. Cregge, J. E. Richman, G. R. Kieczykowski, S. N. Normandin, M. L. Quesada, C. L. Semmelhack, A. J. Poss, and R. H. Schlessinger
pp 1540 - 1544; DOI:
10.1021/ja00500a028
PDF
A total synthesis of racemic avenaciolide
John L. Herrmann, Mitchel H. Berger, and R. H. Schlessinger
pp 1544 - 1549; DOI:
10.1021/ja00500a029
PDF
Organic structure characterization by natural-abundance nitrogen-15 nuclear magnetic resonance spectroscopy. Rauwolfia alkaloids and model compounds
Samuel N. Y. Fanso-Free, George T. Furst, P. R. Srinivasan, Robert L. Lichter, Randall B. Nelson, Jill A. Panetta, and Gordon W. Gribble
pp 1549 - 1553; DOI:
10.1021/ja00500a030
PDF
Nucleoside 4',5'-enol acetates. Synthesis and chemistry of a unique uridine O2,4'-anhydronucleoside
Steven L. Cook and John A. Secrist
pp 1554 - 1564; DOI:
10.1021/ja00500a031
PDF
lin-Benzoadenine nucleotides. Inter- and intramolecular interactions in aqueous solutions as observed by proton magnetic resonance
Jorge R. Barrio, Fu-Tong Liu, Gene E. Keyser, Pieter Van der Lijn, and Nelson J. Leonard
pp 1564 - 1569; DOI:
10.1021/ja00500a032
PDF
Conformational study of the dipeptide arginylglutamic acid and of its complex with nucleic bases
Gerard Lancelot, Roger Mayer, and Claude Helene
pp 1569 - 1576; DOI:
10.1021/ja00500a033
PDF
Comparison of half-met and met apo hemocyanin. Ligand bridging at the binuclear copper active site
Richard S. Himmelwright, Nancy C. Eickman, and Edward I. Solomon
pp 1576 - 1586; DOI:
10.1021/ja00500a034
PDF
Selective epoxidation of eicosa-cis-5,8,11,14-tetraenoic (arachidonic) acid and eicosa-cis-8,11,14-trienoic acid
E. J. Corey, Haruki Niwa, and J. R. Falck
pp 1586 - 1587; DOI:
10.1021/ja00500a035
PDF
Proof of existence of cyclic C4H7+ ions in the dilute gas state
Fulvio Cacace and Maurizio Speranza
pp 1587 - 1589; DOI:
10.1021/ja00500a036
PDF
Neutral metal formyl complexes: generation, reactivity, and models for Fischer-Tropsch catalyst intermediates
Wilson Tam, Wai-Kwok Wong, and J. A. Gladysz
pp 1589 - 1591; DOI:
10.1021/ja00500a037
PDF
Facile syntheses of isolable organic derivatives of hypervalent sulfur, phosphorus, and silicon. Introduction of a stabilizing bidentate ligand via its dilithio derivative
Edmund F. Perozzi and J. C. Martin
pp 1591 - 1593; DOI:
10.1021/ja00500a038
PDF
Interaction of hydrogen and hydrocarbons with transition metals. Neutron diffraction evidence for an activated carbon-hydrogen bond in an electron-deficient tantalum-neopentylidene complex
A. J. Schultz, Jack M. Williams, R. R. Schrock, G. A. Rupprecht, and J. D. Fellmann
pp 1593 - 1595; DOI:
10.1021/ja00500a039
PDF
Influence of a transition metal on the regiochemistry of ring closures. An approach to medium-ring compounds
Barry M. Trost and Thomas R. Verhoeven
pp 1595 - 1597; DOI:
10.1021/ja00500a040
PDF
Competitive radiative decay and metal-metal bond cleavage from the lowest excited state of triphenyltin- and triphenylgermanium tricarbonyl(1,10-phenanthroline)rhenium
John C. Luong, Robert A. Faltynek, and Mark S. Wrighton
pp 1597 - 1598; DOI:
10.1021/ja00500a041
PDF
Regio- and stereoselective cyclopentenone annulation by means of ketone-propargyl alcohol adducts
Tamejiro Hiyama, Masaki Shinoda, and Hitosi Nozaki
pp 1599 - 1600; DOI:
10.1021/ja00500a042
PDF
Nonchair conformations in phosphorus-containing cyclohexanes. Crystal and molecular structures of cis- and trans-2-phenyl-2-oxo-5-tert-butyl-1,3,2-dithiaphosphorinanes and cis-2-phenyl-5-tert-butyl-1,3,2-dithiaphosphorinane
Robert O. Hutchins, Bruce E. Maryanoff, Mario J. Castillo, Karl D. Hargrave, and Andrew T. McPhail
pp 1600 - 1602; DOI:
10.1021/ja00500a043
PDF
X-ray and NMR studies of a cyclophosphamide-like molecule, cis-2-oxo-2-dimethylamino-3-phenyl-5-tert-butyl-1,3,2-oxazaphosphorinane. Twist conformation in both solid phase and in solution
Gurdip S. Bajwa, Wesley G. Bentrude, N. S. Pantaleo, M. Gary Newton, and J. Howard Hargis
pp 1602 - 1604; DOI:
10.1021/ja00500a044
PDF
Outer-sphere chemical activation for electron transfer in the mixed-valence solid Cs2(SbIIIxSbVxSn1-2x)Cl6
H. W. Clark and B. I. Swanson
pp 1604 - 1606; DOI:
10.1021/ja00500a045
PDF
Chemistry of transition metal-phosphine and -phosphite complexes. 1. Photochemical substitution reactions of tetrakis(triphenyl phosphite)cobalt(I) hydride
Harold L. Conder, Arlene R. Courtney, and David DeMarco
pp 1606 - 1606; DOI:
10.1021/ja00500a046
PDF
Selenium-77 NMR studies. 2. Intramolecular rearrangements of monophosphine adducts of bis(diisobutyldiselenocarbamato)platinum(II), Pt(Se2CN-iso-Bu2)2PR3(R = C2H5). An unusual intensity distribution of satellites associated with selenium-77 coupling in phosphorus-31 NMR spectrum
John P. Fackler and Wie-Hin Pan
pp 1607 - 1608; DOI:
10.1021/ja00500a047
PDF
Total synthesis of the racemate of the sesquiterpenoid marine allomone 9-isocyanopupukeanane
E. J. Corey, Mohammad Behforouz, and Masaji Ishiguro
pp 1608 - 1609; DOI:
10.1021/ja00500a048
PDF
Total synthesis of (.+-.)-9-isocyanopupukeanane
Hisashi Yamamoto and Hing L. Sham
pp 1609 - 1611; DOI:
10.1021/ja00500a049
PDF
Tandem Cope-Claisen rearrangement: a contrathermodynamic [3,3] sigmatropic sequence
Frederick E. Ziegler and John J. Piwinski
pp 1611 - 1612; DOI:
10.1021/ja00500a050
PDF
Analysis of monolayer films at the air-water interface by field desorption mass spectrometry
Woodfin V. Ligon and Steven J. Valenty
pp 1612 - 1614; DOI:
10.1021/ja00500a051
PDF
Duplex cyclodextrin
Iwao Tabushi, Yasuhisa Kuroda, and Kazuhiro Shimokawa
pp 1614 - 1615; DOI:
10.1021/ja00500a052
PDF
Bond fixation in annulenes. 5. Absolute configuration and chiroptical properties of optically active 1,2,3-trimethyl- and 1,2,3,4-tetramethylcyclooctatetraenes
John M. Gardlik, Larry K. Johnson, Leo A. Paquette, Barbara A. Solheim, James P. Springer, and Jon Clardy
pp 1615 - 1617; DOI:
10.1021/ja00500a053
PDF
Bond fixation in annulenes. 6. Equalization of ring inversion and bond shifting energetics in methyl-substituted cyclooctatetraenes. Use of buttressing effects for comparing transition-state geometries
John M. Gardlik, Leo A. Paquette, and Rolf Gleiter
pp 1617 - 1620; DOI:
10.1021/ja00500a054
PDF
Configuration and planarity of fluorescent and nonfluorescent 1,5-diazabicyclo[3.3.0]octadienediones (9,10-dioxabimanes) by x-ray crystallography
Edward M. Kosower, Joel Bernstein, Israel Goldberg, Barak Pazhenchevsky, and Ehud Goldstein
pp 1620 - 1621; DOI:
10.1021/ja00500a055
PDF
Rigidity, lipophilicity, and Henry's constant
M. Osinga
pp 1621 - 1622; DOI:
10.1021/ja00500a056
PDF
Totally synthetic heme protein models based on complexes with superstructure ligands
Wayne P. Schammel, Kristin S. B. Mertes, Gary G. Christoph, and Daryle H. Busch
pp 1622 - 1623; DOI:
10.1021/ja00500a057
PDF
Palladium(0) catalyzed reaction of 1,3-diene epoxides. A useful method for the site-specific oxygenation of 1,3-dienes
M. Suzuki, Y. Oda, and R. Noyori
pp 1623 - 1625; DOI:
10.1021/ja00500a058
PDF
New nuclear magnetic resonance methodology in biosynthetic studies of mixtures of statistically enriched carbon-13 and unlabeled precursors
Didier Gagnaire and Francois R. Taravel
pp 1625 - 1626; DOI:
10.1021/ja00500a059
PDF
Chemical properties of metallocarboxylic acids of transition metals
N. Grice, S. C. Kao, and R. Pettit
pp 1627 - 1628; DOI:
10.1021/ja00500a060
PDF
4H-Anthra[1,2-b]pyran antibiotics. Total synthesis of the methyl ether of kidamycinone
Frank M. Hauser and Richard P. Rhee
pp 1628 - 1629; DOI:
10.1021/ja00500a061
PDF
A high-field Moessbauer study of the iron sites in mixed-valent biferrocene monocation
Alan W. Rudie, Alan Davison, and R. B. Frankel
pp 1629 - 1631; DOI:
10.1021/ja00500a062
PDF
Thermally stable copper(III)- and nickel(III)-tripeptide complexes and their photochemical decomposition in acid solution
Sanford T. Kirksey, Thomas A. Neubecker, and Dale W. Margerum
pp 1631 - 1633; DOI:
10.1021/ja00500a063
PDF
Alane reduction of coordinated carbon monoxide: selective ethene production
Christopher Masters, Constance Van der Woude, and Johannes A. Van Doorn
pp 1633 - 1634; DOI:
10.1021/ja00500a064
PDF
Ligand substitution kinetics on ethylenediaminetetraacetato complexes of ruthenium(II) and ruthenium(III) covalently attached to graphite surfaces
Noboru Oyama and Fred C. Anson
pp 1634 - 1635; DOI:
10.1021/ja00500a065
PDF
Transfer of oxygen from a 4a-hydroperoxyflavin anion to a phenolate ion. A flavin-catalyzed dioxygenation reaction
Cemal Kemal and Thomas C. Bruice
pp 1635 - 1638; DOI:
10.1021/ja00500a066
PDF
Three isomers of the aluminum-acetylene system
Michael Trenary, Mark E. Casida, Bernard R. Brooks, and Henry F. Schaefer
pp 1638 - 1639; DOI:
10.1021/ja00500a067
PDF
Laser flash photolysis with NMR detection. Microsecond time-resolved CIDNP: separation of geminate and random-phase processes
G. L. Closs and R. J. Miller
pp 1639 - 1641; DOI:
10.1021/ja00500a068
PDF
Book Reviews

pp 1641 - 1644; DOI:
10.1021/ja00500a600
PDF

Issue 7


Electron nuclear double resonance from high- and low-spin ferric hemoglobins and myoglobins
C. F. Mulks, C. P. Scholes, L. C. Dickinson, and A. Lapidot
pp 1645 - 1654; DOI:
10.1021/ja00501a001
PDF
Resonance Raman and electron paramagnetic resonance studies of the quaternary structure change in carp hemoglobin. Sensitivity of these spectroscopic probes to heme strain
Diane M. Scholler and Brian M. Hoffman
pp 1655 - 1662; DOI:
10.1021/ja00501a002
PDF
Possible interpretation of long-wavelength spectral shifts in phytochrome Pr and Pfr forms
R. Pasternak and G. Wagniere
pp 1662 - 1667; DOI:
10.1021/ja00501a003
PDF
Conformations of cyclohexyl rings after electron impact
R. N. Rej, E. Bacon, and G. Eadon
pp 1668 - 1675; DOI:
10.1021/ja00501a004
PDF
Hydrogen bonding of water to onium ions. Hydration of substituted pyridinium ions and related systems
W. R. Davidson, J. Sunner, and P. Kebarle
pp 1675 - 1680; DOI:
10.1021/ja00501a005
PDF
Remote secondary deuterium kinetic isotope effects as a probe of steric strain in the solvolysis of tertiary alkyl carbinyl systems
Robert C. Badger and James L. Fry
pp 1680 - 1687; DOI:
10.1021/ja00501a006
PDF
Sources of hydrogen in the electrochemical reduction of iodobenzene in dimethylformamide solution
Ramon Alvarado de la Torre and John W. Sease
pp 1687 - 1690; DOI:
10.1021/ja00501a007
PDF
Electrochemical behavior of tetrathiafulvalene-tetracyanoquinodimethane electrodes in aqueous media
Calvin D. Jaeger and Allen J. Bard
pp 1690 - 1699; DOI:
10.1021/ja00501a008
PDF
Quantum-mechanical studies on the origin of barriers to internal rotation about single bonds
T. K. Brunck and F. Weinhold
pp 1700 - 1709; DOI:
10.1021/ja00501a009
PDF
New aromatic anions. 11. Vibrational spectra and force constants for deltate ion, C3O32-
Robert West, David Eggerding, James Perkins, Dewey Handy, and Ernesto C. Tuazon
pp 1710 - 1714; DOI:
10.1021/ja00501a010
PDF
A theoretical investigation of the structure of (Cl2F)+ and protonated ClF
Bhairav D. Joshi and Keiji Morokuma
pp 1714 - 1717; DOI:
10.1021/ja00501a011
PDF
Infrared intensities. The methyl halides. Effect of substituents on charge distributions
Kenneth B. Wiberg
pp 1718 - 1722; DOI:
10.1021/ja00501a012
PDF
Unified theory of resonance energies, ring currents, and aromatic character in the (4n + 2).pi.-electron annulenes
R. C. Haddon
pp 1722 - 1728; DOI:
10.1021/ja00501a013
PDF
Spin-orbit coupling in metal-anion systems. The colors of post-transition metal salts
T. P. Carsey and S. P. McGlynn
pp 1728 - 1733; DOI:
10.1021/ja00501a014
PDF
Cooperative binding of amine substrate molecules by chiral europium(III) shift reagents
Harry G. Brittain
pp 1733 - 1736; DOI:
10.1021/ja00501a015
PDF
Ab initio quantum mechanical calculations of the magnetic shielding tensor of phosphorus-31 of the phosphate group
F. Ribas Prado, C. Giessner-Prettre, B. Pullman, and J. P. Daudey
pp 1737 - 1742; DOI:
10.1021/ja00501a016
PDF
Chemistry of 2-naphthyl bis[bis(dimethylphosphino)ethane] hydride complexes of iron, ruthenium, and osmium. 3. Cleavage of sp2 carbon-hydrogen bonds
C. A. Tolman, S. D. Ittel, A. D. English, and J. P. Jesson
pp 1742 - 1751; DOI:
10.1021/ja00501a017
PDF
A partly staggered quadruple bond in tetrabromobis(1-diphenylphosphino-2-diphenylarsinoethane)dimolybdenum(II)
F. Albert Cotton, Phillip E. Fanwick, John W. Fitch, Howard D. Glicksman, and Richard A. Walton
pp 1752 - 1757; DOI:
10.1021/ja00501a018
PDF
cyclo-Triphosphorus and cyclo-triarsenic as ligands in "double sandwich" complexes of cobalt and nickel
Massimo Di Vaira, Stefano Midollini, and Luigi Sacconi
pp 1757 - 1763; DOI:
10.1021/ja00501a019
PDF
Core-ionization energies and the anomalous basicity of arsabenzene and phosphabenzene
A. J. Ashe, M. K. Bahl, K. D. Bomben, W. T. Chan, J. K. Gimzewski, P. G. Sitton, and T. D. Thomas
pp 1764 - 1767; DOI:
10.1021/ja00501a020
PDF
Carbon dioxide activation. Deoxygenation and disproportionation of carbon dioxide promoted by bis(cyclopentadienyl)titanium and -zirconium derivatives. A novel bonding mode of the carbonato and a trimer of the zirconyl unit
Giuseppe Fachinetti, Carlo Floriani, A. Chiesi-Villa, and Carlo Guastini
pp 1767 - 1775; DOI:
10.1021/ja00501a021
PDF
ENDOR investigation of internal dynamics in cyclopropyl-substituted galvinoxyl radicals
B. Kirste, H. Kurreck, W. Harrer, and J. Reusch
pp 1775 - 1780; DOI:
10.1021/ja00501a022
PDF
Structural effects in solvolytic reactions. 31. High exo:endo rate and product ratios in the solvolyses of the 2-methyl-, 2-phenyl-, and 2-(5'-coumaranyl)-exo-5,6-trimethylene-2-norbornyl p-nitrobenzoates
Herbert C. Brown, C. Gundu Rao, and David L. Vander Jagt
pp 1780 - 1783; DOI:
10.1021/ja00501a023
PDF
Formation of benzyl and tropylium ions from gaseous toluene and cycloheptatriene cations
Fred W. McLafferty and Frank M. Bockhoff
pp 1783 - 1786; DOI:
10.1021/ja00501a024
PDF
Loss of allyl cation configuration in cycloadditions to electron-rich conjugated dienes
D. I. Rawson, B. K. Carpenter, and H. M. R. Hoffmann
pp 1786 - 1793; DOI:
10.1021/ja00501a025
PDF
The degenerate side chain approach to the carbon analog of the Claisen rearrangement. Formation of nine-membered rings by a sterically accelerated ene reaction
Joseph B. Lambert, Dietrich M. Fabricius, and James J. Napoli
pp 1793 - 1800; DOI:
10.1021/ja00501a026
PDF
Stereochemistry of allylic rearrangements. 17. Acid-catalyzed rearrangement of exo- and endo-bicyclo[3.2.1]oct-3-en-2-ol
Harlan L. Goering and James C. Vlazny
pp 1801 - 1805; DOI:
10.1021/ja00501a027
PDF
Superacid-catalyzed transfer nitration of benzene, toluene, and mesitylene with 9-nitroanthracene and pentamethylnitrobenzene. Evidence for the reversibility of electrophilic aromatic nitration in specific cases
George A. Olah, Subhash C. Narang, Ripudaman Malhotra, and Judith A. Olah
pp 1805 - 1807; DOI:
10.1021/ja00501a028
PDF
Effect of acid concentration on the partitioning of the tetrahedral intermediate in the hydrolysis of thioacetanilide
John T. Edward and Sin Cheong Wong
pp 1807 - 1809; DOI:
10.1021/ja00501a029
PDF
Hydrogen atom transfers from thiophenols to triarylmethyl radicals. Rates, substituent effects, and tunnel effects
Thomas H. Colle and Edward S. Lewis
pp 1810 - 1814; DOI:
10.1021/ja00501a030
PDF
Evaluation of addition rates of p-chlorobenzenethiyl radical to vinyl monomers by means of flash photolysis
Osamu Ito and Minoru Matsuda
pp 1815 - 1819; DOI:
10.1021/ja00501a031
PDF
Photochemical generation of 2,3-naphthoquinodimethane derivatives. An extremely facile "forbidden" thermal reaction and evidence for a low-energy doubly excited state
Richard P. Steiner, Robert D. Miller, Harry J. Dewey, and Josef Michl
pp 1820 - 1826; DOI:
10.1021/ja00501a032
PDF
Competitive processes in retardation by mercaptans of photoreduction by alcohols
Saul G. Cohen, Anita W. Rose, Paul G. Stone, and Anne Ehret
pp 1827 - 1832; DOI:
10.1021/ja00501a033
PDF
1,2-Di(9-anthryl)ethane. Crystal and molecular structure of the photoisomer. Conformational effects in the photophysics and photochemistry
Bryan F. Anderson, James Ferguson, Masaharu Morita, and Glen B. Robertson
pp 1832 - 1840; DOI:
10.1021/ja00501a034
PDF
Molecular control of excited cross-conjugated triene rearrangements. Exploratory and mechanistic organic photochemistry
Howard E. Zimmerman and Donald R. Diehl
pp 1841 - 1857; DOI:
10.1021/ja00501a035
PDF
Regiochemical control in dihydrophenanthrene synthesis. A photochemical total synthesis of juncusol
Andrew S. Kende and Dennis P. Curran
pp 1857 - 1864; DOI:
10.1021/ja00501a036
PDF
The complexation chemistry of cyclohexaamyloses. 3. Per-O-methylcyclohexaamylose adducts with 4-biphenylcarboxylate and p-methylcinnamate anions
Robert I. Gelb, Lowell M. Schwartz, John E. Markinac, and Daniel A. Laufer
pp 1864 - 1868; DOI:
10.1021/ja00501a037
PDF
The complexation chemistry of cyclohexaamyloses. 4. Reactions of cyclohexaamylose with formic, acetic, and benzoic acids and their conjugate bases
Robert I. Gelb, Lowell M. Schwartz, Robert F. Johnson, and Daniel A. Laufer
pp 1869 - 1874; DOI:
10.1021/ja00501a038
PDF
Twisted and bent hydrazine radical cations
Stephen F. Nelsen, Carl R. Kessel, and Howard N. Brace
pp 1874 - 1875; DOI:
10.1021/ja00501a039
PDF
Anomalous Broensted behavior of the proton-transfer equilibrium and rate constants for tetraalkylhydrazines and salicylic acid
Stephen F. Nelsen, Patrick J. Kinlen, and Dennis H. Evans
pp 1875 - 1877; DOI:
10.1021/ja00501a040
PDF
1,2 Shift of phenyl from oxygen to carbon in a free radical
Clair J. Collins, W. Howard Roark, Vernon F. Raaen, and Ben M. Benjamin
pp 1877 - 1878; DOI:
10.1021/ja00501a041
PDF
The nonclassical brexyl cation. A reassessment
Clair J. Collins
pp 1878 - 1880; DOI:
10.1021/ja00501a042
PDF
Ligand dynamics of nitrosyl(.eta.3-allyl)bis(triphenylphosphine)iridium(1+). A facile linear-bent nitrosyl equilibrium
Michael W. Schoonover, Edgar C. Baker, and Richard Eisenberg
pp 1880 - 1882; DOI:
10.1021/ja00501a043
PDF
Use of deuteron NMR and mass spectrometry for the investigation of the vitamin D3-previtamin D3 equilibrium
Mordechai Sheves, Elisha Berman, Yehuda Mazur, and Zeev V. I. Zaretskii
pp 1882 - 1883; DOI:
10.1021/ja00501a044
PDF
A structural model for the photosynthetic reaction center
Steven G. Boxer and Rodney R. Bucks
pp 1883 - 1885; DOI:
10.1021/ja00501a045
PDF
Ease of base-catalyzed epimerization of N-methylated peptides and diketopiperazines
Peter Gund and Daniel F. Veber
pp 1885 - 1887; DOI:
10.1021/ja00501a046
PDF
Conformations of cyclododecyne. Evidence from dynamic nuclear magnetic resonance spectroscopy and iterative force-field calculations
Frank A. L. Anet and Tarik N. Rawdah
pp 1887 - 1888; DOI:
10.1021/ja00501a047
PDF
Carbon-13 NMR studies of marine natural products. 1. Use of the SESFORD technique in the total carbon-13 NMR assignment of crassin acetate
Gary E. Martin, James A. Matson, James C. Turley, and Alfred J. Weinheimer
pp 1888 - 1890; DOI:
10.1021/ja00501a048
PDF
Reduction of 1,3-dimethyl-5-(p-nitrophenylimino)barbituric acid by thiols. A high-velocity flavin model reaction with an isolable intermediate
J. M. Sayer, P. Conlon, J. Hupp, J. Fancher, R. Belanger, and E. J. White
pp 1890 - 1893; DOI:
10.1021/ja00501a049
PDF
Desulfurizative stannylation of propargylic or allylic sulfides via an SH' process
Y. Ueno and M. Okawara
pp 1893 - 1894; DOI:
10.1021/ja00501a050
PDF
Radical ions in photochemistry. 7. Configurational isomerization of alkenes induced by irradiation of charge-transfer complexes
Donald R. Arnold and Po Cheong Wong
pp 1894 - 1895; DOI:
10.1021/ja00501a051
PDF
Concerning the diene-induced photodechlorination of chloroaromatics
William K. Smothers, Kirk S. Schanze, and Jack Saltiel
pp 1895 - 1896; DOI:
10.1021/ja00501a052
PDF
Aggregation in strong acid. A micelle of carbonium ions
F. M. Menger and J. M. Jerkunica
pp 1896 - 1898; DOI:
10.1021/ja00501a053
PDF
Photosensitized isomerization of electron donor and acceptor styrenes. Recombination of radical-ion pairs in the singlet and triplet states
Heinz D. Roth and Marcia L. Manion Schilling
pp 1898 - 1900; DOI:
10.1021/ja00501a054
PDF
A rate sequence for SE2 retention with large steric and large electronic effects
Lawrence M. Sayre and Frederick R. Jensen
pp 1900 - 1901; DOI:
10.1021/ja00501a055
PDF
Photochemical formation of trans-1-phenylcyclohexene. Chemical proof of structure
William G. Dauben, Herman C. H. A. Van Riel, Christian Hauw, Francoise Leroy, Jacques Joussot-Dubien, and Roland Bonneau
pp 1901 - 1903; DOI:
10.1021/ja00501a056
PDF
Electronic spectroscopy of trans-styrylpyridines and their conjugate acids
Allan R. Gregory, Willem Siebrand, and Digby F. Williams
pp 1903 - 1904; DOI:
10.1021/ja00501a057
PDF
Electron-transfer photochemistry of di-tert-butyl nitroxide
David Richard Anderson, Joseph S. Keute, Harold L. Chapel, and Tad H. Koch
pp 1904 - 1906; DOI:
10.1021/ja00501a058
PDF
Aluminum chloride catalyzed reactions of methyl chloropropiolate with unactivated alkenes
Barry B. Snider and David M. Roush
pp 1906 - 1907; DOI:
10.1021/ja00501a059
PDF
Additions and Corrections - Stereochemical Studies of Isoprenoid Biosynthesis of Fomannosin from [1,2-13C2]Acetate
David E. Cane, and Robert B. Nachbar
pp 1908 - 1908; DOI:
10.1021/ja00501a600
PDF
Additions and Corrections - Neutral Products from Deprotonation of Tertiary Cations in the Gas Phase
William J. Marinelli, and Thomas Hellman Morton
pp 1908 - 1908; DOI:
10.1021/ja00501a601
PDF
Additions and Corrections - Novel Binuclear Cationic Complexes of Rhodium(I) and Iridium(I)
Martin Cowie, Joel T. Mague, and Alan R. Sanger
pp 1908 - 1908; DOI:
10.1021/ja00501a602
PDF
Additions and Corrections - pσpσ Interactions. 2. π Face Bonding in Cyclobutadiene
Kenney B. Lipkowitz
pp 1908 - 1908; DOI:
10.1021/ja00501a603
PDF
Additions and Corrections - Asymmetric Reductions of Carbocations by Chiral Organosilicon Hydrides. The Stereochemical Nature of the Carbocation Captured
James L. Fry, and Merwyn G. Adlington
pp 1908 - 1908; DOI:
10.1021/ja00501a604
PDF
Additions and Corrections - Characterization and Molecular Structure of [(PPh3)-RhC2B9H11]2, a Phosphinorhodacarborane Dimer Containing Rh-H-B Bridges
R. T. Baker, R. E. King III, C. Knobler, C. A. O'Con, and M. F. Hawthorne
pp 1908 - 1908; DOI:
10.1021/ja00501a605
PDF
Additions and Corrections - Ipso Nitration. Preparation of 4-Methyl-4-nitrocyclohexadienols and Detection of Intramolecular Hydrogen Migration (NIH Shift) upon Solvolytic Rearomatization
K. S. Feldman, Ann McDermott, and P. C. Myhre
pp 1908 - 1908; DOI:
10.1021/ja00501a606
PDF
Additions and Corrections - A Stereocontrolled Total Synthesis of (±)-Hirsutic Acid C
Barry M. Trost, Charles D. Shuey, and Frank DiNinno, Jr.
pp 1908 - 1908; DOI:
10.1021/ja00501a607
PDF
Additions and Corrections - A Total Synthesis of Aphidicolin
Barry M. Trost, Yoshio Nishimura, and Kagetoshi Yamamoto
pp 1908 - 1908; DOI:
10.1021/ja00501a608
PDF
Book Reviews

pp 1909 - 1912; DOI:
10.1021/ja00501a609
PDF

Issue 8


Solvation. A molecular dynamics study of a dipeptide in water
Peter J. Rossky and Martin Karplus
pp 1913 - 1937; DOI:
10.1021/ja00502a001
PDF
Solution stereochemistry of cyclophosphamide and rigid model analogs
D. W. White, D. E. Gibbs, and J. G. Verkade
pp 1937 - 1942; DOI:
10.1021/ja00502a002
PDF
NMR spectroscopic studies on kinetics and thermodynamics of reversible dissociation reactions. 6. Ionization of tropylium azide in liquid sulfur dioxide and selective migration of the azide ligand in less polar solvents
Martin Feigel, Horst Kessler, Dieter Leibfritz, and Axel Walter
pp 1943 - 1950; DOI:
10.1021/ja00502a003
PDF
Secondary ion mass spectrometry of molecular solids. Cluster formation during ion bombardment of frozen water, benzene, and cyclohexane
Gerald M. Lancaster, Fumihiro Honda, Yasuo Fukuda, and J. W. Rabalais
pp 1951 - 1958; DOI:
10.1021/ja00502a004
PDF
Enthalpies of interaction of aliphatic ketones with polar and nonpolar solvents
P. P. S. Saluja, L. A. Peacock, and R. Fuchs
pp 1958 - 1962; DOI:
10.1021/ja00502a005
PDF
Structures and energies of cumulene carbenes
Clifford E. Dykstra, Craig A. Parsons, and Caren L. Oates
pp 1962 - 1965; DOI:
10.1021/ja00502a006
PDF
An amplified sector rule for electric dipole-allowed transitions
Oscar E. Weigang
pp 1965 - 1975; DOI:
10.1021/ja00502a007
PDF
Vibrational analysis by electron paramagnetic resonance spectroscopy. The isopropyl radical
D. Griller and K. F. Preston
pp 1975 - 1979; DOI:
10.1021/ja00502a008
PDF
The inertial contribution to vibrational optical activity in methyl torsion modes
L. D. Barron and A. D. Buckingham
pp 1979 - 1987; DOI:
10.1021/ja00502a009
PDF
Reactivity of 1,3-dipoles in aqueous solution. 3. Theoretical study on the reactions of 1,3-dipoles with nucleophiles. The fulminic acid-hydroxide ion system
G. Leroy, M. T. Nguyen, M. Sana, K. J. Dignam, and A. F. Hegarty
pp 1988 - 1994; DOI:
10.1021/ja00502a010
PDF
Theoretical studies of the oxy anionic substituent effect
Michael L. Steigerwald, William A. Goddard, and David A. Evans
pp 1994 - 1997; DOI:
10.1021/ja00502a011
PDF
Application of ab initio molecular orbital calculations to the structural moieties of carbohydrates. 5. The geometry of the hydrogen bonds
M. D. Newton, G. A. Jeffrey, and Shozo Takagi
pp 1997 - 2002; DOI:
10.1021/ja00502a012
PDF
Investigation of the basis of the valence shell electron pair repulsion model by ab initio calculation of geometry variations in a series of tetrahedral and related molecules
Ann Schmiedekamp, D. W. J. Cruickshank, Steen Skaarup, Peter Pulay, Istvan Hargittai, and James E. Boggs
pp 2002 - 2010; DOI:
10.1021/ja00502a013
PDF
Quantum and statistical mechanical studies of liquids. 3. Deriving intermolecular potential functions for the water dimer from ab initio calculations
William L. Jorgensen
pp 2011 - 2016; DOI:
10.1021/ja00502a014
PDF
Minimal basis set description of the structure and properties of liquid water
William L. Jorgensen
pp 2016 - 2021; DOI:
10.1021/ja00502a015
PDF
Energy transfer from triplet aromatic hydrocarbons to terbium(3+) and europium(3+) in aqueous micellar solutions
M. Almgren, F. Grieser, and J. K. Thomas
pp 2021 - 2026; DOI:
10.1021/ja00502a016
PDF
Activation of water molecule. 2. Generation of strong hydroxo bases by the reaction of water with platinum(0) phosphine complexes and the applications as catalysts for hydrogen-deuterium exchange and hydration reactions
Toshikatsu Yoshida, Tadao Matsuda, Tamon Okano, Tetsumi Kitani, and Sei Otsuka
pp 2027 - 2038; DOI:
10.1021/ja00502a017
PDF
Electron-transfer reactions of metallocenes. Influence of metal oxidation state on structure and reactivity
John D. L. Holloway and William E. Geiger
pp 2038 - 2044; DOI:
10.1021/ja00502a018
PDF
Multiple emission from sulfur complexes of rhodium(III) and iridium(III)
James T. Merrill and M. Keith DeArmond
pp 2045 - 2055; DOI:
10.1021/ja00502a019
PDF
Synthesis and cyclization reactions of alkynyl (.eta.5-cyclopentadienyltricarbonylmolybdenum and -tungsten) complexes
Patricia L. Watson and Robert G. Bergman
pp 2055 - 2062; DOI:
10.1021/ja00502a020
PDF
A bisphenylnitrene complex of molybdenum with a bent nitrene ligand. Preparation and structure of cis-bis(phenylnitrene)bis(diethyldithiocarbamato)molybdenum
Barry L. Haymore, Eric A. Maatta, and R. A. D. Wentworth
pp 2063 - 2068; DOI:
10.1021/ja00502a021
PDF
Experimental determination of the relative rates of rotation, cleavage, closure, and 1,5-hydrogen shift for 3-methyl-1,4-pentanediyl. Evidence for 1,4 biradicals as common intermediates from different precursors, 3,4-(and 3,6-)dimethyl-3,4,5,6-tetrahydropyridazines and 1,2-dimethylcyclobutanes
Peter B. Dervan, Tadao Uyehara, and Donald S. Santilli
pp 2069 - 2075; DOI:
10.1021/ja00502a022
PDF
Stereochemical tests of cyclic 1,1-dialkyldiazene fragmentation reactions. Thermal decomposition of N-(cis-(and trans-)2,3-(and 2,5-)dimethylpyrrolidine)nitrenes
Peter B. Dervan and Tadao Uyehara
pp 2076 - 2082; DOI:
10.1021/ja00502a023
PDF
Electrocyclic ring opening of the cyclobutene radical cation
Michael L. Gross and David H. Russell
pp 2082 - 2086; DOI:
10.1021/ja00502a024
PDF
Decomposition of the 1,3-butadiene radical cation on the microsecond to picosecond time scale
D. H. Russell, M. L. Gross, J. Van der Greef, and N. M. M. Nibbering
pp 2086 - 2090; DOI:
10.1021/ja00502a025
PDF
Radical and ionic reaction pathways in the thermal decomposition of diacyl peroxides
K. Grant Taylor, C. K. Govindan, and Milton S. Kaelin
pp 2091 - 2099; DOI:
10.1021/ja00502a026
PDF
Dominant double rotation in the thermally induced 1,2,4-trimethylspiropentane geometric isomerization
Joseph J. Gajewski, Robert J. Weber, and Ming Jing Chang
pp 2100 - 2107; DOI:
10.1021/ja00502a027
PDF
Syn stereospecificity in the SN2' reaction of an acyclic allylic chloride with secondary amines
Ronald M. Magid and O. Stanley Fruchey
pp 2107 - 2112; DOI:
10.1021/ja00502a028
PDF
Ketyls of cyclic .alpha.,.beta.-unsaturated ketones. 2. Formation of radical anions by electron transfer using trimethylsilylsodium or dimethyl sulfoxide-potassium tert-butoxide
Glen A. Russell, V. Malatesta, T. Morita, C. Osuch, R. L. Blankespoor, Kathleen D. Trahanovsky, and E. Goettert
pp 2112 - 2116; DOI:
10.1021/ja00502a029
PDF
Regiocontrolled anodic cyanation of nitrogen heterocycles. Pyrroles and indoles
Kunihisa Yoshida
pp 2116 - 2121; DOI:
10.1021/ja00502a030
PDF
Syntheses, properties, and photoelectron spectra of substituted and layered [2.2](2,6)pyridinoparacyclophanes
I. D. Reingold, W. Schmidt, and V. Boekelheide
pp 2121 - 2128; DOI:
10.1021/ja00502a031
PDF
A study of the synthesis and properties of [2.2.2.2](1,2,4,5)cyclophane
Richard Gray and V. Boekelheide
pp 2128 - 2136; DOI:
10.1021/ja00502a032
PDF
2,2-Dimethylisoindene and 5,5-dimethylbenzobicyclo[2.1.0]pent-2-ene
William R. Dolbier, Kazumasa Matsui, Harry J. Dewey, David V. Horak, and Josef Michl
pp 2136 - 2139; DOI:
10.1021/ja00502a033
PDF
Synthesis of cyclopropane derivatives from olefins by the reaction with organic gem-dihalides and copper
Nariyoshi Kawabata, Ichiro Kamemura, and Michiharu Naka
pp 2139 - 2145; DOI:
10.1021/ja00502a034
PDF
Electron transfer processes in the photochemistry of .beta.-(dimethylamino)propiophenone
M. V. Encinas and J. C. Scaiano
pp 2146 - 2152; DOI:
10.1021/ja00502a035
PDF
Photopolymerization in chiral crystals. 3. Toward an "absolute" asymmetric synthesis of optically active dimers and polymers with quantitative enantiomeric yield
Lia Addadi and Meir Lahav
pp 2152 - 2156; DOI:
10.1021/ja00502a036
PDF
Photochemical heavy-atom effect. 8. Multipathway photodimerization of 2-methylthianaphthene 1,1-dioxide. An example of a heavy-atom effect on intersystem crossing in a 1,4 diradical
Michael J. Hopkinson, William W. Schloman, Benjamin F. Plummer, E. Wenkert, and M. Raju
pp 2157 - 2164; DOI:
10.1021/ja00502a037
PDF
Investigation of the zeolite catalyzed alkylation of toluene using carbon-13 nuclear magnetic resonance
Michael D. Sefcik
pp 2164 - 2170; DOI:
10.1021/ja00502a038
PDF
Tetracyclines. 10. Chemical-structural properties of tetracycline derivatives. 5. A total synthesis and structural aspects of racemic 8-oxygenated tetracyclines
B. Glatz, G. Helmchen, H. Muxfeldt, H. Porcher, R. Prewo, J. Senn, J. J. Stezowski, R. J. Stojda, and D. R. White
pp 2171 - 2181; DOI:
10.1021/ja00502a039
PDF
Rates and equilibriums for the inactivation of muscle aldolase by an active site directed Michael reaction
Rossana Motiu-DeGrood, William Hunt, Joyce Wilde, and D. J. Hupe
pp 2182 - 2190; DOI:
10.1021/ja00502a040
PDF
Ion cyclotron resonance mass spectrometric and ab initio studies of the structure and mechanism of formation of protonated dimers in simple carbonyl compounds XYCO (X or Y = hydrogen or fluorine)
A. T. Hagler, Z. Karpas, and F. S. Klein
pp 2191 - 2196; DOI:
10.1021/ja00502a041
PDF
A general methodology for pseudoguaiane synthesis: total synthesis of (.+-.)-damsinic acid and (.+-.)-confertin
Paul A. Wender, Michael A. Eissenstat, and Michael P. Filosa
pp 2196 - 2198; DOI:
10.1021/ja00502a042
PDF
Unusual substituent and multiplicity effects in carbenic ring expansion and substitution reactions of benzenes with 3-diazo-2,5-diphenylpyrrole
M. Nagarajan and H. Shechter
pp 2198 - 2200; DOI:
10.1021/ja00502a043
PDF
Flash vacuum pyrolysis studies. 7. Structure and origin of the onion lachrymatory factor. A microwave study
Eric Block, Robert E. Penn, and Larry K. Revelle
pp 2200 - 2201; DOI:
10.1021/ja00502a044
PDF
Photochemical reaction of dicyanoanthracene with acetonitrile in the presence of an aliphatic amine. A novel photochemical amination
Mamoru Ohashi, Hitoshi Kudo, and Shuzo Yamada
pp 2201 - 2202; DOI:
10.1021/ja00502a045
PDF
Nickel atom promoted dimerization of dimethylfulvene. A formal [6 + 6] cycloaddition
Nguyen Hao, Jeffery F. Sawyer, Brian G. Sayer, and Michael J. McGlinchey
pp 2203 - 2204; DOI:
10.1021/ja00502a046
PDF
.sigma. and .pi. Components of substituent effects in saturated systems. Monosubstituted methanes
Kenneth B. Wiberg
pp 2204 - 2205; DOI:
10.1021/ja00502a047
PDF
Photoselected fluorescence detected circular dichroism
Eric W. Lobenstine and Douglas H. Turner
pp 2205 - 2207; DOI:
10.1021/ja00502a048
PDF
Benzylic organolithium carbanion reactivity. 3. Kinetic studies with neopentyl halides and benzyl fluoride
H. E. Zieger and Donald Mathisen
pp 2207 - 2208; DOI:
10.1021/ja00502a049
PDF
A facile ring-opening reaction of furfuryl carbanion. Regioselective generation of di- or trianionic enolates
Kunio Atsumi and Isao Kuwajima
pp 2208 - 2210; DOI:
10.1021/ja00502a050
PDF
Penems. 1. Penem formation via a novel oxidative addition process mediated by copper(I)
Frank DiNinno, Ernest V. Linek, and B. G. Christensen
pp 2210 - 2211; DOI:
10.1021/ja00502a051
PDF
Derivatives of heteropolyanions. 2. Metal-metal-bonded derivatives
W. H. Knoth
pp 2211 - 2213; DOI:
10.1021/ja00502a052
PDF
Spectrophotometric determination of the proton-dependent stability constant of ferric enterobactin
Wesley R. Harris, Carl J. Carrano, and Kenneth N. Raymond
pp 2213 - 2214; DOI:
10.1021/ja00502a053
PDF
Metal alkyls as precursors for polylithium organic compounds. A high yield synthesis for "C2Li6"
Lawrence A. Shimp and Richard J. Lagow
pp 2214 - 2216; DOI:
10.1021/ja00502a054
PDF
Biradicaloid intermediates in photochemistry: spectroscopic and kinetic study of 1,4-perinaphthadiyl and related 1,8-naphthoquinodimethans
Markus Gisin, Erika Rommel, Jakob Wirz, Michael N. Burnett, and Richard M. Pagni
pp 2216 - 2218; DOI:
10.1021/ja00502a055
PDF
Rapid scanning stopped-flow absorption studies of the effect on tryptophanase of a change in pH or potassium(1+) ion concentration: evidence for a slow conformational change
David S. June, Barbara Kennedy, T. H. Pierce, Sami V. Elias, Folim Halaka, Iraj Behbahani-Nejad, Ashraf El Bayoumi, Clarence H. Suelter, and James L. Dye
pp 2218 - 2219; DOI:
10.1021/ja00502a056
PDF
Resonance Raman studies on pyrocatechase
Lawrence Que and Robert H. Heistand
pp 2219 - 2221; DOI:
10.1021/ja00502a057
PDF
Iron-catalyzed oxidative decarboxylation of benzoylformic acid
Brock Siegel and Jane Lanphear
pp 2221 - 2222; DOI:
10.1021/ja00502a058
PDF
Carboxylic and phosphate esters of .alpha.-fluoro alcohols
Paul R. Ortiz de Montellano and Wayne A. Vinson
pp 2222 - 2224; DOI:
10.1021/ja00502a059
PDF
Structure elucidation by high resolution mass spectrometry of a highly modified nucleoside from mammalian transfer RNA. N-[(9-.beta.-D-Ribofuranosyl-2-methylthiopurin-6-yl)carbamoyl]threonine
Z. Yamaizumi, S. Nishimura, Klaus Limburg, Manfred Raba, Hans J. Gross, P. F. Crain, and James A. McCloskey
pp 2224 - 2225; DOI:
10.1021/ja00502a060
PDF
Silyl ketone chemistry. A new regiospecific route to silyl enol ethers
Hans J. Reich, Jay J. Rusek, and Richard E. Olson
pp 2225 - 2227; DOI:
10.1021/ja00502a061
PDF
Chemically induced dynamic nuclear polarization from the selective recombination of radical pairs in micelles
Richard S. Hutton, Heinz D. Roth, Bernhard Kraeutler, William R. Cherry, and Nicholas J. Turro
pp 2227 - 2228; DOI:
10.1021/ja00502a062
PDF
Oxidations and oxygen transfers effected by a flavin N(5)-oxide. A model for flavin-dependent monooxygenases
W. H. Rastetter, T. R. Gadek, J. P. Tane, and J. W. Frost
pp 2228 - 2231; DOI:
10.1021/ja00502a063
PDF
Aspects of artificial photosynthesis. Photoionization and electron transfer in dihexadecyl phosphate vesicles
Jose R. Escabi-Perez, Alejandro Romero, Sava Lukac, and Janos H. Fendler
pp 2231 - 2233; DOI:
10.1021/ja00502a064
PDF
Is formamide planar or nonplanar?
Norman R. Carlsen, Leo Radom, Noel V. Riggs, and William R. Rodwell
pp 2233 - 2234; DOI:
10.1021/ja00502a065
PDF
Bicyclic phosphoranes as precursors of mono- or bidentate eight-membered cyclic ligands. Coordination compounds with the metal in a cradle
Christian Pradat, Jean G. Riess, Daniel Bondoux, Bernard F. Mentzen, Igor Tkatchenko, and Doureid Houalla
pp 2234 - 2235; DOI:
10.1021/ja00502a066
PDF
New evidence for the involvement of monomeric silicon difluoride in reactions with olefins
J. C. Thompson, A. P. G. Wright, and W. F. Reynolds
pp 2236 - 2237; DOI:
10.1021/ja00502a067
PDF
Avoparcin
W. J. McGahren, J. H. Martin, G. O. Morton, R. T. Hargreaves, R. A. Leese, F. M. Lovell, and G. A. Ellestad
pp 2237 - 2239; DOI:
10.1021/ja00502a068
PDF
A radical-chain mechanism in substitution reactions of (unsaturated alkyl) metal carbonyl complexes
Benedict D. Fabian and Jay A. Labinger
pp 2239 - 2240; DOI:
10.1021/ja00502a069
PDF
Novel reactions of dioxygen in organometallic chemistry. Hydrogen atom abstraction vs. dimerization of the 19-electron complexes .eta.5-cyclopentadienyliron(I) .eta.6-arene
Didier Astruc, Enrique Roman, Jean Rene Hamon, and Patrick Batail
pp 2240 - 2242; DOI:
10.1021/ja00502a070
PDF
Intramolecular kinetic isotope effect in gas-phase proton-transfer reactions
Keith M. Wellman, Maria E. Victoriano, Paulo C. Isolani, and Jose M. Riveros
pp 2242 - 2243; DOI:
10.1021/ja00502a071
PDF
Preparation of vinblastine, vincristine, and leurosidine, antitumor alkaloids from Catharanthus species (Apocynaceae)
Pierre Mangeney, R. Zo Andriamialisoa, Nicole Langlois, Yves Langlois, and Pierre Potier
pp 2243 - 2245; DOI:
10.1021/ja00502a072
PDF
Geometrical structure and energetics of Closs's diradical: 1,3-cyclopentadiyl
Morgan P. Conrad, Russell M. Pitzer, and Henry F. Schaefer
pp 2245 - 2246; DOI:
10.1021/ja00502a073
PDF
Nickel-induced conversion of carbon-oxygen into carbon-carbon bonds. One-step transformations of enol ethers into olefins and aryl ethers into biaryls
Ernest Wenkert, Enrique L. Michelotti, and Charles S. Swindell
pp 2246 - 2247; DOI:
10.1021/ja00502a074
PDF
Stereochemically nonrigid silanes, germanes, and stannanes. 4. Chiral silylcyclopentadienes: new evidence for a 1,2 (1,5) metallotropic shift
Alan Bonny and Stephen R. Stobart
pp 2247 - 2249; DOI:
10.1021/ja00502a075
PDF
The chemistry of tetrahedral intermediates. 4. Hemiorthothiolate ester anions - RC(OR')2S- +Na. A novel class of thermally stable tetrahedral intermediates
Farid Khouri and Moses K. Kaloustian
pp 2249 - 2251; DOI:
10.1021/ja00502a076
PDF
A pair-specific osmium reagent for polynucleotides
H. Ford, C. H. Chang, and E. J. Behrman
pp 2251 - 2252; DOI:
10.1021/ja00502a077
PDF
Book Reviews

pp 2253 - 2258; DOI:
10.1021/ja00502a600
PDF

Issue 9


Kinetics and thermodynamics of ion-molecule association reactions of water, hydrogen sulfide, and benzene. Comments on intermolecular entropy effects
Joseph M. Jasinski, Robert N. Rosenfeld, David M. Golden, and John I. Brauman
pp 2259 - 2265; DOI:
10.1021/ja00503a001
PDF
Mechanism of base-promoted phosphonium salt hydrolyses. Kinetics and multiple substituent effects for a nucleophilic attack at phosphorus
Brock Siegel
pp 2265 - 2268; DOI:
10.1021/ja00503a002
PDF
Rates of spin-forbidden organic reactions. 3. Extrusion of nitrogen from methylenepyrazoline
Charles D. Duncan, E. Amitai Halevi, and Carl Trindle
pp 2269 - 2275; DOI:
10.1021/ja00503a003
PDF
ESR and ENDOR studies of a radical anion with formally nonconjugated keto groups: cis-10,11-dimethyldiphensuccindan-9,12-dione
P. Fuerderer, F. Gerson, J. Heinzer, S. Mazur, H. Ohya-Nishiguchi, and A. H. Schroeder
pp 2275 - 2281; DOI:
10.1021/ja00503a004
PDF
Calculated infrared and Raman spectra of the 1Ag ground states of rectangular cyclobutadiene and tetradeuteriocyclobutadiene
L. J. Schaad, B. Andes Hess, and Carl S. Ewig
pp 2281 - 2283; DOI:
10.1021/ja00503a005
PDF
Excited states and optical activity of allenes. Allene, 1,3-dimethylallene, and 1,2-cyclononadiene
Arvi Rauk, Alex F. Drake, and Stephen F. Mason
pp 2284 - 2289; DOI:
10.1021/ja00503a006
PDF
Theoretical study of the reactions of ethene with diimide species
Daniel J. Pasto and Daniel M. Chipman
pp 2290 - 2296; DOI:
10.1021/ja00503a007
PDF
Kinetic studies on 1:1 electron-transfer reactions involving blue copper proteins. 2. Protonation effects and different binding sites in the oxidation of parsley plastocyanin with Co(4,7-DPSphen)33-, Fe(CN)63-, and Co(phen)33+
A. Graham Lappin, Michael G. Segal, David C. Weatherburn, and A. Geoffrey Sykes
pp 2297 - 2301; DOI:
10.1021/ja00503a008
PDF
Kinetic studies on 1:1 electron-transfer reactions involving blue copper proteins. 3. Protonation effects, protein-complex association, and binding sites in reactions of Pseudomonas aeruginosa azurin with Co(phen)33+, Co(4,7-DPSphen)33-, and Fe(CN63- (oxidants) and Fe(CN)64- (reductant)
A. Graham Lappin, Michael G. Segal, David C. Weatherburn, Richard A. Henderson, and A. Geoffrey Sykes
pp 2302 - 2306; DOI:
10.1021/ja00503a009
PDF
A detailed analysis of the charge-transfer bands of a blue copper protein. Studies of the nickel(II), manganese(II), and cobalt(II) derivatives of azurin
David L. Tennent and David R. McMillin
pp 2307 - 2311; DOI:
10.1021/ja00503a010
PDF
Electrochemical studies on a series of manganese(III) complexes containing symmetrical pentadentate ligands
W. M. Coleman, R. R. Goehring, L. T. Taylor, J. G. Mason, and R. K. Boggess
pp 2311 - 2315; DOI:
10.1021/ja00503a011
PDF
Electrochemistry in liquid sulfur dioxide. 1. Oxidation of thianthrene, phenothiazine, and 9,10-diphenylanthracene
Lawrence A. Tinker and Allen J. Bard
pp 2316 - 2319; DOI:
10.1021/ja00503a012
PDF
Neighboring ortho carboxyl group participation and .alpha.-deuterium isotope effects in the hydrolysis of benzyl bromides
V. P. Vitullo, S. Sridharan, and L. P. Johnson
pp 2320 - 2322; DOI:
10.1021/ja00503a013
PDF
On the conformational dependence of secondary .beta.-deuterium isotope effects
Douglas J. DeFrees, Warren J. Hehre, and Dionis E. Sunko
pp 2323 - 2327; DOI:
10.1021/ja00503a014
PDF
Oxygen-17 nuclear quadrupole double resonance spectroscopy. 1. Introduction. Results for organic carbonyl compounds
C. P. Cheng and Theodore L. Brown
pp 2327 - 2334; DOI:
10.1021/ja00503a015
PDF
The ultraviolet transitions of benzoic acid. 1. Interpretation of the singlet absorption spectrum
J. Clayton Baum and Donald S. McClure
pp 2335 - 2339; DOI:
10.1021/ja00503a016
PDF
The ultraviolet transitions of benzoic acid. 2. Hydrogen bonding in the ground and excited states
J. Clayton Baum and Donald S. McClure
pp 2340 - 2343; DOI:
10.1021/ja00503a017
PDF
Methoxy group nonplanarity in o-dimethoxybenzenes. Simple predictive models for conformations and rotational barriers in alkoxyaromatics
George M. Anderson, Peter A. Kollman, L. N. Domelsmith, and K. N. Houk
pp 2344 - 2352; DOI:
10.1021/ja00503a018
PDF
Chiral trialkylborane reducing agents. Preparation of 1-deuterio primary alcohols of high enantiomeric purity
M. Mark Midland, Sue Greer, Alfonso Tramontano, and Stephen A. Zderic
pp 2352 - 2355; DOI:
10.1021/ja00503a019
PDF
Reactions of resonance stabilized anions. 35. Electron transfer processes. 18. Reaction of 2-halo-2-nitropropanes and 2,2-dinitropropane with resonance-stabilized carbanions and 1-alkynyllithiums
Glen A. Russell, Mikolaj Jawdosiuk, and Mieczyslaw Makosza
pp 2355 - 2359; DOI:
10.1021/ja00503a020
PDF
Electron transfer processes. 19. Reaction of aryl radicals with anions in aqueous solution
Glen A. Russell and A. R. Metcalfe
pp 2359 - 2362; DOI:
10.1021/ja00503a021
PDF
Photodimer of 9,10-dimethylanthracene and tetracene. Crystal and molecular structure, photophysics, and photochemistry
James Ferguson, Albert W. H. Mau, and Peter O. Whimp
pp 2363 - 2369; DOI:
10.1021/ja00503a022
PDF
1-(9-Anthryl)-3-(1-naphthyl)propane. Crystal and molecular structure of the photoisomer. Photophysics and photochemistry of the two isomers
James Ferguson, Albert W. H. Mau, and Peter O. Whimp
pp 2370 - 2377; DOI:
10.1021/ja00503a023
PDF
CIDNP studies of the photoreduction of aromatic ketones by aromatic amines. Singlet vs. triplet radical ion pair formation by selective excitation
Ben M. P. Hendriks, Robert I. Walter, and Hanns Fischer
pp 2378 - 2383; DOI:
10.1021/ja00503a024
PDF
Cyclopropylcarbinyl radicals in the photochemistry of .beta.,.gamma.-cyclopropyl ketones
Ioannis M. Takakis and William C. Agosta
pp 2383 - 2389; DOI:
10.1021/ja00503a025
PDF
Competitive condensation and proton-transfer reactions. Temperature and pressure effects and the detailed mechanism
Michael Meot-Ner
pp 2389 - 2395; DOI:
10.1021/ja00503a026
PDF
Ion thermochemistry of low-volatility compounds in the gas phase. 2. Intrinsic basicities and hydrogen-bonded dimers of nitrogen heterocyclics and nucleic bases
Michael Meot-Ner
pp 2396 - 2403; DOI:
10.1021/ja00503a027
PDF
Thermochemistry of bridged-ring substances. Enthalpies of formation of some diamondoid hydrocarbons and of perhydroquinacene. Comparisons with data from empirical force field calculations
Timothy Clark, Trevor M. Knox, M. Anthony McKervey, Henry Mackle, and John J. Rooney
pp 2404 - 2410; DOI:
10.1021/ja00503a028
PDF
Stereochemistry and mechanism for the palladium(II)-catalyzed oxidation of ethene in water (the Wacker process)
J. E. Baeckvall, B. Akermark, and S. O. Ljunggren
pp 2411 - 2416; DOI:
10.1021/ja00503a029
PDF
The triplet state of the chlorophyll dimer
Richard H. Clarke, David R. Hobart, and Willem R. Leenstra
pp 2416 - 2423; DOI:
10.1021/ja00503a030
PDF
Lactim/lactam tautomeric interconversion mechanism in water/polar aprotic solvent water systems. 2. Hydration of 2-hydroxypyridines. Evidence for a bifunctional water-catalyzed proton transfer
Olivier Bensaude, Marianne Chevrier, and Jacques Emile Dubois
pp 2423 - 2429; DOI:
10.1021/ja00503a031
PDF
Micellar catalysis and reactant incorporation in dephosphorylation and nucleophilic substitution
Clifford A. Bunton, Giorgio Cerichelli, Yasuji Ihara, and Luis Sepulveda
pp 2429 - 2435; DOI:
10.1021/ja00503a032
PDF
Synthesis in the tropane class of alkaloids. Pseudotropine and dl-cocaine
Joseph J. Tufariello, George B. Mullen, John J. Tegeler, Eugene J. Trybulski, Shing Chun Wong, and S. Asrof Ali
pp 2435 - 2442; DOI:
10.1021/ja00503a033
PDF
A kinetic model for R- and T-state hemoglobin. Flash photolysis of heme-imidazole-carbon monoxide mixtures
Dabney K. White, John B. Cannon, and T. G. Traylor
pp 2443 - 2454; DOI:
10.1021/ja00503a034
PDF
Carbon-13 NMR spectroscopy of [20%-1,2-13C2-Gly6]-bradykinin. Role of serine in reducing structural heterogeneity
Robert E. London, John M. Stewart, Robert Williams, John R. Cann, and N. A. Matwiyoff
pp 2455 - 2462; DOI:
10.1021/ja00503a035
PDF
Crystal and molecular structure of oxythiamin chloride hydrochloride monohydrate. A thiamin antagonist with a conformation that differs from thiamin
Whanchul Shin, James Pletcher, Martin Sax, and Gary Blank
pp 2462 - 2469; DOI:
10.1021/ja00503a036
PDF
Aromatization of arene 1,2-oxides. 1-Carboxy- and 1-carboalkoxybenzene oxides
Derek R. Boyd and Glenn A. Berchtold
pp 2470 - 2474; DOI:
10.1021/ja00503a037
PDF
Cyclobutane-bicyclobutane system. 2. Protonation, deprotonation, and intermediate carbanion stereochemistry in the 1,3-hydrochloric acid elimination from 3-chlorocyclobutanecarbonitrile
S. Hoz, M. Albeck, and M. Livneh
pp 2475 - 2480; DOI:
10.1021/ja00503a038
PDF
cis-Methyldiazene
Norman C. Craig, Mark A. Kliewer, and Nancy C. Shih
pp 2480 - 2482; DOI:
10.1021/ja00503a039
PDF
Sulfur 2p photoelectron spectra of 1,8-bis(2'pyridyl)-3,6-dithiaoctane and its copper(II) complex. Possible interpretation of the S2p 168-eV peak in blue copper proteins
Michael Thompson, John Whelan, Deborah J. Zemon, B. Bosnich, E. I. Solomon, and Harry B. Gray
pp 2482 - 2483; DOI:
10.1021/ja00503a040
PDF
Anthracyclines and related substances. 2. An efficient and regiospecific synthesis of dl-7,9-dideoxydaunomycinone
K. S. Kim, Ermes Vanotti, Antonino Suarato, and Francis Johnson
pp 2483 - 2484; DOI:
10.1021/ja00503a041
PDF
2-Hydroperoxyhexafluoro-2-propanol. A low-cost, catalytic oxidant for synthesis and a structural analog of naturally occurring flavin hydroperoxides
Richard P. Heggs and Bruce Ganem
pp 2484 - 2486; DOI:
10.1021/ja00503a042
PDF
SN2 character of solvolyses of tert-butyl halides and of trifluoroacetolyses of secondary alkyl sulfonates
T. William Bentley, Christine T. Bowen, William Parker, and C. Ian F. Watt
pp 2486 - 2488; DOI:
10.1021/ja00503a043
PDF
Chain mechanism for the autoxidation of the isopropylchromium(III) cation
Debra Ann Ryan and James H. Espenson
pp 2488 - 2489; DOI:
10.1021/ja00503a044
PDF
A novel phase transfer catalyst capable of facilitating acid-catalyzed and/or electrophilic reactions
Daniel W. Armstrong and Mark Godat
pp 2489 - 2491; DOI:
10.1021/ja00503a045
PDF
Evidence for silicon-carbon and silicon-nitrogen multiple-bonded (p.pi.-p.pi.) intermediates from photolysis. Dipolar character of the unsaturated linkages
Maher Elsheikh, Norman R. Pearson, and Leo H. Sommer
pp 2491 - 2492; DOI:
10.1021/ja00503a046
PDF
A spirocyclophosphazene with iron-phosphorus bonds and a phosphorus-iron-iron three-membered ring
Paul P. Greigger and Harry R. Allcock
pp 2492 - 2493; DOI:
10.1021/ja00503a047
PDF
(.+-.)-Periplanone-B. Total synthesis and structure of the sex excitant pheromone of the American cockroach
W. Clark Still
pp 2493 - 2495; DOI:
10.1021/ja00503a048
PDF
Sex pheromone of the American cockroach: absolute configuration of periplanone-B
Michael A. Adams, Koji Nakanishi, W. Clark Still, Edward V. Arnold, Jon Clardy, and C. J. Persoons
pp 2495 - 2498; DOI:
10.1021/ja00503a049
PDF
Effect of solvation upon carbonyl substitution reactions
Elaine K. Fukuda and Robert T. McIver
pp 2498 - 2499; DOI:
10.1021/ja00503a050
PDF
Micellar stereoselectivity. Cleavage of diastereomeric substrates by functional surfactant micelles
Robert A. Moss, Yoon-Sik Lee, and Thomas J. Lukas
pp 2499 - 2501; DOI:
10.1021/ja00503a051
PDF
Stereoselective synthesis of threo-3-hydroxy-2-methylcarboxylic acids using alkoxyalkyl propionates
A. I. Meyers and Paul J. Reider
pp 2501 - 2502; DOI:
10.1021/ja00503a052
PDF
Photoionization by green light
J. K. Thomas and P. L. Piciulo
pp 2502 - 2503; DOI:
10.1021/ja00503a053
PDF
Adamantylideneadamantane radical cation, a long-lived one-electron, two-center .pi.-bonded species
Stephen F. Nelsen and Carl R. Kessel
pp 2503 - 2504; DOI:
10.1021/ja00503a054
PDF
Tetradecaisopropoxydihydridotetratungsten(IV). Oxidative addition of PrO-H across a tungsten-to-tungsten triple bond
Minoru Akiyama, Dorothy Little, Malcolm H. Chisholm, Deborah A. Haitko, F. Albert Cotton, and Michael W. Extine
pp 2504 - 2506; DOI:
10.1021/ja00503a055
PDF
The "supershort" chromium-to-chromium quadruple bond: its occurrence in a tetracarboxamidatodichromium(II) compound
Avi Bino, F. Albert Cotton, and Wolfgang Kaim
pp 2506 - 2507; DOI:
10.1021/ja00503a056
PDF
Book Reviews

pp 2508 - 2510; DOI:
10.1021/ja00503a600
PDF

Issue 10


Importance of cycloamylose substrate geometry and dynamic coupling in the deacylation of 3- and 4-nitrophenyl acetates
Raymond J. Bergeron and Michael Almy Channing
pp 2511 - 2516; DOI:
10.1021/ja00504a001
PDF
Electron spin resonance studies on radiolysis of crystalline methanol at 4.2 K
Kazumi Toriyama and Machio Iwasaki
pp 2516 - 2523; DOI:
10.1021/ja00504a002
PDF
Low-temperature infrared studies of the styrene-ozone reaction. Formation of an unusual ozonide
I. C. Hisatsune, Kiyonori Shinoda, and Julian Heicklen
pp 2524 - 2526; DOI:
10.1021/ja00504a003
PDF
Lipophilic [2.2.2] cryptands as phase-transfer catalysts. Activation and nucleophilicity of anions in aqueous-organic two-phase systems and in organic solvents of low polarity
Dario Landini, Angelamaria Maia, Fernando Montanari, and Pietro Tundo
pp 2526 - 2530; DOI:
10.1021/ja00504a004
PDF
Study of electrolytic solution process using the scaled-particle theory. 1. The standard free energy of solvation
Utpal Sen
pp 2531 - 2534; DOI:
10.1021/ja00504a005
PDF
Semiconductor electrodes. 20. Photogeneration of solvated electrons on p-type gallium arsenide electrodes in liquid ammonia
Richard E. Malpas, Kingo Itaya, and Allen J. Bard
pp 2535 - 2537; DOI:
10.1021/ja00504a006
PDF
Organic transition states. 6. Thermal decomposition of 1-pyrazolines
Philippe C. Hiberty and Yves Jean
pp 2538 - 2543; DOI:
10.1021/ja00504a007
PDF
Ab initio mechanistic study of radical reactions. Transition states and reaction barriers for the reaction of atomic hydrogen with acetylene
Shigeru Nagase and C. William Kern
pp 2544 - 2549; DOI:
10.1021/ja00504a008
PDF
Systematic ab initio gradient calculation of molecular geometries, force constants, and dipole moment derivatives
Peter Pulay, Geza Fogarasi, Frank Pang, and James E. Boggs
pp 2550 - 2560; DOI:
10.1021/ja00504a009
PDF
Theoretical ab initio SCF investigation of the photochemical behavior of the three-membered rings. 5. Oxaziridine
B. Bigot, D. Roux, A. Sevin, and A. Devaquet
pp 2560 - 2566; DOI:
10.1021/ja00504a010
PDF
Photodetachment of electrons from anions of high symmetry. Electron photodetachment spectra of the cyclooctatetraenyl and perinaphthenyl anions
Ruedi Gygax, H. Lee McPeters, and John I. Brauman
pp 2567 - 2570; DOI:
10.1021/ja00504a011
PDF
Stereospecificity in reactions of activated .eta.3-allyl complexes of molybdenum
R. D. Adams, D. F. Chodosh, J. W. Faller, and A. M. Rosan
pp 2570 - 2578; DOI:
10.1021/ja00504a012
PDF
Isocyanide insertion reactions and their role in the cluster-catalyzed hydrogenation of isocyanide molecules
Richard D. Adams and Nancy M. Golembeski
pp 2579 - 2587; DOI:
10.1021/ja00504a013
PDF
Open-chain polyethers. Influence of aromatic donor end groups on thermodynamics and kinetics of alkali metal ion complex formation
Burkhard Tuemmler, Guenter Maass, Fritz Voegtle, Heinz Sieger, Ulrich Heimann, and Edwin Weber
pp 2588 - 2598; DOI:
10.1021/ja00504a014
PDF
Properties of clusters in the gas phase. 3. Hydration complexes of carbonate(1-) and bicarbonate(1-) ions
Robert G. Keesee, Naisin Lee, and A. W. Castleman
pp 2599 - 2604; DOI:
10.1021/ja00504a015
PDF
Bonding capabilities of transition metal clusters. 2. Relationship to bulk metals
Joseph W. Lauher
pp 2604 - 2607; DOI:
10.1021/ja00504a016
PDF
A study of the bonding in transition metal carbonyl hydrides
Hsiang-Wen Chen, William L. Jolly, Juergen Kopf, and Ting Ho Lee
pp 2607 - 2610; DOI:
10.1021/ja00504a017
PDF
X-ray photoelectron spectra of inorganic molecules. 21. Sulfur 2p chemical shifts associated with the binding of thiol and thioether groups of transition metal ions
V. Srinivasan, E. I. Stiefel, A. Elsberry, and R. A. Walton
pp 2611 - 2614; DOI:
10.1021/ja00504a018
PDF
Thermochemistry of the reaction of hydrogen sulfide with iodine and the heat of formation of HSI - a new sulfur compound
R. J. Hwang and S. W. Benson
pp 2615 - 2617; DOI:
10.1021/ja00504a019
PDF
Preparation and characterization of [rac-5,7,7,12,14,14,-hexamethyl-1,4,8,11-tetraazocyclotetradecane]copper(II) o-mercaptobenzoate hydrate, [Cu(tet b)(o-SC6H4CO2)].H2O, a complex with a CuN4S (mercaptide) chromophore
Joseph L. Hughey, Timothy G. Fawcett, Steven M. Rudich, R. A. Lalancette, Joseph A. Potenza, and Harvey J. Schugar
pp 2617 - 2623; DOI:
10.1021/ja00504a020
PDF
Metal-nitroxyl interactions. 8. Exchange interactions in a spin-labeled copper complex (3-(N-(3-2,2,5,5-tetramethylpyrroline-1-oxyl)amido)-4,9-dimethyl-5,8-diazadodeca-4,8-diene-2,11-dione)copper(II)
D. L. DuBois, G. R. Eaton, and S. S. Eaton
pp 2624 - 2627; DOI:
10.1021/ja00504a021
PDF
Metal complexes of fluorophosphines. 9. Structure of a novel complex from benzalacetonetricarbonyliron and methylaminobis(difluorophosphine)
M. G. Newton, R. B. King, M. Chang, and J. Gimeno
pp 2627 - 2631; DOI:
10.1021/ja00504a022
PDF
Structural and chemical characterization of a phosphine bound M-H-M bridged carbonylate: Et4N+(.mu.-H)[Mo2(CO)9PPh3]-
Marcetta Y. Darensbourg, Jerry L. Atwood, Robert R. Burch, William E. Hunter, and Nyal Walker
pp 2631 - 2637; DOI:
10.1021/ja00504a023
PDF
Controlling the number of metal sites to which a di(tertiary phosphine) coordinates in Group 6 metal carbonyls
R. L. Keiter, Y. Y. Sun, J. W. Brodack, and L. W. Cary
pp 2638 - 2641; DOI:
10.1021/ja00504a024
PDF
Laboratory and mass spectrometric studies of ligand exchange processes involving pentakis(trifluorophosphine)iron(0)
Ralph C. Dougherty, Martin A. Krevalis, and Ronald J. Clark
pp 2642 - 2644; DOI:
10.1021/ja00504a025
PDF
Oxygen atom transfer processes. Reaction of trans-dinitrobis(triethylphosphine)nickel(II), Ni(NO2)2(PEt3)2, with carbon monoxide
David T. Doughty, Gilbert Gordon, and Robert P. Stewart
pp 2645 - 2648; DOI:
10.1021/ja00504a026
PDF
Porphyrin core expansion and doming in heme proteins. New evidence from resonance Raman spectra of six-coordinate high-spin iron(III) hemes
Thomas G. Spiro, John D. Stong, and Paul Stein
pp 2648 - 2655; DOI:
10.1021/ja00504a027
PDF
The nature of bis(cyclopentadienyl)uranium dichloride and cyclopentadienyluranium trichloride in solution and in the solid state
Richard D. Ernst, William J. Kennelly, Cynthia Secaur Day, Victor W. Day, and Tobin J. Marks
pp 2656 - 2664; DOI:
10.1021/ja00504a028
PDF
Aggregation of alkylammonium carboxylates and aerosol-OT in apolar solvents studied using absorption and fluorescence probes
U. Herrmann and Z. A. Schelly
pp 2665 - 2669; DOI:
10.1021/ja00504a029
PDF
Ortho ester hydrolysis: direct evidence for a three-stage reaction mechanism
M. Ahmad, R. G. Bergstrom, M. J. Cashen, Y. Chiang, A. J. Kresge, R. A. McClelland, and M. F. Powell
pp 2669 - 2677; DOI:
10.1021/ja00504a030
PDF
The substituent effect on the thermal decomposition of acetal hydrotrioxides. Polar and radical decomposition paths
Franci Kovac and Bozo Plesnicar
pp 2677 - 2681; DOI:
10.1021/ja00504a031
PDF
Nucleophilic attacks on carbon-carbon double bonds. 25. Reactions of monoamines and diamines with 1,1-dicyano-2-p-dimethylaminophenyl-2-trifluoroethoxyethylene
Zvi Rappoport and Pnina Peled
pp 2682 - 2693; DOI:
10.1021/ja00504a032
PDF
Rhodium(I)-catalyzed rearrangements of strained molecules containing fused cyclobutane rings
Miriam Sohn, Jochanan Blum, and Jack Halpern
pp 2694 - 2698; DOI:
10.1021/ja00504a033
PDF
Anomalous rates of proton transfer to and from nitrogen and carbon in the reactions of amines with 1,1-dinitro-2,2-diphenylethylene
Claude F. Bernasconi and David J. Carre
pp 2698 - 2707; DOI:
10.1021/ja00504a034
PDF
Rate of protonation of 2,6-di-tert-butylpyridine by the hydronium ion. Steric hindrance to proton transfer
Claude F. Bernasconi and David J. Carre
pp 2707 - 2709; DOI:
10.1021/ja00504a035
PDF
Biosynthesis of uroporphyrinogens. Synthesis of .alpha.-aminomethylbilanes and their interaction with the enzymic system
Luis Diaz, Rosalia B. Frydman, Aldonia Valasinas, and Benjamin Frydman
pp 2710 - 2716; DOI:
10.1021/ja00504a036
PDF
Active site studies of neurohypophyseal hormones. Comparison of oxytocin and arginine vasopressin analogs containing 2-D-tyrosine
Victor J. Hruby, Donald A. Upson, Diane M. Yamamoto, Clark W. Smith, and Roderich Walter
pp 2717 - 2721; DOI:
10.1021/ja00504a037
PDF
Coordination chemistry of microbial iron transport compounds. 16. Isolation, characterization, and formation constants of ferric aerobactin
Wesley R. Harris, Carl J. Carrano, and Kenneth N. Raymond
pp 2722 - 2727; DOI:
10.1021/ja00504a038
PDF
Ferric ion sequestering agents. 1. Hexadentate O-bonding N,N',N"-tris(2,3-dihydroxybenzoyl) derivatives of 1,5,9-triazacyclotridecane and 1,3,5-triaminomethylbenzene
Frederick L. Weitl and Kenneth N. Raymond
pp 2728 - 2731; DOI:
10.1021/ja00504a039
PDF
Attachment of organic groups to heteropoly oxometalate anions
Frans Zonnevijlle and Michael T. Pope
pp 2731 - 2732; DOI:
10.1021/ja00504a040
PDF
Thermal generation of bis(triethylphosphine)-3,3-dimethylplatinacyclobutane from dineopentylbis(triethylphosphine)platinum(II)
Paul Foley and George M. Whitesides
pp 2732 - 2733; DOI:
10.1021/ja00504a041
PDF
Silicon-carbon double-bond formation via 1,5-sigmatropic migration of trimethylsilyl from silicon to carbon
Thomas J. Barton, William D. Wulff, Edward V. Arnold, and Jon Clardy
pp 2733 - 2735; DOI:
10.1021/ja00504a042
PDF
Serendipitous synthesis of a sila-.alpha.-pyran - convenient, penultimate precursor to dimethylsilanone
T. J. Barton and W. D. Wulff
pp 2735 - 2736; DOI:
10.1021/ja00504a043
PDF
Spin-inversion and orbital symmetry conspiracy in type A lumiketone rearrangements
Sason S. Shaik
pp 2736 - 2738; DOI:
10.1021/ja00504a044
PDF
A new method for converting oxiranes to allylic alcohols by an organosilicon reagent
S. Murata, M. Suzuki, and R. Noyori
pp 2738 - 2739; DOI:
10.1021/ja00504a045
PDF
2,2'-Bisallylmethane: thermal degenerate rearrangement of 1,3-dimethylenecyclopentane. Partly stereospecific generation of a biradical
Joseph J. Gajewski and Jose Salazar
pp 2739 - 2740; DOI:
10.1021/ja00504a046
PDF
2,2'-Bisallylmethane: thermal degenerate rearrangement of 1,3-dimethylenecyclopentane. Partly stereospecific closure of a biradical
Joseph J. Gajewski and Jose Salazar
pp 2740 - 2741; DOI:
10.1021/ja00504a047
PDF
A novel deuterium effect on dual charge-transfer and ligand-field emission of the cis-dichlorobis(2,2'-bipyridine)iridium(III) ion
Richard J. Watts, Shlomo Efrima, and Horia Metiu
pp 2742 - 2743; DOI:
10.1021/ja00504a048
PDF
Radical ions in photochemistry. 9. Reactions of the 1,1,2,2-tetraphenylcyclopropane radical cation
D. R. Arnold and R. W. R. Humphreys
pp 2743 - 2744; DOI:
10.1021/ja00504a049
PDF
Deuterium nuclear magnetic resonance measurements of glycoproteins which have been specifically deuterated either at selected carbohydrate or at lysine residues: determination of motional correlation times
Michael A. Bernstein, Laurance D. Hall, and William E. Hull
pp 2744 - 2746; DOI:
10.1021/ja00504a050
PDF
Secondary deuterium isotope effects and transition state structure in the aromatic Claisen rearrangement
Kirk D. McMichael and Gailerd L. Korver
pp 2746 - 2747; DOI:
10.1021/ja00504a051
PDF
Aliphatic Claisen rearrangement transition state structure from secondary .alpha.-deuterium isotope effects
J. J. Gajewski and N. D. Conrad
pp 2747 - 2748; DOI:
10.1021/ja00504a052
PDF
Structure and stereochemistry of officinalic acid, a novel triterpene from Fomes officinalis
W. W. Epstein, F. W. Sweat, G. VanLear, F. M. Lovell, and E. J. Gabe
pp 2748 - 2750; DOI:
10.1021/ja00504a053
PDF
Electron-transfer chemistry of the 3,5,5-trimethyl-2-morpholinon-3-yl radical
John M. Burns, Donald L. Wharry, and Tad H. Koch
pp 2750 - 2752; DOI:
10.1021/ja00504a054
PDF
On the involvement of lipoic acid in .alpha.-keto acid dehydrogenase complexes
William H. Rastetter, Julian Adams, John W. Frost, Larry J. Nummy, Jane E. Frommer, and Kenneth B. Roberts
pp 2752 - 2753; DOI:
10.1021/ja00504a055
PDF
Mechanism of photosubstitution of (.eta.5-C5H5)2Fe2(CO)4 by triphenylphosphine and triisopropyl phosphite. Direct observation of a binuclear intermediate, (.eta.5-C5H5)2Fe2(CO)4{P[OCH(CH3)2]3}, a molecule with a carbonyl bridge but no metal-metal bond
David R. Tyler, Maryke A. Schmidt, and Harry B. Gray
pp 2753 - 2755; DOI:
10.1021/ja00504a056
PDF
Metamagnetic properties of one-dimensional decamethylferrocenium 7,7,8,8-tetracyano-p-quinodimethanide (1:1):[Fe(.eta.5-C5Me5)2]+.cntdot.(TCNQ)-.cntdot.
G. A. Candela, L. J. Swartzendruber, Joel S. Miller, and M. J. Rice
pp 2755 - 2756; DOI:
10.1021/ja00504a057
PDF
Crystal and molecular structure of the paramagnetic 1:1 decamethylferrocenium 7,7,8,8-tetracyano-p-quinodimethanide dimer salt: {[Fe(C5Me5)2]+.cntdot.}2(TCNQ)22-
A. H. Reis, L. D. Preston, J. M. Williams, S. W. Peterson, G. A. Candela, L. J. Swartzendruber, and Joel S. Miller
pp 2756 - 2758; DOI:
10.1021/ja00504a058
PDF
Spin trapping of adsorbed hydrogen
Taizo Uda, Akio Kazusaka, Russell F. Howe, and George W. Keulks
pp 2758 - 2759; DOI:
10.1021/ja00504a059
PDF
Asymmetric reductions with a chiral 1,4-dihydropyridine crown ether
J. G. De Vries and Richard M. Kellogg
pp 2759 - 2761; DOI:
10.1021/ja00504a060
PDF
Extraordinary reactivity of the prostaglandin endoperoxide nucleus. Nonpolar rearrangement of 2,3-dioxabicyclo[2.2.1]heptane and -[2.2.2]octane
Daniel J. Coughlin and Robert G. Salomon
pp 2761 - 2763; DOI:
10.1021/ja00504a061
PDF
Electrochemical study of the generation and fate of iron dinitrosyl, a powerful catalyst for carbon-carbon bond formation from dienes
Danielle Ballivet-Tkatchenko, Marcel Riveccie, and Nabil El Murr
pp 2763 - 2765; DOI:
10.1021/ja00504a062
PDF
Metal binding to four different sites in adenine ligands. Crystal structures of 2:1 methylmercury complexes with adenine and 9-methyladenine
Leonardo Prizant, Marc J. Olivier, Roland Rivest, and Andre L. Beauchamp
pp 2765 - 2767; DOI:
10.1021/ja00504a063
PDF
Solution pH-induced reversal of stereoselectivity. Deuteration of malonate methylenes in some bis(malonato)cobalt(III) complexes
Ushio Sakaguchi, Kaiji Morito, and Hayami Yoneda
pp 2767 - 2768; DOI:
10.1021/ja00504a064
PDF
Apparent concurrent acetylene-vinylidenecarbene rearrangements, silyl-acetylide metathesis, and alkyne cleavage in the interaction of bis(trimethylsilyl)acetylene with (.eta.5-C5H5)Co(CO)2. Crystal and molecular structure of a novel biscarbyne complex: [.mu.3.eta.1-CSi(CH3)3][.mu.3.eta.1-C3Si(CH3)3][(.eta.5-C5H5)Co]3
John R. Fritch, K. Peter C. Vollhardt, Michael R. Thompson, and Victor W. Day
pp 2768 - 2770; DOI:
10.1021/ja00504a065
PDF
The nature of molybdenum(IV) in aqueous 4 M hydrochloric acid solution. Structure analysis by EXAFS
S. P. Cramer, Harry B. Gray, Zvi Dori, and Avi Bino
pp 2770 - 2772; DOI:
10.1021/ja00504a066
PDF
The molybdenum site of sulfite oxidase. Structural information from x-ray absorption spectroscopy
Stephen P. Cramer, Harry B. Gray, and K. V. Rajagopalan
pp 2772 - 2774; DOI:
10.1021/ja00504a067
PDF
Structural results relevant to the molybdenum sites in xanthine oxidase and sulfite oxidase. Crystal structures of MoO2L, L = (SCH2CH2)2NCH2CH2X with X = SCH3, N(CH3)2
Jeremy M. Berg, Keith O. Hodgson, Stephen P. Cramer, J. L. Corbin, A. Elsberry, N. Pariyadath, and Edward I. Stiefel
pp 2774 - 2776; DOI:
10.1021/ja00504a068
PDF
The molybdenum site of xanthine oxidase. Structural evidence from x-ray absorption spectroscopy
Thomas D. Tullius, D. M. Kurtz, S. D. Conradson, and Keith O. Hodgson
pp 2776 - 2779; DOI:
10.1021/ja00504a069
PDF
Photocontrol of binding ability of capped cyclodextrin
Akihiko Ueno, Hiromitsu Yoshimura, Rumiko Saka, and Tetsuo Osa
pp 2779 - 2780; DOI:
10.1021/ja00504a070
PDF
Differential reactivity of the .alpha.-methylene protons of bis(pyridoxylideneglycinato)cobalt(III) - inferences for vitamin B6 catalyzed reactions
J. R. Fischer and E. H. Abbott
pp 2781 - 2782; DOI:
10.1021/ja00504a071
PDF
Hydrido[tris(hexamethyldisilylamido)]thorium(IV) and -uranium(IV)
Howard W. Turner, Stephen J. Simpson, and Richard A. Andersen
pp 2782 - 2782; DOI:
10.1021/ja00504a072
PDF
A new approach toward the synthesis and chemistry of fluoroxy compounds
Shlomo Rozen and Ori Lerman
pp 2782 - 2784; DOI:
10.1021/ja00504a073
PDF
Sesbanine, a novel cytotoxic alkaloid from Sesbania drummondii
Richard G. Powell, Cecil R. Smith, David Weisleder, David A. Muthard, and Jon Clardy
pp 2784 - 2785; DOI:
10.1021/ja00504a074
PDF
Stopped-flow circular dichroism (SFCD) spectroscopy. Implication of significant conformational differences in the redox mechanism of cytochrome c
Iwao Tabushi, Kazuo Yamamura, and Takako Nishiya
pp 2785 - 2787; DOI:
10.1021/ja00504a075
PDF
Pulsed infrared laser induced visible luminescence
G. E. Hardy, B. P. Chandra, Jeffrey I. Zink, Arthur W. Adamson, Robert C. Fukuda, and R. T. Walters
pp 2787 - 2788; DOI:
10.1021/ja00504a076
PDF
Book Reviews

pp 2789 - 2792; DOI:
10.1021/ja00504a600
PDF

Issue 11


Vibronic coupling model for mixed-valence compounds. Comparisons and predictions
K. Y. Wong, P. N. Schatz, and S. B. Piepho
pp 2793 - 2803; DOI:
10.1021/ja00505a001
PDF
Nature of the semipolar XO bond. Comparative ab initio study of H3NO, H2NOH, H3PO, H2POH, H2P(O)F, H2SO, HSOH, HClO, ArO, and related molecules
Holger Wallmeier and Werner Kutzelnigg
pp 2804 - 2814; DOI:
10.1021/ja00505a002
PDF
Ab initio calculations of amplitude and phase functions for extended x-ray absorption fine structure spectroscopy
Boon-Keng Teo and P. A. Lee
pp 2815 - 2832; DOI:
10.1021/ja00505a003
PDF
Resonance Raman spectroelectrochemistry. 6. Ultraviolet laser excitation of the tetracyanoquinodimethane dianion
Richard P. Van Duyne, Mary R. Suchanski, Joseph M. Lakovits, Allen R. Siedle, Keith D. Parks, and Therese M. Cotton
pp 2832 - 2837; DOI:
10.1021/ja00505a004
PDF
Kinetics and thermochemistry of the reaction atomic chlorine + cyclopropane .dblarw. hydrochloric acid + cyclopropyl. Heat of formation of the cyclopropyl radical
Mohammad H. Baghal-Vayjooee and Sidney W. Benson
pp 2838 - 2840; DOI:
10.1021/ja00505a005
PDF
Study of micelle formation in solutions of alkylammonium carboxylates in apolar solvents by positron annihilation techniques
Luz Alicia Fucugauchi, Belkacem Djermouni, Edward D. Handel, and Hans J. Ache
pp 2841 - 2844; DOI:
10.1021/ja00505a006
PDF
Theoretical studies on E2 elimination reactions. Evidence that syn elimination is accompanied by inversion of configuration at the carbanionic center
Robert D. Bach, Robert C. Badger, and Timothy J. Lang
pp 2845 - 2848; DOI:
10.1021/ja00505a007
PDF
The unusual structures, energies, and bonding of lithium-substituted allenes, propynes, and cyclopropenes
Eluvathingal D. Jemmis, Jayaraman Chandrasekhar, and Paul von Rague Schleyer
pp 2848 - 2856; DOI:
10.1021/ja00505a008
PDF
Accurate binding energies of diborane, borane carbonyl, and borazane determined by many-body perturbation theory
Lynn T. Redmon, George D. Purvis, and Rodney J. Bartlett
pp 2856 - 2862; DOI:
10.1021/ja00505a009
PDF
Hartree-Fock minimal and extended basis set and configuration interaction calculations on the hydroboration reaction
Kenneth R. Sundberg, Glenn D. Graham, and William N. Lipscomb
pp 2863 - 2869; DOI:
10.1021/ja00505a010
PDF
A molecular orbital study of strong metal-support interaction between platinum and titanium dioxide
J. A. Horsley
pp 2870 - 2874; DOI:
10.1021/ja00505a011
PDF
Effect of iodine incorporation on the electrical conductivity of films of nickel phthalocyanine
W. A. Orr and S. C. Dahlberg
pp 2875 - 2877; DOI:
10.1021/ja00505a012
PDF
Adsorptive and catalytic properties of isolated units of [Fe4S4(SR)4]2-
Robert G. Bowman and Robert L. Burwell
pp 2877 - 2880; DOI:
10.1021/ja00505a013
PDF
Low-temperature NMR studies of a single crystal of trans-Cu(DL-ala)2.H2O
T. Sandreczki, D. Ondercin, and R. W. Kreilick
pp 2880 - 2884; DOI:
10.1021/ja00505a014
PDF
Kinetic studies of the reactions of N,N-dimethylformamide and N,N-dimethylacetamide with sodium in liquid ammonia
Clifton A. Young and Robert R. Dewald
pp 2884 - 2888; DOI:
10.1021/ja00505a015
PDF
The nature of the lowest excited state in fac-tricarbonylhalobis(4-phenylpyridine)rhenium(I) and fac-tricarbonylhalobis(4,4'-bipyridine)rhenium(I): emissive organometallic complexes in fluid solution
Paul J. Giordano and Mark S. Wrighton
pp 2888 - 2897; DOI:
10.1021/ja00505a016
PDF
Quantitative studies of chemical reactivity of tetra-.mu.-butyrato-dirhodium(II) complexes
Russell S. Drago, S. Peter Tanner, Robert M. Richman, and John R. Long
pp 2897 - 2903; DOI:
10.1021/ja00505a017
PDF
A novel bimetallic sulfur cluster. Crystal and molecular structure of a dimer of bis[methyldiphenylphosphinesilver]tetrathiotungsten, [(C6H5)2PCH3]4Ag4W2S8
Judith K. Stalick, Allen R. Siedle, Alan D. Mighell, and Camden R. Hubbard
pp 2903 - 2907; DOI:
10.1021/ja00505a018
PDF
Excited-state behavior of polypyridyl complexes of chromium(III)
N. Serpone, M. A. Jamieson, M. S. Henry, M. Z. Hoffman, F. Bolletta, and M. Maestri
pp 2907 - 2916; DOI:
10.1021/ja00505a019
PDF
The onset of band-like properties in the ligand-bridged, trimeric cluster {[(py)2Ru3O(OAc)6(pyr)]2[Ru3O(OAc)6(CO)]}
John A. Baumann, Stephen T. Wilson, Dennis J. Salmon, Pamela L. Hood, and Thomas J. Meyer
pp 2916 - 2920; DOI:
10.1021/ja00505a020
PDF
Rational synthesis of unidimensional mixed valence solids. Structural, spectral, and electrical studies of charge distribution and transport in partially oxidized nickel and palladium bisdiphenylglyoximates
Martin Cowie, Alain Gleizes, Gregory W. Grynkewich, Davida Webster Kalina, Malcolm S. McClure, Raymond P. Scaringe, Robert C. Teitelbaum, Stanley L. Ruby, James A. Ibers, and et al.
pp 2921 - 2936; DOI:
10.1021/ja00505a021
PDF
Rational synthesis of unidimensional mixed valence solids. Structure-oxidation state-charge transport relationships in iodinated nickel and palladium bis(benzoquinone dioximates)
Leo D. Brown, Davida Webster Kalina, Malcolm S. McClure, Steven Schultz, Stanley L. Ruby, James A. Ibers, Carl R. Kannewurf, and Tobin J. Marks
pp 2937 - 2947; DOI:
10.1021/ja00505a022
PDF
The missing heme spin state and a model for cytochrome c'. The mixed S = 3/2, 5/2 intermediate spin ferric porphyrin: perchlorato(meso-tetraphenylporphinato)iron(III)
Christopher A. Reed, Toshio Mashiko, Steven P. Bentley, Margaret E. Kastner, W. Robert Scheidt, K. Spartalian, and George Lang
pp 2948 - 2958; DOI:
10.1021/ja00505a023
PDF
Electrochemical reduction of allyl halides in nonaqueous solvents - a reinvestigation
Allen J. Bard and Andreas Merz
pp 2959 - 2965; DOI:
10.1021/ja00505a024
PDF
Hydroboration. 51. Hydroboration of representative allenes with 9-borabicyclo[3.3.1]nonane. An exceptional directive effect providing a direct synthesis of B-allyl-9-borabicyclo[3.3.1]nonane derivatives
Herbert C. Brown, Ronald Liotta, and Gary W. Kramer
pp 2966 - 2970; DOI:
10.1021/ja00505a025
PDF
Synthesis, stereostructure, pyramidal inversion, and alkylation of 1-thioniabicyclo[4.4.0]decane salts
David M. Roush, Elisabeth M. Price, Lieselotte K. Templeton, David H. Templeton, and Clayton H. Heathcock
pp 2971 - 2981; DOI:
10.1021/ja00505a026
PDF
Trans-cis photoisomerization of the stilbenes and a reexamination of the positional dependence of the heavy-atom effect
Jack Saltiel, A. Marinari, David W. L. Chang, James C. Mitchener, and E. Dennis Megarity
pp 2982 - 2996; DOI:
10.1021/ja00505a027
PDF
Reaction of vinyl chloride with difluorosilylene by cocondensation
Chao-Shiuan Liu and Tsai-Lih Hwang
pp 2996 - 2999; DOI:
10.1021/ja00505a028
PDF
Unimolecular isomerization of chemically activated thiirane to vinylthiol
A. G. Sherwood, I. Safarik, B. Verkoczy, G. Almadi, H. A. Wiebe, and O. P. Strausz
pp 3000 - 3004; DOI:
10.1021/ja00505a029
PDF
Acyl substituent effects on thiohemiacetal equilibriums
Marc S. Kanchuger and Larry D. Byers
pp 3005 - 3010; DOI:
10.1021/ja00505a030
PDF
The timing of the proton transfer process in acid-catalyzed carbonyl addition. Evidence for a preassociation mechanism for catalysis of carbinolamine formation from acethydrazide and p-chlorobenzaldehyde
J. M. Sayer and Carl Edman
pp 3010 - 3016; DOI:
10.1021/ja00505a031
PDF
Metal ion effects on intramolecular general base and nucleophilic carboxyl group participation in ester hydrolysis. Hydrolysis of salicyl phenanthroline-2-carboxylate and 8-(2-carboxyquinolyl) hydrogen glutarate
Thomas H. Fife, Theodore J. Przystas, and Vanessa Lum Squillacote
pp 3017 - 3026; DOI:
10.1021/ja00505a032
PDF
Concurrent general acid and general base catalysis in the hydrolysis of an imidate ester. 2. Bifunctional catalysis
Yin-Nan Lee and Gaston L. Schmir
pp 3026 - 3035; DOI:
10.1021/ja00505a033
PDF
Host-guest complexation. 14. Host covalently bound to polystyrene resin for chromatographic resolution of enantiomers of amino acid and ester salts
G. Dotsevi Yao Sogah and Donald J. Cram
pp 3035 - 3042; DOI:
10.1021/ja00505a034
PDF
Asymmetric synthesis. Preparation of chiral methyl chiral lactic acid by catalytic asymmetric hydrogenation
M. D. Fryzuk and B. Bosnich
pp 3043 - 3049; DOI:
10.1021/ja00505a035
PDF
The entropy-controlled reactivity of singlet oxygen (1.DELTA.g) toward furans and indoles in toluene. A variable-temperature study by pulse radiolysis
A. A. Gorman, G. Lovering, and M. A. J. Rodgers
pp 3050 - 3055; DOI:
10.1021/ja00505a036
PDF
Lucibufagins. 2. Esters of 12-oxo-2.beta.,5.beta.,11.alpha.-trihydroxybufalin, the major defensive steroids of the firefly Photinus pyralis (Coleoptera: Lampyridae)
Jerrold Meinwald, David F. Wiemer, and Thomas Eisner
pp 3055 - 3060; DOI:
10.1021/ja00505a037
PDF
Identity of the chain-carrying species in halogenations with bromo- and chloroarylalkoxyiodinanes: selectivities of iodinanyl radicals
Ronald L. Amey and J. C. Martin
pp 3060 - 3065; DOI:
10.1021/ja00505a038
PDF
The configuration at C-24 in oogoniol (24R-3.beta.,11.alpha.,15.beta.,29-tetrahydroxystigmast-5-en-7-one) and identification of 24(28)-dehydrooogoniols as hormones in Achlya
Martin W. Preus and Trevor C. McMorris
pp 3066 - 3071; DOI:
10.1021/ja00505a039
PDF
Paramagnetic ion induced perturbations in the proton NMR spectrum of lysozyme: a reassignment of the tryptophan indole NH resonances
R. E. Lenkinski, J. L. Dallas, and J. D. Glickson
pp 3071 - 3077; DOI:
10.1021/ja00505a040
PDF
A fluorine-19 NMR method for identification of iron-sulfur cores extruded from active centers of proteins, with applications to milk xanthine oxidase and the iron-molybdenum proteins of nitrogenase
Geoffrey B. Wong, Donald M. Kurtz, R. H. Holm, L. E. Mortenson, and R. G. Upchurch
pp 3078 - 3090; DOI:
10.1021/ja00505a041
PDF
Maleylacetone cis-trans-isomerase. Mechanism of the interaction of coenzyme glutathione and substrate maleylacetone in the presence and absence of enzyme
Stanley Seltzer and Mow Lin
pp 3091 - 3097; DOI:
10.1021/ja00505a042
PDF
Reagents for the crosslinking of proteins by equilibrium transfer alkylation
Sumita Mitra and Richard G. Lawton
pp 3097 - 3110; DOI:
10.1021/ja00505a043
PDF
Stereochemical dependence of isotope effects in the singlet oxygen-olefin reaction
M. Bellarmine Grdina, Michael Orfanopoulos, and L. M. Stephenson
pp 3111 - 3112; DOI:
10.1021/ja00505a044
PDF
Kinetics of disulfide cleavage by methylmercury. Evidence for a concomitant electrophilic and nucleophilic mechanism
Robert D. Bach and Sundar J. Rajan
pp 3112 - 3114; DOI:
10.1021/ja00505a045
PDF
Structure of preuroporphyrinogen. Exploration of an enzyme mechanism by carbon-13 and nitrogen-15 NMR spectroscopy
G. Burton, H. Nordlov, S. Hosozawa, H. Matsumoto, P. M. Jordan, P. E. Fagerness, L. M. Pryde, and A. I. Scott
pp 3114 - 3116; DOI:
10.1021/ja00505a046
PDF
Investigation of the mechanism of the unimolecular and the electron-donor-catalyzed thermal fragmentation of secondary peroxy esters. Chemiluminescence of 1-phenylethyl peroxyacetate by the chemically initiated electron-exchange luminescence mechanism
Brian G. Dixon and Gary B. Schuster
pp 3116 - 3118; DOI:
10.1021/ja00505a047
PDF
Silver-catalyzed 1,2-acyl migration in an optically active chlorohydrin. Evidence for neighboring-group participation by carbonyl carbon
John M. Domagala and Robert D. Bach
pp 3118 - 3120; DOI:
10.1021/ja00505a048
PDF
Applications of homonuclear two-dimensional J spectroscopy: an alternative to broad band heteronuclear and homonuclear decoupling
Laurance D. Hall and Subramaniam Sukumar
pp 3120 - 3121; DOI:
10.1021/ja00505a049
PDF
Reaction of aromatic diazonium salts with carrier-free radioiodine and astatine. Evidence for complex formation
G. J. Meyer, K. Roessler, and G. Stoecklin
pp 3121 - 3123; DOI:
10.1021/ja00505a050
PDF
Flash photolysis in the adsorbed state: pyrene on porous glass
Paul L. Piciulo and James W. Sutherland
pp 3123 - 3125; DOI:
10.1021/ja00505a051
PDF
[2.2.2.2.2](1,2,3,4,5)Cyclophane
Paulo F. T. Schirch and Virgil Boekelheide
pp 3125 - 3126; DOI:
10.1021/ja00505a052
PDF
[2.2.2.2.2.2](1,2,3,4,5,6)Cyclophane: superphane
Y. Sekine, M. Brown, and V. Boekelheide
pp 3126 - 3127; DOI:
10.1021/ja00505a053
PDF
Heterogeneous photosynthetic production of amino acids from methane-ammonia-water at platinum/titanium dioxide. Implications in chemical evolution
Harald Reiche and Allen J. Bard
pp 3127 - 3128; DOI:
10.1021/ja00505a054
PDF
Three-center oxidative addition. Formation, structure, and dissociation of (PhCH2NC)12Rh3I23+ and related cations
Alan L. Balch and Marilyn M. Olmstead
pp 3128 - 3129; DOI:
10.1021/ja00505a055
PDF
Virtually complete enantioface differentiation in carbonyl group reduction by a complex aluminum hydride reagent
R. Noyori, I. Tomino, and Y. Tanimoto
pp 3129 - 3131; DOI:
10.1021/ja00505a056
PDF
Triangular iron-silver clusters
Arthur J. Carty, Graham N. Mott, and Nicholas J. Taylor
pp 3131 - 3133; DOI:
10.1021/ja00505a057
PDF
Complex chemistry of reactive organic compounds. 28. Carbene addition to metal carbonyls - a novel reaction in organometallic chemistry. Direct synthesis of .eta.2-ketene complexes from diazoalkanes
Wolfgang A. Herrmann, Johann Plank, Manfred L. Ziegler, and Klaus Weidenhammer
pp 3133 - 3135; DOI:
10.1021/ja00505a058
PDF
Direct observation of the methyldiazonium ion in fluorosulfuric acid
Daniel Berner and John F. McGarrity
pp 3135 - 3136; DOI:
10.1021/ja00505a059
PDF
3a-Hydroperoxypyrroloindole from tryptophan. Isolation and transformation to formylkynurenine
Masako Nakagawa, Shiro Kato, Shigehiro Kataoka, and Tohru Hino
pp 3136 - 3137; DOI:
10.1021/ja00505a060
PDF
Book Reviews

pp 3138 - 3140; DOI:
10.1021/ja00505a600
PDF

Issue 12


Some hydrido-bridged transition-metal dimers and their unsupported analogs. Speculations on pentuple bonding and pentuple bridging
Alain Dedieu, Thomas A. Albright, and Roald Hoffmann
pp 3141 - 3151; DOI:
10.1021/ja00506a001
PDF
Luminescence quenching of the bis(2,2'-bipyridine)aquo-2,2'-bipyridineiridium(III) ion and its conjugate base
Steven F. Bergeron and Richard J. Watts
pp 3151 - 3156; DOI:
10.1021/ja00506a002
PDF
Symmetries of hydrogen-bonded enol forms of diketones as determined by x-ray photoelectron spectroscopy
R. S. Brown, A. Tse, T. Nakashima, and R. C. Haddon
pp 3157 - 3162; DOI:
10.1021/ja00506a003
PDF
Characterization of the chemical ionization condensation products for the benzyl acetate system using mass-analyzed ion kinetic energy spectrometry
D. Cameron and R. G. Cooks
pp 3162 - 3168; DOI:
10.1021/ja00506a004
PDF
Effect of reaction energetics on the hydrogen chemical ionization mass spectra of halobenzene derivatives. Estimates of the heats of formation of substituted phenyl cations
Hei-Wun Leung and A. G. Harrison
pp 3168 - 3173; DOI:
10.1021/ja00506a005
PDF
ESR evidence for a biradical dimer initiator in diacetylene polymerization
Y. Hori and L. D. Kispert
pp 3173 - 3177; DOI:
10.1021/ja00506a006
PDF
A heterogeneous chemical oscillator. The Belousov-Zhabotinskii-type reaction of oxalic acid
Zoltan Noszticzius and Janos Bodiss
pp 3177 - 3182; DOI:
10.1021/ja00506a007
PDF
Orbital contributions to the nuclear spin-spin coupling constants of molecules
Wellington S. Lee and Jerome M. Schulman
pp 3182 - 3184; DOI:
10.1021/ja00506a008
PDF
Triplet [2 + 2] cycloadditions. Spin-inversion control of stereoselectivity
Sason S. Shaik
pp 3184 - 3196; DOI:
10.1021/ja00506a009
PDF
Solute-solvent interactions in the ground state and in electronic excited states. The dipolar aprotic to polar protic solvent blue shift of some anilines and phenols
Paul Haberfield, Douglas Rosen, and Ira Jasser
pp 3196 - 3199; DOI:
10.1021/ja00506a010
PDF
The effect of temperature on the structure of gaseous molecules. 4. Molecular structure and barrier to internal rotation for diboron tetrabromide
Donald D. Danielson and Kenneth Hedberg
pp 3199 - 3203; DOI:
10.1021/ja00506a011
PDF
Electron spin resonance studies of Ziegler-type catalysts. 3. The complex derived from dichlorobis(.eta.-cyclopentadienyl)vanadium and diethylaluminum chloride
Alwyn G. Evans, Jeffrey C. Evans, and Jonathan Mortimer
pp 3204 - 3206; DOI:
10.1021/ja00506a012
PDF
Synthesis of stable chromium(V) complexes of tertiary hydroxy acids
Miroslav Krumpolc and Jan Rocek
pp 3206 - 3209; DOI:
10.1021/ja00506a013
PDF
Multiple metal-carbon bonds. 13. Preparation and characterization of monocyclopentadienyl mononeopentylidene complexes of niobium and tantalum including the first details of an .alpha.-abstraction process
C. D. Wood, S. J. McLain, and R. R. Schrock
pp 3210 - 3222; DOI:
10.1021/ja00506a014
PDF
Structural studies of organic silver complexes in dimethyl sulfoxide by carbon-13 and silver-109 NMR
P. M. Henrichs, S. Sheard, J. J. H. Ackerman, and G. E. Maciel
pp 3222 - 3228; DOI:
10.1021/ja00506a015
PDF
The second dimension in metal vapor chemistry. A new general synthesis for metal alkyls
Timothy J. Juhlke, Ronald W. Braun, Tom R. Bierschenk, and Richard J. Lagow
pp 3229 - 3231; DOI:
10.1021/ja00506a016
PDF
Catalysis of the decomposition of hydrogen peroxide by a complex of iron(III) with a synthetic macrocyclic ligand
Alexandra C. Melnyk, Nicholas K. Kildahl, Alan R. Rendina, and Daryle H. Busch
pp 3232 - 3240; DOI:
10.1021/ja00506a017
PDF
Ring size limits for the direct observation of hydrido-bridged secondary cycloalkyl cations. Correspondence with chemical reactivity studies
Roger P. Kirchen and Ted S. Sorensen
pp 3240 - 3243; DOI:
10.1021/ja00506a018
PDF
Reactions in compressed solutions. 56. Evidence for a carbene-anion pair. 1,4-Disubstituted adamantanes as a stereochemical probe
W. J. Le Noble, Der-Ming Chiou, and Y. Okaya
pp 3244 - 3251; DOI:
10.1021/ja00506a019
PDF
Photochemical synthesis. 72. Thione photochemistry. Adamantanethione as a model for singlet .pi.,.pi.* hydrogen abstraction
K. Y. Law and P. De Mayo
pp 3251 - 3260; DOI:
10.1021/ja00506a020
PDF
Photochemical studies on the mechanism of the oxadi-.pi.-methane rearrangement. An example of a stereospecific rearrangement
Rick L. Coffin, William W. Cox, Robert G. Carlson, and Richard S. Givens
pp 3261 - 3272; DOI:
10.1021/ja00506a021
PDF
Reactions of photoradicals with nitroxide spin labels
James R. Sheats and Harden M. McConnell
pp 3272 - 3277; DOI:
10.1021/ja00506a022
PDF
Products and transients in the photolysis of methylated 2-indanones. Observation and kinetics of o-xylylenes
K. Kamal De Fonseka, John J. McCullough, and A. John Yarwood
pp 3277 - 3282; DOI:
10.1021/ja00506a023
PDF
.alpha.'.beta. Elimination of carbanions derived from thioethers
Jean Francois Biellmann, Hugues d'Orchymont, and Jean Louis Schmitt
pp 3283 - 3288; DOI:
10.1021/ja00506a024
PDF
Separation of polar and resonance substituent effects in the reactions of acetophenones with bisulfite and of benzyl halides with nucleophiles
P. R. Young and W. P. Jencks
pp 3288 - 3294; DOI:
10.1021/ja00506a025
PDF
Prediction of SN2 transition state variation by the use of More O'Ferrall plots
J. Milton Harris, Steven G. Shafer, John R. Moffatt, and Allyn R. Becker
pp 3295 - 3300; DOI:
10.1021/ja00506a026
PDF
Heavy-atom isotope effects on the alkaline hydrolysis and hydrazinolysis of methyl benzoate
Marion H. O'Leary and John F. Marlier
pp 3300 - 3306; DOI:
10.1021/ja00506a027
PDF
Naphtho[1,8-c,d:4,5-c',d']bis[1,2,6]selenadiazine
M. L. Kaplan, R. C. Haddon, F. C. Schilling, J. H. Marshall, and F. B. Bramwell
pp 3306 - 3308; DOI:
10.1021/ja00506a028
PDF
Synthesis and reactivity of exo- and endo-bicyclo[2.1.0]pentan-5-ol and their derivatives
Joseph J. Tufariello, Arthur C. Bayer, and Joseph J. Spadaro
pp 3309 - 3315; DOI:
10.1021/ja00506a029
PDF
Synthesis and stereomutation of 5-substituted bicyclo[2.1.0]pentanes
Joseph J. Tufariello, Jun Hsin Chang, and Arthur C. Bayer
pp 3315 - 3324; DOI:
10.1021/ja00506a030
PDF
Cycloaddition reactions of stilbene-electron-poor-alkene exciplexes
B. S. Green, M. Rejto, D. E. Johnson, C. E. Hoyle, J. T. Simpson, P. E. Correa, T. I. Ho, F. McCoy, and F. D. Lewis
pp 3325 - 3331; DOI:
10.1021/ja00506a031
PDF
Electron transfer processes. 20. Conversion to p,p'-dinitrostilbene and other examples of the SRN1 substitution reactions of p-nitrobenzyl derivatives
Glen A. Russell and Joseph M. Pecoraro
pp 3331 - 3334; DOI:
10.1021/ja00506a032
PDF
Electrochemical behavior of cytochrome c3 of Desulfovibrio vulgaris, strain Miyazaki, on the mercury electrode
Katsumi Niki, Tatsuhiko Yagi, Hiroo Inokuchi, and Keisaku Kimura
pp 3335 - 3340; DOI:
10.1021/ja00506a033
PDF
Isoprene synthons. Silicon- and tin-mediated terpene synthesis
Stephen R. Wilson, Lawrence R. Phillips, and Kenneth J. Natalie
pp 3340 - 3344; DOI:
10.1021/ja00506a034
PDF
Structure of ionomycin - a novel diacidic polyether antibiotic having high affinity for calcium ions
Barbara K. Toeplitz, Allen I. Cohen, Phillip T. Funke, William L. Parker, and Jack Z. Gougoutas
pp 3344 - 3353; DOI:
10.1021/ja00506a035
PDF
A novel zwitterionic structure and an unusual sugar ring conformation in 5-iodo-5'-amino-2',5'-dideoxyuridine, an antiviral nucleoside
George I. Birnbaum, Tai-Shun Lin, George T. Shiau, and William H. Prusoff
pp 3353 - 3358; DOI:
10.1021/ja00506a036
PDF
Biosynthesis of camptothecin. 3. Definition of strictosamide as the penultimate biosynthetic precursor assisted by carbon-13 and deuterium NMR spectroscopy
C. Richard Hutchinson, Amos H. Heckendorf, John L. Straughn, Peter E. Daddona, and David E. Cane
pp 3358 - 3369; DOI:
10.1021/ja00506a037
PDF
Intermediacy of tetracyclo[3.2.0.02.7.04.6]hept-1(7)-ene, a highly strained bridgehead olefin
Joachim Harnisch, Otto Baumgaertel, Guenter Szeimies, Maurice Van Meerssche, Gabriel Germain, and Jean Paul Declercq
pp 3370 - 3371; DOI:
10.1021/ja00506a038
PDF
Disproportionation of a neutral metal-formyl complex and synthesis of a stable hydroxymethyl-metal compound
Charles P. Casey, Mark A. Andrews, and Donald R. McAlister
pp 3371 - 3373; DOI:
10.1021/ja00506a039
PDF
A new strategy for gibberellin synthesis
Lewis N. Mander and Stephen G. Pyne
pp 3373 - 3375; DOI:
10.1021/ja00506a040
PDF
Isolation and x-ray study of a host-guest complex of an amino acid ester salt and a simple acyclic ligand derived from triphenylphosphine oxide
Albert H. Alberts, Klaas Timmer, Jan G. Noltes, and Antony L. Spek
pp 3375 - 3376; DOI:
10.1021/ja00506a041
PDF
Resonance Raman evidence for charge-transfer interactions of phenols with the flavin mononucleotide of Old Yellow Enzyme
Teizo Kitagawa, Yasuzo Nishina, Kiyoshi Shiga, Hiroshi Watari, Yuichi Matsumura, and Toshio Yamano
pp 3376 - 3378; DOI:
10.1021/ja00506a042
PDF
Electron transfer processes. 21. The use of .alpha.-halo nitroalkanes as ketone equivalents in condensation reactions
Glen A. Russell, Mikolaj Jawdosiuk, and Francisco Ros
pp 3378 - 3379; DOI:
10.1021/ja00506a043
PDF
Formation of bis[bis(3,5-di-tert-butylcatecholato)oxomolybdenum(VI)] and related stable molybdenum-catechol complexes
John P. Wilshire, Luis Leon, Paula Bosserman, and Donald T. Sawyer
pp 3379 - 3381; DOI:
10.1021/ja00506a044
PDF
Bimetallic copper(I) and -(II) macrocyclic complexes as mimics for type 3 copper pairs in copper enzymes
Y. Agnus, R. Louis, and R. Weiss
pp 3381 - 3384; DOI:
10.1021/ja00506a045
PDF
Fluoroxysulfate: a powerful new oxidant and fluorinating agent
Evan H. Appelman, Louis J. Basile, and Richard C. Thompson
pp 3384 - 3385; DOI:
10.1021/ja00506a046
PDF
The enzymic conversion of farnesyl to nerolidyl pyrophosphate: role of the pyrophosphate moiety
David E. Cane and Radha Iyengar
pp 3385 - 3388; DOI:
10.1021/ja00506a047
PDF
Reactions of organocyclopropanes and spirocycles with metal atoms
J. A. Gladysz, J. G. Fulcher, R. C. Ugolick, A. J. Lee Hanlan, and A. B. Bocarsly
pp 3388 - 3390; DOI:
10.1021/ja00506a048
PDF
Photochemical transformations of small ring compounds. 104. Stereochemical course of the thermal and photosensitized intramolecular [2 + 2] cycloaddition reaction of allyl-substituted cyclopropenes
Albert Padwa and Thomas J. Blacklock
pp 3390 - 3392; DOI:
10.1021/ja00506a049
PDF
Reaction of [Fe(SC6H5)4]2- with organic trisulfides and implications concerning the biosynthesis of ferredoxins. Synthesis and structure of the [(C6H5)4P]2Fe2S12 complex
D. Coucouvanis, D. Swenson, P. Stremple, and N. C. Baenziger
pp 3392 - 3394; DOI:
10.1021/ja00506a050
PDF
Peptide synthesis in water and the use of immobilized carboxypeptidase Y for deprotection
Garfield P. Royer and G. M. Anantharmaiah
pp 3394 - 3396; DOI:
10.1021/ja00506a051
PDF
Kinetics of carbon monoxide binding to Fe(TPP)(Im) and Fe(TPP)(Im-): evidence regarding protein control of heme reactivity
James C. Swartz, Marlene A. Stanford, James N. Moy, Brian M. Hoffman, and Joan S. Valentine
pp 3396 - 3398; DOI:
10.1021/ja00506a052
PDF
Matrix isolation of a triplet biradical from a carbene precursor
Matthew S. Platz
pp 3398 - 3399; DOI:
10.1021/ja00506a053
PDF
Redox properties of small metallocarborane clusters: electrochemistry of cobalt triple-decker sandwich compounds
David E. Brennan and William E. Geiger
pp 3399 - 3400; DOI:
10.1021/ja00506a054
PDF
Mapping of cocaine and cinnamoylcocaine in whole coca plant tissues by MIKES
M. Youssefi, R. G. Cooks, and J. L. McLaughlin
pp 3400 - 3402; DOI:
10.1021/ja00506a055
PDF
The structure of asukamycin, a possible shunt metabolite from 3-dehydroquinic acid in the shikimate pathway
Katsumi Kakinuma, Nobuo Ikekawa, Akira Nakagawa, and Satoshi Omura
pp 3402 - 3404; DOI:
10.1021/ja00506a056
PDF
Zoapatanol and montanol, novel oxepane diterpenoids, from the Mexican plant zoapatle (Montanoa tomentosa)
Seymour D. Levine, Richard E. Adams, Robert Chen, Mary Lou Cotter, Allen F. Hirsch, Vinayak V. Kane, Ramesh M. Kanojia, Charles Shaw, Michael P. Wachter, and et al.
pp 3404 - 3405; DOI:
10.1021/ja00506a057
PDF
Preparation and properties of molybdenum- and tungsten-dinitrogen complexes. 10. Conversion of ligating dinitrogen into hydrazine with hydrazido(1-) complexes as intermediates
Tamotsu Takahashi, Yasushi Mizobe, Maki Sato, Yasuzo Uchida, and Masanobu Hidai
pp 3405 - 3407; DOI:
10.1021/ja00506a058
PDF
Structural consequences of electron-transfer reactions. 3. Electrochemical isomerization of a metal-hydrocarbon bond in the reduction of cyclopentadienylcobalt cyclooctatetraene
Jerry Moraczewski and William E. Geiger
pp 3407 - 3408; DOI:
10.1021/ja00506a059
PDF
Fluorescence lifetime of all-trans-retinal at 77 K
Robert D. Fugate and Pill-Soon Song
pp 3408 - 3409; DOI:
10.1021/ja00506a060
PDF
Quinuclidin-4-yl
Shelton Bank, William K. S. Cleveland, D. Griller, and K. U. Ingold
pp 3409 - 3411; DOI:
10.1021/ja00506a061
PDF
Organic photochemistry with 6.7-eV photons: bicyclo[4.1.0]hept-3-ene. Internal transfer and carryover of electronic energy
R. Srinivasan and J. A. Ors
pp 3411 - 3412; DOI:
10.1021/ja00506a062
PDF
Reaction of iron(III) porphyrins and iodosoxylene. The active oxene complex of cytochrome P-450
C. K. Chang and Ming-Shang Kuo
pp 3413 - 3415; DOI:
10.1021/ja00506a063
PDF
Nonconjugated charge delocalization by remote .pi. electrons via relay through a double bond proximate to a solvolysis center
Evan L. Allred, Gregory D. Lyon, and Gary Stroebel
pp 3415 - 3416; DOI:
10.1021/ja00506a064
PDF
Photochemical cyanation of acetophenones. Acetyl displacement
Andrew L. Colb
pp 3416 - 3418; DOI:
10.1021/ja00506a065
PDF
Book Reviews

pp 3418 - 3424; DOI:
10.1021/ja00506a600
PDF

Issue 13


Electronic properties of bis(.eta.5-cyclopentadienyl)titanium 2,2'-bipyridyl. A singlet molecule with a low-lying triplet excited state
Arlene Mootz McPherson, Benjamin F. Fieselmann, Dennis L. Lichtenberger, Gary L. McPherson, and Galen D. Stucky
pp 3425 - 3430; DOI:
10.1021/ja00507a001
PDF
Heterogeneous and homogeneous electron transfers to aromatic halides. An electrochemical redox catalysis study in the halobenzene and halopyridine series
Claude P. Andrieux, Claude Blocman, Jean Michel Dumas-Bouchiat, and Jean Michel Saveant
pp 3431 - 3441; DOI:
10.1021/ja00507a002
PDF
An x-ray photoelectron spectroscopic study of multilayers of an electroactive ferrocene derivative attached to platinum and gold electrodes
Alan B. Fischer, Mark S. Wrighton, M. Umana, and Royce W. Murray
pp 3442 - 3446; DOI:
10.1021/ja00507a003
PDF
Spectra of the H2 phthalocyanine in low-temperature matrixes
V. E. Bondybey and J. H. English
pp 3446 - 3450; DOI:
10.1021/ja00507a004
PDF
Polymeric ligands as anchoring groups for the attachment of metal complexes to graphite electrode surfaces
Noboru Oyama and Fred C. Anson
pp 3450 - 3456; DOI:
10.1021/ja00507a005
PDF
M3L9(ligand) complexes
Birgitte E. R. Schilling and Roald Hoffmann
pp 3456 - 3467; DOI:
10.1021/ja00507a006
PDF
Metal-rare gas interaction. A new bond?
J. Demuynck, E. Kochanski, and A. Veillard
pp 3467 - 3472; DOI:
10.1021/ja00507a007
PDF
Reactions of methyl cations with methylsilanes
G. W. Goodloe, E. R. Austin, and F. W. Lampe
pp 3472 - 3478; DOI:
10.1021/ja00507a008
PDF
Theoretical investigations on carbocations. Structure and stability of C3H5+,C4H9+(2-butyl cation), C5H5+,C6H7+(protonated benzene), and C7H11+(2-norbornyl cation)
Hans Joachim Koehler and Hans Lischka
pp 3479 - 3486; DOI:
10.1021/ja00507a009
PDF
Nitrosoacetaldehyde and its enol and oxime isomers. A theoretical investigation of an asymmetric 1,5-sigmatropic hydrogen shift
Willem J. Bouma and Leo Radom
pp 3487 - 3490; DOI:
10.1021/ja00507a010
PDF
Protonation and proton affinity of anisole. A theoretical study
J. Catalan and M. Yanez
pp 3490 - 3492; DOI:
10.1021/ja00507a011
PDF
An ab initio study of the cis-trans photoisomerization of stilbene
G. Orlandi, P. Palmieri, and G. Poggi
pp 3492 - 3497; DOI:
10.1021/ja00507a012
PDF
Ab initio investigation of the electronic properties of cyclopropyl, .alpha.-fluorocyclopropyl, and .alpha.-chlorocyclopropyl anions
J. Tyrrell, V. M. Kolb, and C. Y. Meyers
pp 3497 - 3500; DOI:
10.1021/ja00507a013
PDF
Infrared spectra, structure, and bonding in the dihalocarbene cations in solid argon
Lester Andrews and Brian W. Keelan
pp 3500 - 3504; DOI:
10.1021/ja00507a014
PDF
Selective naked-cluster cryophotochemistry and SCF-X.alpha.-SW calculations for copper (Cu2) and silver (Ag2)
Geoffrey A. Ozin, Helmut Huber, Douglas McIntosh, Steven Mitchell, Joe G. Norman, and Louis Noodleman
pp 3504 - 3511; DOI:
10.1021/ja00507a015
PDF
Macrocyclic ligand complexation kinetics. Solvent, ring size, and macrocyclic effects on the formation and dissociation reactions of copper(II)-cyclic polythiaether complexes
Leonard L. Diaddario, L. Lawrence Zimmer, Thomas E. Jones, Lucia S. W. L. Sokol, Renato B. Cruz, Edmund L. Yee, L. A. Ochrymowycz, and D. B. Rorabacher
pp 3511 - 3520; DOI:
10.1021/ja00507a016
PDF
Preparation of organoaluminum compounds by hydrozirconation-transmetalation
Denise B. Carr and Jeffrey Schwartz
pp 3521 - 3531; DOI:
10.1021/ja00507a017
PDF
Resonance Raman spectra, excitation profiles and excited (iron .fwdarw. pyridine charge transfer) state geometry of bispyridine iron(II) heme
P. G. Wright, P. Stein, J. M. Burke, and T. G. Spiro
pp 3531 - 3535; DOI:
10.1021/ja00507a018
PDF
.eta.5-Cyclohexadienyltricarbonylchromium(0) complexes from addition of carbon nucleophiles to .eta.6-benzenetricarbonylchromium(0). Formation, chemical and spectroscopic features, and x-ray diffraction analysis
M. F. Semmelhack, H. T. Hall, R. Farina, M. Yoshifuji, G. Clark, T. Bargar, K. Hirotsu, and J. Clardy
pp 3535 - 3544; DOI:
10.1021/ja00507a019
PDF
Host-guest complexation. 15. Macrocyclic acetylacetone ligands for metal cations
Albert H. Alberts and Donald J. Cram
pp 3545 - 3553; DOI:
10.1021/ja00507a020
PDF
Host-guest complexation. 16. Synthesis and cation binding characteristics of macrocyclic polyethers containing convergent methoxyaryl groups
Karl E. Koenig, George M. Lein, Peter Stuckler, Takahiro Kaneda, and Donald J. Cram
pp 3553 - 3566; DOI:
10.1021/ja00507a021
PDF
Cytochalasin support studies. Macrocycle synthesis via enolate-assisted, intraannular 1,4-fragmentation reactions
David A. Clark and Philip L. Fuchs
pp 3567 - 3576; DOI:
10.1021/ja00507a022
PDF
Mechanism of the Cannizzaro reaction
C. Gardner Swain, Arnet L. Powell, William A. Sheppard, and Charles R. Morgan
pp 3576 - 3583; DOI:
10.1021/ja00507a023
PDF
Reduction of benzaldehyde by methoxide ion in aqueous methanol
C. Gardner Swain, Arnet L. Powell, Thomas J. Lynch, Sigma R. Alpha, and Richard P. Dunlap
pp 3584 - 3587; DOI:
10.1021/ja00507a024
PDF
Eliminations forming carbon-heteroatom multiple bonds. Base-promoted dehydrochlorination of N-chlorobenzylmethylamines
Richard A. Bartsch and Bong Rae Cho
pp 3587 - 3591; DOI:
10.1021/ja00507a025
PDF
Hydrogen atom exchange between nitroxides and hydroxylamines
Martin A. Schwartz, J. Wallace Parce, and Harden M. McConnell
pp 3592 - 3595; DOI:
10.1021/ja00507a026
PDF
Sulfuranes. 39. Syntheses and structure studies of stable difluoro- and dichlorosulfuranes. Apicophilicity orders in sulfuranes
Larry D. Martin, Edmund F. Perozzi, and J. C. Martin
pp 3595 - 3602; DOI:
10.1021/ja00507a027
PDF
Synthesis of alkenes by reductive elimination of .beta.-hydroxysulfoximines
Carl R. Johnson and Robert A. Kirchhoff
pp 3602 - 3607; DOI:
10.1021/ja00507a028
PDF
Excited-state chemistry of 1-alkenyl-2-pyridones. Exploratory and mechanistic investigations and kinetic analysis of photocyclization reactions involving conversion of the N-vinylamide to oxazolium ylide function
Patrick S. Mariano and Andrea A. Leone
pp 3607 - 3617; DOI:
10.1021/ja00507a029
PDF
Proton and carbon-13 nuclear magnetic resonance spectra of dimethylnaphthalenium ions. Calculation on the site of protonation and correlation between carbon-13 chemical shifts and electron density by the Hueckel MO method
Koop Lammertsma and Hans Cerfontain
pp 3618 - 3624; DOI:
10.1021/ja00507a030
PDF
Electron transfer reactions involving porphyrins and chlorophyll a
P. Neta, A. Scherz, and Haim Levanon
pp 3624 - 3629; DOI:
10.1021/ja00507a031
PDF
Total synthesis of optically pure nucleoside Q. Determination of absolute configuration of natural nucleoside Q
Tadaaki Ohgi, Tadao Kondo, and Toshio Goto
pp 3629 - 3633; DOI:
10.1021/ja00507a032
PDF
Solvent deuterium isotope effect on the liver alcohol dehydrogenase reaction
Jack Schmidt, Judy Chen, Michael DeTraglia, Daniel Minkel, and James T. McFarland
pp 3634 - 3640; DOI:
10.1021/ja00507a033
PDF
Kinetic and thermodynamic study of the specificity in the elementary steps of .alpha.-chymotrypsin-catalyzed hydrolysis reaction
Shigeru Kunugi, Hideo Hirohara, and Norio Ise
pp 3640 - 3646; DOI:
10.1021/ja00507a034
PDF
Diazocarbonyl compounds and 1-diethylaminopropyne
Rolf Huisgen, Hans Ulrich Reissig, and Helmut Huber
pp 3647 - 3648; DOI:
10.1021/ja00507a035
PDF
Conducted tour mechanism of ester group migration in a 3H-pyrazole
Hans Ulrich Reissig and Rolf Huisgen
pp 3648 - 3649; DOI:
10.1021/ja00507a036
PDF
Intramolecular energy-transfer reactions in mixed metal dimers. (NH3)5RuIILRhIII(NH3)5
Janette A. Gelroth, Joseph E. Figard, and John D. Petersen
pp 3649 - 3651; DOI:
10.1021/ja00507a037
PDF
1,6-Diazabicyclo[4.4.4]tetradecane and its oxidized ions
R. W. Alder and R. B. Sessions
pp 3651 - 3652; DOI:
10.1021/ja00507a038
PDF
Inside- and outside-protonated ions from 1,6-diazabicyclo[4.4.4]tetradecane
Roger W. Alder, Alan Casson, and Richard B. Sessions
pp 3652 - 3653; DOI:
10.1021/ja00507a039
PDF
Cytochrome c models
Toshio Mashiko, Jean Claude Marchon, Donald T. Musser, Christopher A. Reed, Margaret E. Kastner, and W. Robert Scheidt
pp 3653 - 3655; DOI:
10.1021/ja00507a040
PDF
20-Methylsirohydrochlorin. A revised structure for a trimethylisobacteriochlorin intermediate (factor III) in the biosynthesis of vitamin B12
G. Mueller, K. D. Gneuss, H. P. Kriemler, A. I. Scott, and A. J. Irwin
pp 3655 - 3657; DOI:
10.1021/ja00507a041
PDF
Planar s-cis-1,3-butadiene
M. E. Squillacote, R. S. Sheridan, O. L. Chapman, and F. A. L. Anet
pp 3657 - 3659; DOI:
10.1021/ja00507a042
PDF
Equilibrium between metallaindans and aryne olefin-metal complexes
Gerhard Erker and Kurt Kropp
pp 3659 - 3660; DOI:
10.1021/ja00507a043
PDF
Non-bromide(1-) ion-controlled oscillations in the Belousov-Zhabotinskii reaction of malonic acid
Zoltan Noszticzius
pp 3660 - 3663; DOI:
10.1021/ja00507a044
PDF
Thermal decomposition of cis-tetrahydropyridazine-3,4-d2. Relative rates of rotation, cleavage, and closure for tetramethylene
Donald S. Santilli and Peter B. Dervan
pp 3663 - 3664; DOI:
10.1021/ja00507a045
PDF
Molecular recognition of nucleic acid by small molecules. Binding affinity and structural specificity of bis(methidium)spermine
Michael McClellan Becker and Peter B. Dervan
pp 3664 - 3666; DOI:
10.1021/ja00507a046
PDF
Mode of nucleophilic addition to epichlorohydrin and related species: chiral aryloxymethyloxiranes
D. E. McClure, B. H. Arison, and J. J. Baldwin
pp 3666 - 3668; DOI:
10.1021/ja00507a047
PDF
A manganese phthalocyanine-dioxygen molecular adduct
A. B. P. Lever, J. P. Wilshire, and S. K. Quan
pp 3668 - 3669; DOI:
10.1021/ja00507a048
PDF
Azetidine-2,4-diones via photoinduced ring contraction of succinimides
Kazuhiro Maruyama, Takeshi Ishitoku, and Yasuo Kubo
pp 3670 - 3671; DOI:
10.1021/ja00507a049
PDF
S1 vs. T2 photoreactivity of .beta.,.gamma.-unsaturated ketones. Temperature dependent photo-CIDNP of 2-cyclopentenyl methyl ketones
Andreas Henne, Nancy P. Y. Siew, and Kurt Schaffner
pp 3671 - 3673; DOI:
10.1021/ja00507a050
PDF
Valence electrons in open-shell molecules: experimental studies using polarized neutron scattering
Brian N. Figgis, Ronald Mason, Andrew R. P. Smith, and Geoffrey A. Williams
pp 3673 - 3675; DOI:
10.1021/ja00507a051
PDF
Photochemical probes for model membrane structures
Michael F. Czarniecki and Ronald Breslow
pp 3675 - 3676; DOI:
10.1021/ja00507a052
PDF
Arylcyclopropane photochemistry. Substituent effects on the photochemical cyclopropylcarbinyl-homoallyl rearrangement of 2-arylcyclopropylcarbinyl acetates
Stephen S. Hixson, Jeffrey A. Gere, and Lothar A. Franke
pp 3677 - 3679; DOI:
10.1021/ja00507a053
PDF
Evidence for diastereomers of the [platinum(N,N,N',N'-tetramethylethylenediamine)(guanosine)2]2+ cation
Roger E. Cramer and Phillip L. Dahlstrom
pp 3679 - 3681; DOI:
10.1021/ja00507a054
PDF
Bis(tetramethylammonium) tris(sorbitolato)manganate(IV), an EPR-active monomeric complex of manganese(IV)
David T. Richens and Donald T. Sawyer
pp 3681 - 3683; DOI:
10.1021/ja00507a055
PDF
Water-soluble complexes of tertiary phosphines and rhodium(I) as homogeneous catalysts
Ralph G. Nuzzo, David Feitler, and George M. Whitesides
pp 3683 - 3685; DOI:
10.1021/ja00507a056
PDF
Intramolecular ion solvation effects on gas-phase acidities and basicities. A new stereochemical probe in mass spectrometry
F. J. Winkler and D. Stahl
pp 3685 - 3687; DOI:
10.1021/ja00507a057
PDF
Surprising synthesis and reactivity of an acidic hydroxyphosphorane
Yoffi Segall and Itshak Granoth
pp 3687 - 3688; DOI:
10.1021/ja00507a058
PDF
The bihydroxide (H3O2-) anion. A very short, symmetric hydrogen bond
Kamal Abu-Dari, Kenneth N. Raymond, and Derek P. Freyberg
pp 3688 - 3689; DOI:
10.1021/ja00507a059
PDF
The role of .alpha. and .beta. fluorine in product determination of fluoro olefin-tertiary phosphine reactions. Ylide vs. vinylphosphorane formation
Donald J. Burton, Seiji Shinya, and Richard D. Howells
pp 3689 - 3690; DOI:
10.1021/ja00507a060
PDF
3-Pyridylmethylene: infrared spectrum and photochemistry
O. L. Chapman and R. S. Sheridan
pp 3690 - 3692; DOI:
10.1021/ja00507a061
PDF
Spin trapping in electrochemistry. 1. Electrooxidation of organoborides
Eric E. Bancroft, Henry N. Blount, and Edward G. Janzen
pp 3692 - 3694; DOI:
10.1021/ja00507a062
PDF
Photosynthesis of polyatomic organic molecules from carbon dioxide and water by the photocatalytic action of visible-light-illuminated platinized chlorophyll a dihydrate polycrystals
D. R. Fruge, G. D. Fong, and F. K. Fong
pp 3694 - 3697; DOI:
10.1021/ja00507a063
PDF
A method for determining the spatial distribution of spin-labeled organic ligands covalently bound to a noncrystalline surface: dipolar contribution to nitroxide EPR spectrum
Laurance D. Hall and John C. Waterton
pp 3697 - 3698; DOI:
10.1021/ja00507a064
PDF
Sequential oscillations in mixed-substrate Belousov-Zhabotinskii systems
Edwin J. Heilweil, Michael J. Henchman, and Irving R. Epstein
pp 3698 - 3700; DOI:
10.1021/ja00507a065
PDF
Laser-induced infrared multiphoton isomerization of hexadienes
James L. Buechele, Eric Weitz, and Frederick D. Lewis
pp 3700 - 3701; DOI:
10.1021/ja00507a066
PDF
Magnetic field effects on the thermolysis of endoperoxides of aromatic compounds. Correlations with singlet oxygen yield and activation entropies
Nicholas J. Turro and Ming-Fea Chow
pp 3701 - 3703; DOI:
10.1021/ja00507a067
PDF
A synthetic amphiphilic helical docosapeptide with the surface properties of plasma apolipoprotein A-I
Daikichi Fukushima, Josh P. Kupferberg, Shinji Yokoyama, Daniel J. Kroon, E. T. Kaiser, and F. J. Kezdy
pp 3703 - 3704; DOI:
10.1021/ja00507a068
PDF
N-Phenylselenophthalimide (N-PSP) and N-phenylselenosuccinimide (N-PSS). Two versatile carriers of the phenylseleno group. Oxyselenation of olefins and a selenium-based macrolide synthesis
K. C. Nicolaou, D. A. Claremon, W. E. Barnette, and S. P. Seitz
pp 3704 - 3706; DOI:
10.1021/ja00507a069
PDF
Additions and Corrections - Steric and Electronic Effects on 15N Chemical Shifts of Saturated Aliphatic Amines and Their Hydrochlorides
Rudolph O. Duthaler, and John D. Roberts
pp 3706 - 3706; DOI:
10.1021/ja00507a601
PDF
Additions and Corrections - Structures and Energetics of Planar and Tetrahedral Dilithiomethane. A Near Degeneracy of Singlet and Triplet Electronic States.
William D. Laidig, and Henry F. Schaefer
pp 3706 - 3706; DOI:
10.1021/ja00507a602
PDF
Additions and Corrections - Reactivity in Methyl Reactions. 3. Equilibria and Rates in Transfers between Substituted Thiophenoxides.
Edward S. Lewis, and Semyon Kukes
pp 3706 - 3707; DOI:
10.1021/ja00507a603
PDF
Additions and Corrections - Structures and Mass Spectral Behavior of the Inositol Cyclic Boronic Esters
Jacek Wiecko, and William R. Sherman
pp 3707 - 3707; DOI:
10.1021/ja00507a604
PDF
Additions and Corrections - Nonchair Conformations in Phosphorus-Containing Cyclohexanes. Crystal and Molecular Structures of cis- and trans-2-Phenyl-2-oxo-5-tert-butyl-1,3,2-dithiaphosphorinanes and cis-2-Phenyl-5-tert-butyl-1,3,2-dithiaphosphorinane
Robert O. Hutchins, Bruce E. Maryanoff, Mario J. Castillo, Karl D. Hargrave, and Andrew T. McPhail
pp 3707 - 3707; DOI:
10.1021/ja00507a605
PDF
Additions and Corrections - A Pair-Specific Osmium Reagent for Polynucleotides
H. Ford, C.-H. Chang, and E. J. Behrman
pp 3707 - 3707; DOI:
10.1021/ja00507a606
PDF
Book Reviews

pp 3707 - 3708; DOI:
10.1021/ja00507a600
PDF

Issue 14


Negative ion-molecule reactions in sulfuryl halides
Richard Robbiani and J. L. Franklin
pp 3709 - 3715; DOI:
10.1021/ja00508a001
PDF
Gas phase nucleophilic displacement reactions of negative ions with carbonyl compounds
Olabode I. Asubiojo and John I. Brauman
pp 3715 - 3724; DOI:
10.1021/ja00508a002
PDF
An experimental study of the gas-phase kinetics of reactions with hydrated hydronium(1+) ions(n = 1-3) at 298 K
D. K. Bohme, G. I. Mackay, and S. D. Tanner
pp 3724 - 3730; DOI:
10.1021/ja00508a003
PDF
An electron-diffraction investigation of the molecular structure of gaseous 2,3-butanedione (biacetyl) at 228 and 525.degree.C
Donald D. Danielson and Kenneth Hedberg
pp 3730 - 3734; DOI:
10.1021/ja00508a004
PDF
Solvatochromic comparison methods. 13. Linear solvation energy relationship. 5. Correlations between infrared .DELTA..nu. values and the .beta. scale of hydrogen bond acceptor basicities
Mortimer J. Kamlet, Abraham Solomonovici, and R. W. Taft
pp 3734 - 3739; DOI:
10.1021/ja00508a005
PDF
Conformation of 3'-nucleotides. Crystal structure of uncharged 3'-uridine monophosphate monohydrate and hydrogen bonding to the furanose ring oxygen
T. Srikrishnan, Susan M. Fridey, and R. Parthasarathy
pp 3739 - 3744; DOI:
10.1021/ja00508a006
PDF
Dynamics of nonadiabatic atom transfer in biological systems. Carbon monoxide binding to hemoglobin
Joshua Jortner and Jens Ulstrup
pp 3744 - 3754; DOI:
10.1021/ja00508a007
PDF
Structural, kinetic, and mechanistic aspects of cation complexation by cyclo-(L-Pro-L-Val-D-Ala-D-Val)3
D. G. Davis and B. F. Gisin
pp 3755 - 3762; DOI:
10.1021/ja00508a008
PDF
Barriers to rotation of methyl groups in 9-methyltriptycene and 9-methyl-,9,10-dihydro-9,10-ethenoanthracene
Fumio Imashiro, Takehiko Terao, and A. Saika
pp 3762 - 3766; DOI:
10.1021/ja00508a009
PDF
Internal rotation in biacetyl. A theoretical study
James Tyrrell
pp 3766 - 3768; DOI:
10.1021/ja00508a010
PDF
Do ozone-olefin complexes really exist?
Bengt Nelander and Leif Nord
pp 3769 - 3770; DOI:
10.1021/ja00508a011
PDF
Potential surfaces for the planar cyclopentadienyl radical and cation
Weston Thatcher Borden and Ernest R. Davidson
pp 3771 - 3775; DOI:
10.1021/ja00508a012
PDF
Proton and carbon-13 nuclear magnetic resonance spectroscopy studies of aluminum halide-alkylpyridinium halide molten salts and their benzene solutions
J. Robinson, R. C. Bugle, H. L. Chum, D. Koran, and R. A. Osteryoung
pp 3776 - 3779; DOI:
10.1021/ja00508a013
PDF
A study of transient phenomena in the reactions of alkoxy radicals with triphenylphosphine and triphenylborane
D. Griller, K. U. Ingold, L. K. Patterson, J. C. Scaiano, and R. D. Small
pp 3780 - 3785; DOI:
10.1021/ja00508a014
PDF
Theoretical investigations on some C2SiH4 isomers
Jean Claude Barthelat, Georges Trinquier, and Guy Bertrand
pp 3785 - 3789; DOI:
10.1021/ja00508a015
PDF
Structures of mixed ligand sulfur-containing spirocyclic phosphoranes
Roberta O. Day, Arjun C. Sau, and Robert R. Holmes
pp 3790 - 3801; DOI:
10.1021/ja00508a016
PDF
Ethylene complexes. Bonding, rotational barriers, and conformational preferences
Thomas A. Albright, Roald Hoffmann, Jack C. Thibeault, and David L. Thorn
pp 3801 - 3812; DOI:
10.1021/ja00508a017
PDF
Polyene-ML2 and -ML4 complexes. Conformational preferences and barriers of rotation
Thomas A. Albright, Roald Hoffmann, Yuk-Ching Tse, and Ted D'Ottavio
pp 3812 - 3821; DOI:
10.1021/ja00508a018
PDF
M2L9 complexes
Richard H. Summerville and Roald Hoffmann
pp 3821 - 3831; DOI:
10.1021/ja00508a019
PDF
Chemical composition and crystal structure of graphite fluoride
Yasushi Kita, Nobuatsu Watanabe, and Yukio Fujii
pp 3832 - 3841; DOI:
10.1021/ja00508a020
PDF
An EDTA complex containing two triangular trimolybdenum clusters with molybdenum-molybdenum single bonds
Avi Bino, F. Albert Cotton, and Zvi Dori
pp 3842 - 3847; DOI:
10.1021/ja00508a021
PDF
Photoinduced fragmentation of dodecacarbonyltrihydrotrirhenium and dodecacarbonyltrihydrotrimanganese
Ronald A. Epstein, Thomas R. Gaffney, Gregory L. Geoffroy, Wayne L. Gladfelter, and Richard S. Henderson
pp 3847 - 3852; DOI:
10.1021/ja00508a022
PDF
Syntheses and electronic structures of decamethylmanganocenes
John L. Robbins, Norman M. Edelstein, Stephen R. Cooper, and James C. Smart
pp 3853 - 3857; DOI:
10.1021/ja00508a023
PDF
Substituent effects in the electroreduction of porphyrins and metalloporphyrins
A. Giraudeau, H. J. Callot, Joseph Jordan, I. Ezhar, and Maurice Gross
pp 3857 - 3862; DOI:
10.1021/ja00508a024
PDF
Acid- and base-catalyzed anti to syn isomerization of (dienone) tricarbonyliron compounds
John S. Frederiksen, Robert E. Graf, Douglas G. Gresham, and C. Peter Lillya
pp 3863 - 3867; DOI:
10.1021/ja00508a025
PDF
Electronic structure of tetrahedral carbonyls and dinitrogen complexes of nickel, cobalt, and iron as calculated by the multiple-scattering method
Manuel Braga, Sven Larsson, and Jose R. Leite
pp 3867 - 3873; DOI:
10.1021/ja00508a026
PDF
Metal atom synthesis of iron diene phosphite complexes
Steven D. Ittel, F. A. Van-Catledge, and J. P. Jesson
pp 3874 - 3884; DOI:
10.1021/ja00508a027
PDF
Phenylseleno- and phenylsulfenolactonizations. Two highly efficient and synthetically useful cyclization procedures
K. C. Nicolaou, S. P. Seitz, W. J. Sipio, and J. F. Blount
pp 3884 - 3893; DOI:
10.1021/ja00508a028
PDF
Conformation and Cope rearrangement of sym-oxepin oxides
William H. Rastetter and Thomas J. Richard
pp 3893 - 3897; DOI:
10.1021/ja00508a029
PDF
Quantitative prediction of structure-reactivity relationships for unimolecular reactions of unsaturated hydrocarbons. Development of a semiempirical model
Charles F. Wilcox and Barry K. Carpenter
pp 3897 - 3905; DOI:
10.1021/ja00508a030
PDF
Chemistry of 9-diazoxanthene and 9-xanthylidene
G. W. Jones, K. T. Chang, and H. Shechter
pp 3906 - 3916; DOI:
10.1021/ja00508a031
PDF
Solvent nucleophilicity. A scale based on triethyloxonium ion solvolysis
Dennis N. Kevill and Gloria Meichia L. Lin
pp 3916 - 3919; DOI:
10.1021/ja00508a032
PDF
Polymer-supported phase-transfer catalysts. High catalytic activity of ammonium and phosphonium quaternary salts bonded to a polystyrene matrix
Henriette Molinari, Fernando Montanari, Silvio Quici, and Pietro Tundo
pp 3920 - 3927; DOI:
10.1021/ja00508a033
PDF
Stereoelectronic control in the electrochemical and mercury-promoted reductive acetoxylation of .alpha.,.alpha.'-dibromobicycloalkanones
Albert J. Fry and Geoffrey S. Ginsburg
pp 3927 - 3932; DOI:
10.1021/ja00508a034
PDF
Stable carbocations. 221. Study of the highly strained bicyclo[1.1.1]pentyl cations under stable ion conditions
George A. Olah, G. K. Surya Prakash, and Gao Liang
pp 3932 - 3934; DOI:
10.1021/ja00508a035
PDF
Stable carbocations. 220. Carbon-13 NMR spectroscopic study of potential tris- and bishomocyclopropenyl cations
George A. Olah, G. K. Surya Prakash, Tarik N. Rawdah, David Whittaker, and John C. Rees
pp 3935 - 3939; DOI:
10.1021/ja00508a036
PDF
Carbon-13 NMR chemical shifts and transfer of carbon-13 spin saturation and the structures and rearrangements of 9-barbaralyl cations, protonated barbaralone, and barbaralone
Carin Engdahl and Per Ahlberg
pp 3940 - 3946; DOI:
10.1021/ja00508a037
PDF
Elucidation of stereochemistry of the carboxypeptidase A catalyzed enolization of 2-benzyl-3-p-methoxybenzoylpropionate, a ketone substrate
Takuji Sugimoto and E. T. Kaiser
pp 3946 - 3951; DOI:
10.1021/ja00508a038
PDF
Role of active-site residues in the catalytic mechanism of ribonuclease A
Carol A. Deakyne and Leland C. Allen
pp 3951 - 3959; DOI:
10.1021/ja00508a039
PDF
Water and related systems. 1. The hydronium ion (H3O+). Preparation and characterization by high resolution oxygen-17 nuclear magnetic resonance
Gheorghe D. Mateescu and George M. Benedikt
pp 3959 - 3960; DOI:
10.1021/ja00508a040
PDF
Two stable thiosulfuranes, CF3(CF3S)S[OC(CF3)3]2 and C6F5(C6F5S)S[OC(CF3)3]2
Qui Chee Mir, Daniel P. Babb, and Jean'ne M. Shreeve
pp 3961 - 3961; DOI:
10.1021/ja00508a041
PDF
Copper(I) catalysis of olefin photoreactions. 8. A stepwise olefin metathesis synthesis of cyclopent-2-en-1-ones via photobicyclization of 3-hydroxyhepta-1,6-dienes
Robert G. Salomon, Daniel J. Coughlin, and Eileen M. Easler
pp 3961 - 3963; DOI:
10.1021/ja00508a042
PDF
Sodium tetramolybdenum hexoxide (NaMo4O6). A metallic infinite-chain polymer derived by condensation of octahedral clusters
Charlie C. Torardi and Robert E. McCarley
pp 3963 - 3964; DOI:
10.1021/ja00508a043
PDF
Quaternary boron. 5. An unexpected hydride transfer reaction of hydridoborates. A convenient new route to highly hindered potassium trialkylhydridoborates
Charles Allan Brown and John L. Hubbard
pp 3964 - 3966; DOI:
10.1021/ja00508a044
PDF
Synthesis and structure of a 2-aminothiazolinecobalt(III) complex derived from (R)-cysteine
Graeme J. Gainsford, W. Gregory Jackson, and Alan M. Sargeson
pp 3966 - 3967; DOI:
10.1021/ja00508a045
PDF
Vinylic cations from solvolysis. 28. Solvent dependency of the solvolytic site of 9-(.alpha.-bromoanisylidene)-10-hydroxy-9,10-dihydroanthracene
Zvi Rappoport and Jeremy Greenblatt
pp 3967 - 3969; DOI:
10.1021/ja00508a046
PDF
Transient photocurrents and conversion losses in polysulfide-based photoelectrochemical cells
Dan Lando, Joost Manassen, Gary Hodes, and David Cahen
pp 3969 - 3971; DOI:
10.1021/ja00508a047
PDF
Preparation of a porphyrin-iron-carbene model for the cytochrome P 450 complexes obtained upon metabolic oxidation of the insecticide synergists of the 1,3-benzodioxole series
D. Mansuy, J. P. Battioni, J. C. Chottard, and V. Ullrich
pp 3971 - 3973; DOI:
10.1021/ja00508a048
PDF
Reaction of a metal alkyl with ethylene as a model for Ziegler-Natta polymerization. Evidence for the olefin insertion mechanism
Eric R. Evitt and Robert G. Bergmann
pp 3973 - 3974; DOI:
10.1021/ja00508a049
PDF
Titanium(III) porphyrins and their dioxygen adducts
Jean Marc Latour, Jean Claude Marchon, and Masayuki Nakajima
pp 3974 - 3976; DOI:
10.1021/ja00508a050
PDF
Detection of thiobenzoylphenylmethylene by electron spin resonance spectroscopy
H. Murai, M. Torres, and O. P. Strausz
pp 3976 - 3979; DOI:
10.1021/ja00508a051
PDF
Insertion of beryllium into a boron-boron bond. The synthesis of .mu.-[.eta.5-cyclopentadienylberylla]octahydropentaborate, .mu.-[.eta.5-(C5H5)Be]B5H8
Donald F. Gaines, Kraig M. Coleson, and Joseph C. Calabrese
pp 3979 - 3980; DOI:
10.1021/ja00508a052
PDF
NMR evidence for C3 ground-state conformations and multiple site exchange processes in systems of the type t-Bu3MX
R. J. Wroczynski and Kurt Mislow
pp 3980 - 3981; DOI:
10.1021/ja00508a053
PDF
Free-radical alkylthiylation of a pentacovalent phosphorus-hydrogen compound
Takayuki Kawashima and Wesley G. Bentrude
pp 3981 - 3982; DOI:
10.1021/ja00508a054
PDF
Synthesis of L-erythro-.beta.-hydroxyhistidine from D-glucosamine
Sidney M. Hecht, Kathleen M. Rupprecht, and Paula M. Jacobs
pp 3982 - 3983; DOI:
10.1021/ja00508a055
PDF
A facile synthesis of substituted N-hydroxy-2-azetidinones. A biogenetic type .beta.-lactam synthesis
Phillip G. Mattingly, James F. Kerwin, and Marvin J. Miller
pp 3983 - 3985; DOI:
10.1021/ja00508a056
PDF
Polymer-supported .eta.5-cyclopentadienylcobalt. An immobilized "homogeneous" Fischer-Tropsch catalyst
Patrick Perkins and K. Peter C. Vollhardt
pp 3985 - 3987; DOI:
10.1021/ja00508a057
PDF
Evidence for a possible trans oxidative addition of hydrogen to an iridium complex
John F. Harrod, Gordon Hamer, and William Yorke
pp 3987 - 3989; DOI:
10.1021/ja00508a058
PDF
Benzocyclobutenedione monoketal. A 1,4-dipole equivalent for anthracyclinone synthesis. Synthesis of (.+-.)-4-demethoxydaunomycinone
Daniel K. Jackson, Lakshmi Narasimhan, and John S. Swenton
pp 3989 - 3990; DOI:
10.1021/ja00508a059
PDF
Novel copper-pyridine catalyzed ring opening reactions of aryl oxiranes. An asymmetric synthesis of (+)-indene 1,2-oxide and (+)-cis-1,2-indandiol
Mitsuru Imuta and Herman Ziffer
pp 3990 - 3991; DOI:
10.1021/ja00508a060
PDF
Control elements in the intramolecular Diels-Alder reaction. Synthesis of (.+-.)-torreyol
Douglass F. Taber and Bruce P. Gunn
pp 3992 - 3993; DOI:
10.1021/ja00508a061
PDF
Electron-transfer reactions in the "abnormal" free-energy region
Jeffrey K. Nagle, Walter J. Dressick, and Thomas J. Meyer
pp 3993 - 3995; DOI:
10.1021/ja00508a062
PDF
Exciplex formation from transition-metal complexes. Luminescent nonpolar exciplexes from palladium(II) porphyrin triplets and N,N-dimethylaniline
Janet A. Mercer-Smith, Carol R. Sutcliffe, Russell H. Schmehl, and David G. Whitten
pp 3995 - 3997; DOI:
10.1021/ja00508a063
PDF
Thermally and photochemically induced shifts of silicon on the phenalene ring system
Jared A. Butcher and Richard M. Pagni
pp 3997 - 3998; DOI:
10.1021/ja00508a064
PDF
The infrared photodissociation of MeOHF-
Robert N. Rosenfeld, Joseph M. Jasinski, and John I. Brauman
pp 3999 - 4000; DOI:
10.1021/ja00508a065
PDF
Early events and transient chemistry in the photohomolysis of alkylcobalamins
John F. Endicott and T. L. Netzel
pp 4000 - 4002; DOI:
10.1021/ja00508a066
PDF
Flow tube measurement of the rate constants of the N(2D, 2P, and 4S) + Cl2 reactions
M. P. Iannuzzi and F. Kaufman
pp 4002 - 4003; DOI:
10.1021/ja00508a067
PDF
A versatile three-carbon annelation. Synthesis of cyclopentanones and cyclopentanone derivatives from olefins
Andrew E. Greene and Jean Pierre Depres
pp 4003 - 4005; DOI:
10.1021/ja00508a068
PDF
Cyclization of olefinic tosylhydrazones under acidic conditions. A facile synthesis of bicyclic azo compounds
R. Marshall Wilson and John W. Rekers
pp 4005 - 4007; DOI:
10.1021/ja00508a069
PDF
Applications of light-induced electron-transfer reactions. Coupling of hydrogen generation with photoreduction of ruthenium(II) complexes by triethylamine
Patricia J. DeLaive, B. P. Sullivan, T. J. Meyer, and D. G. Whitten
pp 4007 - 4008; DOI:
10.1021/ja00508a070
PDF
Orbital topology in a photochemical carbanionic ring opening
Marye Anne Fox
pp 4008 - 4010; DOI:
10.1021/ja00508a071
PDF
Formation of the Norrish type II products from the biacetyl-sensitized photolysis of valerophenone diperoxide
Yoshikatsu Ito, Teruo Matsuura, and Hiroaki Yokoya
pp 4010 - 4011; DOI:
10.1021/ja00508a072
PDF
Bromo-substituted physostigmine alkaloids from a marine bryozoa Flustra foliacea
Joergen S. Carle and Carsten Christophersen
pp 4012 - 4013; DOI:
10.1021/ja00508a073
PDF
A novel 30-membered synthetic macrolide from (+)-(1R,5R)-6,8-dioxabicyclo[3.2.1]octan-7-one
Masahiko Okada, Hiroshi Sumitomo, and Ichiro Tajima
pp 4013 - 4014; DOI:
10.1021/ja00508a074
PDF
Macrocyclic ring-size control of kinetic lability. Kinetics of dissociation of a range of nickel(II) complexes of O2N2- donor macrocycles in acid
A. Ekstrom, Leonard F. Lindoy, and Roland J. Smith
pp 4014 - 4016; DOI:
10.1021/ja00508a075
PDF
Photooxygenations in aqueous solution with a hydrophilic polymer-immobilized photosensitizer
A. Paul Schaap, Arthur L. Thayer, K. A. Zaklika, and Peter C. Valenti
pp 4016 - 4017; DOI:
10.1021/ja00508a076
PDF
4a-Hydroperoxyflavin N-oxidation of tertiary amines
Sheldon Ball and Thomas C. Bruice
pp 4017 - 4019; DOI:
10.1021/ja00508a077
PDF
Book Reviews

pp 4020 - 4022; DOI:
10.1021/ja00508a600
PDF

Issue 15


Characterization of surfactant vesicles as membrane mimetic agents. 1. Interactions and reactions of sodium 2,2,5,5-tetramethyl-1-pyrrolidinyloxy-3-carboxylate spin probe in sonicated dioctadecyldimethylammonium chloride
Yau Yan Lim and Janos H. Fendler
pp 4023 - 4029; DOI:
10.1021/ja00509a001
PDF
Characterization of surfactant vesicles as membrane mimetic agents. 2. Temperature-dependent changes of the turbidity, viscosity, fluorescence polarization of 2-methylanthracene, and positron annihilation in sonicated dioctadecyldimethylammonium chloride
Koji Kano, Alejandro Romero, Belkacem Djermouni, Hans J. Ache, and Janos H. Fendler
pp 4030 - 4037; DOI:
10.1021/ja00509a002
PDF
Assignments of proton nuclear magnetic resonances of the cystyl, asparaginyl, and aromatic residues of arginine vasopressin in water-d2. A comparison with lysine vasopressin and oxytocin in terms of solution conformation
Herman R. Wyssbrod, Alan J. Fischman, David H. Live, Victor J. Hruby, Nirankar S. Agarwal, and Donald A. Upson
pp 4037 - 4043; DOI:
10.1021/ja00509a003
PDF
Molecular structures of the dihydrodiols and diol epoxides of carcinogenic polycyclic aromatic hydrocarbons. X-ray crystallographic and NMR analysis
D. E. Zacharias, J. P. Glusker, P. P. Fu, and R. G. Harvey
pp 4043 - 4051; DOI:
10.1021/ja00509a004
PDF
Multinuclear NMR study of dibenzo-30-crown-10 complexes with sodium, potassium, and cesium ions in nonaqueous solvents
Mojtaba Shamsipur and Alexander I. Popov
pp 4051 - 4055; DOI:
10.1021/ja00509a005
PDF
J-Cross polarization in silanes
P. Dubois Murphy, T. Taki, T. Sogabe, R. Metzler, T. G. Squires, and B. C. Gerstein
pp 4055 - 4058; DOI:
10.1021/ja00509a006
PDF
Determination of NMR spin coupling constants using J-cross polarization. A comment on "J-Cross polarization in silanes
G. C. Chingas, R. D. Bertrand, A. N. Garroway, and W. B. Moniz
pp 4058 - 4059; DOI:
10.1021/ja00509a007
PDF
Liquid-solid-liquid triphase catalysis. Consideration of the rate-limiting step, role of stirring, and catalyst efficiency for simple nucleophilic displacement
Steven L. Regen and Jacques J. Besse
pp 4059 - 4063; DOI:
10.1021/ja00509a008
PDF
Structure of 1,2-difluorocyclopropane and the "cis effect"
Anne Skancke and James E. Boggs
pp 4063 - 4067; DOI:
10.1021/ja00509a009
PDF
Photoelectron spectroscopy of methyl, ethyl, isopropyl, and tert-butyl radicals. Implications for the thermochemistry and structures of the radicals and their corresponding carbonium ions
F. A. Houle and J. L. Beauchamp
pp 4067 - 4074; DOI:
10.1021/ja00509a010
PDF
A photoelectron spectroscopic-molecular orbital study of sulfur tetrafluoride and related fluorosulfuranes
A. H. Cowley, M. Lattman, and M. L. Walker
pp 4074 - 4080; DOI:
10.1021/ja00509a011
PDF
Molecular orbital investigation of multiply hydrogen bonded systems. Formic acid dimer and DNA base pairs
Steve Scheiner and C. W. Kern
pp 4081 - 4085; DOI:
10.1021/ja00509a012
PDF
Effect of electron correlation on theoretical equilibrium geometries
Douglas J. DeFrees, Beverly A. Levi, Steven K. Pollack, Warren J. Hehre, J. Stephen Binkley, and John A. Pople
pp 4085 - 4089; DOI:
10.1021/ja00509a013
PDF
Perturbation theory and "quasi-lone pairs" in main group angular and trigonal pyramidal compounds
Evgeny Shustorovich and Paul A. Dobosh
pp 4090 - 4095; DOI:
10.1021/ja00509a014
PDF
Ion-solvent interaction. Effects of added polar compounds on the conductances of lithium, sodium, and tributylammonium picrates in tetrahydrofuran at 25.degree.C
W. R. Gilkerson and M. D. Jackson
pp 4096 - 4100; DOI:
10.1021/ja00509a015
PDF
(Cross-conjugated dienyl)tricarbonyliron cations. 2. 4-Methyl derivatives
Benedict R. Bonazza, C. Peter Lillya, Elaine S. Magyar, and Gary Scholes
pp 4100 - 4106; DOI:
10.1021/ja00509a016
PDF
The design and mechanism of palladium catalysts for synthesis of methylene lactones by cyclocarbonylation of acetylenic alcohols
Timothy F. Murray and Jack R. Norton
pp 4107 - 4119; DOI:
10.1021/ja00509a017
PDF
Enthalpies of formation and solution of macrocyclic and noncyclic tetraaza ligands. Origins of the enthalpy term in the macrocyclic effect
R. M. Clay, M. Micheloni, P. Paoletti, and W. V. Steele
pp 4119 - 4122; DOI:
10.1021/ja00509a018
PDF
Photochemistry and electronic structure of bis(dicarbonyl(.eta.5-cyclopentadienyl)ruthenium) and its iron analog
Harmon B. Abrahamson, Michael C. Palazzotto, Carol L. Reichel, and Mark S. Wrighton
pp 4123 - 4127; DOI:
10.1021/ja00509a019
PDF
Synthesis and x-ray crystal structures of hexakis(trimethylphosphine)tris-.mu.-methylene-diruthenium(III) and its mono- and dicationic derivatives
Michael B. Hursthouse, Richard A. Jones, K. M. Abdul Malik, and Geoffrey Wilkinson
pp 4128 - 4139; DOI:
10.1021/ja00509a020
PDF
Synthetic approaches to the molybdenum site in nitrogenase. Preparation and structural properties of the molybdenum-iron-sulfur "double-cubane" cluster complexes [Mo2Fe6S8(SC2H5)9]3- and [Mo2Fe6S9(SC2H5)8]3-
Thomas E. Wolff, Jeremy M. Berg, Keith O. Hodgson, Richard B. Frankel, and R. H. Holm
pp 4140 - 4150; DOI:
10.1021/ja00509a021
PDF
A complex reaction product of dimolybdenum tetraacetate with aqueous hydrochloric acid. Structural characterization of the hydrido-bridged [Mo2Cl8H]3- ion, the [Mo(O)Cl4(H2O)]- ion, and an H5O2+ ion with an exceptionally short hydrogen bond
Avi Bino and F. Albert Cotton
pp 4150 - 4154; DOI:
10.1021/ja00509a022
PDF
Mercury-sensitized photolysis of small boranes and carboranes
Jeffrey S. Plotkin, Robert J. Astheimer, and Larry G. Sneddon
pp 4155 - 4163; DOI:
10.1021/ja00509a023
PDF
Histidine-containing ternary amino acid-copper(II) complexes. Syntheses and properties
Osamu Yamauchi, Takeshi Sakurai, and Akitsugu Nakahara
pp 4164 - 4172; DOI:
10.1021/ja00509a024
PDF
Tetracarbon metallocarboranes. 8. Structure of a 12-vertex arachno carborane, .sigma.-(.eta.5-C5H5)Co(.eta.5-C5H4)+-Me4C4B8H8-, an analog of B12H126- and C2B10H124-. Mechanisms of carborane fluxional behavior and metallocarborane formation from the Me4C4B8H82- ion
Russell N. Grimes, J. Robert Pipal, and Ekk Sinn
pp 4172 - 4180; DOI:
10.1021/ja00509a025
PDF
Blue copper proteins. Synthesis, chemistry, and spectroscopy of CuIN3(SR) and CuIIN3(SR) active site approximations. Crystal structure of potassium p-nitrobenzenethiolato(hydrotris(3,5-dimethyl-1-pyrazolyl)borato)cuprate(I) diacetone, K[Cu(HB(3,5-Me2pz)3)-(SC6H4NO2)].2C3H6O
Jeffery S. Thompson, Tobin J. Marks, and James A. Ibers
pp 4180 - 4192; DOI:
10.1021/ja00509a026
PDF
Synthesis, structure, and spectroscopy of pseudotetrahedral CoIIN3(SR) complexes. Active site approximations to the cobalt(II)-substituted type 1 copper proteins
Jeffery S. Thompson, Theophilus Sorrell, Tobin J. Marks, and James A. Ibers
pp 4193 - 4200; DOI:
10.1021/ja00509a027
PDF
.eta.3-Allyl metal hydride complexes. Oxidative addition of cyclopropane and olefin substrates to iridium(I) complexes. Structure of IrClH[.eta.3-C3H4(1-C6H5)][P(C6H5)3]2
Thomas H. Tulip and James A. Ibers
pp 4201 - 4211; DOI:
10.1021/ja00509a028
PDF
Hydration and reduction of carbon dioxide by rhodium hydride compounds. Preparation and reactions of rhodium bicarbonate and formate complexes, and the molecular structure of RhH2(O2COH)(P(i-Pr)3)2
T. Yoshida, David L. Thorn, T. Okano, James A. Ibers, and S. Otsuka
pp 4212 - 4221; DOI:
10.1021/ja00509a029
PDF
Stereoselectivity in ion-pair formation. 5. The contribution of the rotamers to the interaction of mono- and disubstituted succinate dianions with tris(ethylenediamine)cobalt(III)
Toshiaki Taura
pp 4221 - 4228; DOI:
10.1021/ja00509a030
PDF
Photobehavior of copper(I) compounds. Role of copper(I)-phosphine compounds in the photosensitized valence isomerization of norbornadiene
Paul A. Grutsch and Charles Kutal
pp 4228 - 4233; DOI:
10.1021/ja00509a031
PDF
Mechanism of rearrangement of platinacyclobutanes
Charles P. Casey, Daniel M. Scheck, and Alan J. Shusterman
pp 4233 - 4236; DOI:
10.1021/ja00509a032
PDF
Stereochemistry and mechanism of the reaction of LiCuMe2 with .beta.-cyclopropyl .alpha.,.beta.-unsaturated ketones
Charles P. Casey and Mark C. Cesa
pp 4236 - 4244; DOI:
10.1021/ja00509a033
PDF
Novel syntheses of mesoionic compounds and .alpha.-amino acid derivatives from acyltetracarbonylferrates
Howard Alper and Masato Tanaka
pp 4245 - 4249; DOI:
10.1021/ja00509a034
PDF
Polymeric pseudocrown ethers. 1. Synthesis and complexation with transition metal anions
Abraham Warshawsky, Rami Kalir, Abraham Deshe, Hedva Berkovitz, and Avraham Patchornik
pp 4249 - 4258; DOI:
10.1021/ja00509a035
PDF
Helical hydrocarbons capped by five-membered rings as precursors of polymeric metallocenes
Thomas J. Katz and Wojciech Slusarek
pp 4259 - 4267; DOI:
10.1021/ja00509a036
PDF
Anodic cyanation. Aromatic nucleophilic substitution of monomethyl- and dimethylnaphthalenes
Kunihisa Yoshida and Shigeru Nagase
pp 4268 - 4272; DOI:
10.1021/ja00509a037
PDF
Structures of strained ring systems. 3. Crystal and molecular structure of naphtho[b,e]dicyclobutene
James D. Korp and Ivan Bernal
pp 4273 - 4276; DOI:
10.1021/ja00509a038
PDF
Liquid-phase reactions of free methyl cations from the decay of methane-t4. Alternative alkylation sites in halobenzenes
Pierluigi Giacomello
pp 4276 - 4281; DOI:
10.1021/ja00509a039
PDF
Infrared laser induced organic reactions. 3. Demonstration of Woodward-Hoffmann behavior in the pulsed, infrared laser induced reaction of cis-3,4-dichlorocyclobutene
Wayne C. Danen, David F. Koster, and Robert N. Zitter
pp 4281 - 4283; DOI:
10.1021/ja00509a040
PDF
Laser-induced reactions in pyridoxal catalysis
John W. Ledbetter, Harold W. Askins, and Raymond S. Hartman
pp 4284 - 4289; DOI:
10.1021/ja00509a041
PDF
The peroxide transfer reaction
Mary F. Salomon and Robert G. Salomon
pp 4290 - 4299; DOI:
10.1021/ja00509a042
PDF
Mechanism of hydrolysis of phosphorylethanolamine triesters. Multiple catalytic effects of an intramolecular amino group
Robert A. Lazarus and Stephen J. Benkovic
pp 4300 - 4312; DOI:
10.1021/ja00509a043
PDF
ESR of transient radicals during pyrolysis of fluids
Ralph Livingston, Henry Zeldes, and Mark S. Conradi
pp 4312 - 4319; DOI:
10.1021/ja00509a044
PDF
Synthesis of prostaglandin H2
Ned A. Porter, Jim D. Byers, Katherine M. Holden, and Daniel B. Menzel
pp 4319 - 4322; DOI:
10.1021/ja00509a045
PDF
Chiral[16O, 17O, 18O]phosphate monoesters. Asymmetric synthesis and stereochemical analysis of [1(R)-16O, 17O, 18O]phospho-(S)-propane-1,2-diol
Steven J. Abbott, Stephen R. Jones, Steven A. Weinman, Frank M. Bockhoff, F. W. McLafferty, and Jeremy R. Knowles
pp 4323 - 4332; DOI:
10.1021/ja00509a046
PDF
Allosteric effects in organic chemistry. Site-specific binding
J. Rebek, J. E. Trend, R. V. Wattley, and S. Chakravorti
pp 4333 - 4337; DOI:
10.1021/ja00509a047
PDF
Nitroxides. 87. ESR determination of the thermodynamic data for the association of two paramagnetic enantiomers with .beta.-cyclodextrin
J. Michon and A. Rassat
pp 4337 - 4339; DOI:
10.1021/ja00509a048
PDF
Role of buffers in a methylase model reaction. General base catalysis by oxyanions vs. nucleophilic dealkylation by amines
Jay O. Knipe and James K. Coward
pp 4339 - 4348; DOI:
10.1021/ja00509a049
PDF
.alpha.-Deuterium isotope effects and transition-state structure in an intramolecular model system for methyl-transfer enzymes
Ivan Mihel, Jay O. Knipe, James K. Coward, and Richard L. Schowen
pp 4349 - 4351; DOI:
10.1021/ja00509a050
PDF
.alpha.-Deuterium and carbon-13 isotope effects for a simple, intermolecular sulfur-to-oxygen methyl-transfer reaction. Transition-state structures and isotope effects in transmethylation and transalkylation
Carmen H. Gray, James K. Coward, K. Barbara Schowen, and Richard L. Schowen
pp 4351 - 4358; DOI:
10.1021/ja00509a051
PDF
.alpha.-Deuterium and carbon-13 isotope effects for methyl transfer catalyzed by catechol O-methyltransferase. SN2-like transition state
Mohamed F. Hegazi, Ronald T. Borchardt, and Richard L. Schowen
pp 4359 - 4365; DOI:
10.1021/ja00509a052
PDF
Stereochemistry of intermediates in thiamin catalysis. 3. Crystal structure of DL-2-(.alpha.-hydroxybenzyl)oxythiamin chloride hydrochloride trihydrate, an inhibitor adduct
Whanchul Shin, James Pletcher, and Martin Sax
pp 4365 - 4371; DOI:
10.1021/ja00509a053
PDF
Synthesis and characterization of bis(fulvalene)divanadium and the crystal structure of its oxidation product, bis(fulvalene)bis(acetonitrile)divanadium(III)(V-V) bis(hexafluorophosphate)-acetonitrile (1/1)
James C. Smart, Barry L. Pinsky, Michael F. Fredrich, and Victor W. Day
pp 4371 - 4373; DOI:
10.1021/ja00509a054
PDF
Photoassisted decomposition of water at the gas-solid interface on titanium dioxide
H. Van Damme and W. Keith Hall
pp 4373 - 4374; DOI:
10.1021/ja00509a055
PDF
Computer retrieval and analysis of molecular geometry. 4. Intermolecular interactions
Peter Murray-Rust and W. D. Sam Motherwell
pp 4374 - 4376; DOI:
10.1021/ja00509a056
PDF
Small errors in carbon-hydrogen bond lengths may cause large errors in rotational correlation times determined from carbon-13 spin-lattice relaxation measurements
Kilian Dill and Adam Allerhand
pp 4376 - 4378; DOI:
10.1021/ja00509a057
PDF
A stereocontrolled approach toward vitamin D metabolites. A synthesis of the Inhoffen-Lythgoe diol
Barry M. Trost, Peter R. Bernstein, and Peter C. Funfschilling
pp 4378 - 4380; DOI:
10.1021/ja00509a058
PDF
Bicyclo[2.2.1]heptanes in organic synthesis. Stereocontrolled approach to sterol side-chain construction: synthesis of De-AB-cholest-11-en-9-one
Paul A. Grieco, Tetsuo Takigawa, and David R. Moore
pp 4380 - 4381; DOI:
10.1021/ja00509a059
PDF
.alpha.,.beta. Dehydrogenation of carboxamides
R. Da Costa, M. Gillard, J. B. Falmagne, and L. Ghosez
pp 4381 - 4383; DOI:
10.1021/ja00509a060
PDF
Solar energy storage reactions involving polynuclear rhodium isocyanide complexes. Flash photolysis studies in aqueous sulfuric acid solutions
Vincent M. Miskowski, I. S. Sigal, Kent R. Mann, Harry B. Gray, Steven J. Milder, George S. Hammond, and P. Ray Ryason
pp 4383 - 4385; DOI:
10.1021/ja00509a061
PDF
A simple synthesis of L-.gamma.-carboxyglutamate and derivatives thereof
Samuel Danishefsky, Ellen Berman, Lane A. Clizbe, and Masahiro Hirama
pp 4385 - 4386; DOI:
10.1021/ja00509a062
PDF
Structure of elasnin, a novel elastase inhibitor
S. Omura, A. Nakagawa, and H. Ohno
pp 4386 - 4388; DOI:
10.1021/ja00509a063
PDF
Upper excited triplet state mechanism in the trans .fwdarw. cis photoisomerization of 4-bromostilbene
H. Goerner and D. Schulte-Frohlinde
pp 4388 - 4390; DOI:
10.1021/ja00509a064
PDF
Ferraborane B3H7Fe2(CO)6, a diiron analog of pentaborane(9)
E. L. Andersen, K. J. Haller, and T. P. Fehlner
pp 4390 - 4391; DOI:
10.1021/ja00509a065
PDF
Time-resolved resonance Raman study of the lowest (d.pi.*,3CT) excited state of tris(2,2'-bipyridine)ruthenium(II)
Richard F. Dallinger and William H. Woodruff
pp 4391 - 4393; DOI:
10.1021/ja00509a066
PDF
Substituent effects in concerted reactions. A nonlinear free-energy relationship for the 3,3-shift and the Diels-Alder reaction
Joseph J. Gajewski
pp 4393 - 4394; DOI:
10.1021/ja00509a067
PDF
Charge-transfer luminescence from a nonaromatic .alpha.-diimine complex of ruthenium(II)
William P. Krug and J. N. Demas
pp 4394 - 4396; DOI:
10.1021/ja00509a068
PDF
Stereochemistry of the permanganate oxidation of 1,5-dienes
D. M. Walba, M. D. Wand, and M. C. Wilkes
pp 4396 - 4397; DOI:
10.1021/ja00509a069
PDF
The role of substrate and media polarity on the stereochemistries of the SF2 bromination of trialkyl-sec-butyltin compounds
Lawrence F. McGahey and Frederick R. Jensen
pp 4397 - 4398; DOI:
10.1021/ja00509a070
PDF
Stereospecific total synthesis of (.+-.)-warburganal and related compounds
Steven P. Tanis and Koji Nakanishi
pp 4398 - 4400; DOI:
10.1021/ja00509a071
PDF
A total synthesis of (.+-.)-warburganal
Tadashi Nakata, Hiroyuki Akita, Takanobu Naito, and Takeshi Oishi
pp 4400 - 4401; DOI:
10.1021/ja00509a072
PDF
Synthesis of mokupalide
F. W. Sum and Larry Weiler
pp 4401 - 4403; DOI:
10.1021/ja00509a073
PDF
Synthetic studies on .beta.-lactam antibiotics. 12. Stereocontrolled synthesis of 7.alpha.-methoxy-1-oxacephems from 6-epipenicillin G
Shoichiro Uyeo, Ikuo Kikkawa, Yoshio Hamashima, Hisao Ona, Yasuhiro Nishitani, Kyo Okada, Tadatoshi Kubota, Koji Ishikura, Yutaka Ide, and et al.
pp 4403 - 4404; DOI:
10.1021/ja00509a074
PDF
Biomimetic polyene cyclizations. Trapping of the resultant carbocation by an internal nucleophile
Michael E. Garst, Yak-Fa Cheung, and William S. Johnson
pp 4404 - 4406; DOI:
10.1021/ja00509a075
PDF
Catalytic asymmetric hydrogenation with a rhodium(I) chiral bisphosphine system. A study of itaconic acid and some of its derivatives and homologs
W. C. Christopfel and B. D. Vineyard
pp 4406 - 4408; DOI:
10.1021/ja00509a076
PDF
Conformational preference and structural similarity of the lanthanide [2.2.1] cryptates
Otto A. Gansow, David J. Pruett, and Kelly B. Triplett
pp 4408 - 4409; DOI:
10.1021/ja00509a077
PDF
Reaction of alkynes with a methylnickel complex: observation of a cis insertion mechanism capable of giving kinetically controlled trans products
John M. Huggins and Robert G. Bergman
pp 4410 - 4412; DOI:
10.1021/ja00509a078
PDF
Electroreduction of retinal. Formation of pinacol in the presence of malonate esters
Linda A. Powell and R. M. Wightman
pp 4412 - 4413; DOI:
10.1021/ja00509a079
PDF
New synthetic methods. Allylic alkylation of enol thioethers
Barry M. Trost and Yoshio Tanigawa
pp 4413 - 4416; DOI:
10.1021/ja00509a080
PDF
Mechanism of the oxidation of alkanes with nitronium tetrafluoroborate in acetonitrile. Evidence for a carbenium ion intermediate
Robert D. Bach, Joseph W. Holubka, Robert C. Badger, and Sundar J. Rajan
pp 4416 - 4417; DOI:
10.1021/ja00509a081
PDF
Primary processes in the photochemistry of pentaamminechlorocobalt(2+)
J. Lilie
pp 4417 - 4419; DOI:
10.1021/ja00509a082
PDF
Synthesis of 7,8-didemethyl-8-hydroxy-5-deazariboflavin and confirmation of its identity with the deazaisoalloxazine chromophore of Methanobacterium redox coenzyme F420
Wallace T. Ashton, Ronald D. Brown, Fredric Jacobson, and Christopher Walsh
pp 4419 - 4420; DOI:
10.1021/ja00509a083
PDF
Regiospecific photosensitized oxygenation of vinylsilanes. A method for converting saturated ketones to 1,2-transposed allylic alcohols. Possible role of silicon in directing the regioselectivity of epoxysilane cleavage reactions
William E. Fristad, Thomas R. Bailey, Leo A. Paquette, Rolf Gleiter, and Michael C. Boehm
pp 4420 - 4423; DOI:
10.1021/ja00509a084
PDF
A novel pyrimidine to pyridine ring transformation reaction. A facile synthesis of 2,6-dihydroxypyridines
Kosaku Hirota, Yukio Kitade, Shigeo Senda, Michael J. Halat, Kyoichi A. Watanabe, and Jack J. Fox
pp 4423 - 4425; DOI:
10.1021/ja00509a085
PDF
Heteroatomic biradicals. Electron spin resonance spectroscopy of a nitrogen analog of 1,8-naphthoquinodimethane
Matthew S. Platz and John R. Burns
pp 4425 - 4426; DOI:
10.1021/ja00509a086
PDF
Synthesis and Cope rearrangement of cis-1,2-dialkenylcyclopropanes
Manfred P. Schneider and Angelika Rau
pp 4426 - 4427; DOI:
10.1021/ja00509a087
PDF
Book Reviews

pp 4428 - 4432; DOI:
10.1021/ja00509a600
PDF

Issue 16


Binding of oxygen and carbon monoxide to hemoglobin. An analysis of the ground and excited states
D. A. Case, Boi Hanh Huynh, and M. Karplus
pp 4433 - 4453; DOI:
10.1021/ja00510a001
PDF
Effects of methyl substitution on the excited states of butadiene
U. Dinur and B. Honig
pp 4453 - 4460; DOI:
10.1021/ja00510a002
PDF
Electrochemistry of horse heart cytochrome c
Mark J. Eddowes and H. Allen O. Hill
pp 4461 - 4464; DOI:
10.1021/ja00510a003
PDF
Infrared laser chemistry of large molecules
A. Kaldor, R. B. Hall, D. M. Cox, J. A. Horsley, P. Rabinowitz, and G. M. Kramer
pp 4465 - 4471; DOI:
10.1021/ja00510a004
PDF
Synthesis and temperature-dependent conformational preferences of macrocycles containing the 2,2'-bipyridyl moiety
George R. Newkome, Ashutosh Nayak, Frank Fronczek, Toshio Kawato, Hellen C. R. Taylor, Leah Meade, and Wayne Mattice
pp 4472 - 4477; DOI:
10.1021/ja00510a005
PDF
Molecular origin of the temperature-dependent NMR spectrum of 1:1 crown ether macrocycles containing a 2,2'-bipyridyl subunit
Wayne L. Mattice and George R. Newkome
pp 4477 - 4480; DOI:
10.1021/ja00510a006
PDF
Sensitivity enhanced detection of weak nuclei using heteronuclear multiple quantum coherence
Luciano Mueller
pp 4481 - 4484; DOI:
10.1021/ja00510a007
PDF
NMR study of the spatial effect of polyacrylamide gel upon the water molecules confined in it
Seiji Katayama and Shizuo Fujiwara
pp 4485 - 4488; DOI:
10.1021/ja00510a008
PDF
Generation of spirodihydroaromatic anions. Chemistry and carbon-13 NMR
S. Q. A. Rizvi, Joseph Foos, Frank Steel, and Gideon Fraenkel
pp 4488 - 4492; DOI:
10.1021/ja00510a009
PDF
Conformational analysis of 1,1,2,2-tetracyclohexylethane
S. G. Baxter, Hans Fritz, Goetz Hellmann, Brigitte Kitschke, Hans Joerg Lindner, Kurt Mislow, Christoph Ruechardt, and Siegried Weiner
pp 4493 - 4497; DOI:
10.1021/ja00510a010
PDF
Conformational study of cyclohexanecarboxaldehyde by microwave spectroscopy
Peter N. Kao and Paul H. Turner
pp 4497 - 4499; DOI:
10.1021/ja00510a011
PDF
High-resolution microwave spectra and conformations of 2-tetrahydropyranylcarbinol and 2-aminomethyltetrahydropyran
Paul H. Turner
pp 4499 - 4501; DOI:
10.1021/ja00510a012
PDF
Systematics in the electronic spectra of polar molecules. 1. Para-disubstituted benzenes
T. P. Carsey, G. L. Findley, and S. P. McGlynn
pp 4502 - 4510; DOI:
10.1021/ja00510a013
PDF
Systematics in the electronic spectra of polar molecules. 2. Ortho- and meta-disubstituted benzenes
G. L. Findley, T. P. Carsey, and S. P. McGlynn
pp 4511 - 4517; DOI:
10.1021/ja00510a014
PDF
Crystal and molecular structure of [n-Bu4N+][S3N3-] and the vibrational assignments and electronic structure of the planar six-membered ring of the trisulfur trinitride anion
J. Bojes, T. Chivers, W. G. Laidlaw, and M. Trsic
pp 4517 - 4522; DOI:
10.1021/ja00510a015
PDF
Photolytic separation of carbon isotopes in cryogenic solutions of carbon disulfide
Samuel M. Freund, William B. Maier, Redus F. Holland, and Willard H. Beattie
pp 4522 - 4524; DOI:
10.1021/ja00510a016
PDF
A theoretical study on the paths of photodissociation: cyclopropanone .fwdarw. carbon monoxide + ethylene
Shinichi Yamabe, Tsutomu Minato, and Yoshihiro Osamura
pp 4525 - 4531; DOI:
10.1021/ja00510a017
PDF
Geometry predictions for conjugated free radicals containing three .pi. electrons using ab initio MO theory
N. Colin Baird, Rashmi R. Gupta, and Kathleen F. Taylor
pp 4531 - 4533; DOI:
10.1021/ja00510a018
PDF
Generalized transition state theory. Bond energy-bond order method for canonical variational calculations with application to hydrogen atom transfer reactions
Bruce C. Garrett and Donald G. Truhlar
pp 4534 - 4548; DOI:
10.1021/ja00510a019
PDF
Photophysical and photochemical properties of rhodium(III) halopentaammine complexes in aqueous solution. Reaction kinetics of ligand field excited states
Michael A. Bergkamp, James Brannon, Doug Magde, Richard J. Watts, and Peter C. Ford
pp 4549 - 4554; DOI:
10.1021/ja00510a020
PDF
Metal-metal charge transfer in thallous tetracarbonylcobaltate ion pairs. Spectroscopy and equilibrium constants
Charles Schramm and Jeffrey I. Zink
pp 4554 - 4558; DOI:
10.1021/ja00510a021
PDF
Preparation and characterization of tantalum(III) olefin complexes and tantalum(V) metallacyclopentane complexes made from acyclic .alpha. olefins
S. J. McLain, C. D. Wood, and R. R. Schrock
pp 4558 - 4570; DOI:
10.1021/ja00510a022
PDF
Binuclear complexes of macrocyclic ligands. Electrochemical and spectral properties of homobinuclear CuIICuII, CuIICuI, and CuICuI species including an estimated intramolecular electron transfer rate
Robert R. Gagne, Carl A. Koval, Thomas J. Smith, and Marc C. Cimolino
pp 4571 - 4580; DOI:
10.1021/ja00510a023
PDF
Technetium radiopharmaceutical development. 1. Synthesis, characterization, and structure of dichloro[hydrotris(1-pyrazolyl)borato]oxotechnetium(V)
Rudy W. Thomas, Gregory W. Estes, R. C. Elder, and Edward Deutsch
pp 4581 - 4585; DOI:
10.1021/ja00510a024
PDF
Crystal structure of [(C2H5)4N]3[Fe4S4(SCH2Ph)4], a reduced ferredoxin site analog with a nontetragonal Fe4S4 core structure in the solid state
Jeremy M. Berg, Keith O. Hodgson, and R. H. Holm
pp 4586 - 4593; DOI:
10.1021/ja00510a025
PDF
Studies on vitamin B12 and related compounds. 49. Direct synthesis of alkyl- and of .omega.-carboxyalkylcobalamins from vitamin B12 and aliphatic carboxylic acids under "oxidizing-reducing" conditions
Gerhard N. Schrauzer and Masao Hashimoto
pp 4593 - 4601; DOI:
10.1021/ja00510a026
PDF
Chemistry of cobalamins and related compounds. 48. Sterically induced, spontaneous dealkylation of secondary alkylcobalamins due to axial base coordination and conformational changes of the corrin ligand
John H. Grate and G. N. Schrauzer
pp 4601 - 4611; DOI:
10.1021/ja00510a027
PDF
Photochemically generated silicon-carbon double-bonded intermediates. 10. Photochemical behavior of 1-disilanyl- and 2-disilanylnaphthalenes
Mitsuo Ishikawa, Michio Oda, Naoto Miyoshi, Laszlo Fabry, Makoto Kumada, Tokio Yamabe, Kazuo Akagi, and Kenichi Fukui
pp 4612 - 4618; DOI:
10.1021/ja00510a028
PDF
Hydroxyphosphoranes and phosphoranoxide anions - synthesis, reactivity, and acidity of pentacoordinate phosphorus acids
Itshak Granoth and J. C. Martin
pp 4618 - 4622; DOI:
10.1021/ja00510a029
PDF
Direct observation of phosphoranide anions. Extremely stable phosphorus-hydrogen dioxyphosphoranes containing two carbon-phosphorus bonds
Itshak Granoth and J. C. Martin
pp 4623 - 4626; DOI:
10.1021/ja00510a030
PDF
Angular dependence of the electron-acceptor character of alkylthio groups in organic radicals
Angelo Alberti, Maurizio Guerra, Giorgio Martelli, Fernando Bernardi, Angelo Mangini, and Gian Franco Pedulli
pp 4627 - 4631; DOI:
10.1021/ja00510a031
PDF
Studies on the carbanions affected by neighboring sulfur groups. 1. Effect of the oxidation number of sulfur atom on ion pairing and electron transfer of the alkali metal fluorenyl carbanions substituted in 9 position with phenyl sulfur groups
Shinichi Nishi and Minoru Matsuda
pp 4632 - 4637; DOI:
10.1021/ja00510a032
PDF
Electrochemistry of the carbon-halogen bond. 9-Fluorenyl and benzhydryl halides in dimethylformamide at platinum and vitreous carbon electrodes
F. M. Triebe, K. J. Borhani, and M. D. Hawley
pp 4637 - 4645; DOI:
10.1021/ja00510a033
PDF
Reappraisal of the stereochemistry of electrophilic additions to 3-norcarenes. X-ray and proton NMR analysis of norcarene epoxide conformation. The role of magnetic anisotropic contributions of epoxide rings
Leo A. Paquette, William E. Fristad, Cliff A. Schuman, Mark A. Beno, and Gary G. Christoph
pp 4645 - 4655; DOI:
10.1021/ja00510a034
PDF
Stereoreversed electrophilic additions to 3-norcarenes. Insight into the relative steric demands of singlet oxygen in the ene reaction
Leo A. Paquette and Guy Kretschmer
pp 4655 - 4663; DOI:
10.1021/ja00510a035
PDF
The quasi-solid liquid lattice and volume change on melting of a solid. A modified significant structure theory of liquids. 1
Leonard S. Levitt and Eric T. Hsieh
pp 4664 - 4668; DOI:
10.1021/ja00510a036
PDF
An investigation of the reduction of aryldiazonium ions by hydrazines
William T. Evanochko and Philip B. Shevlin
pp 4668 - 4672; DOI:
10.1021/ja00510a037
PDF
Substituent effects on the general- and specific-acid-catalyzed hydrolyses of acetals of benzaldehydes
James L. Jensen, Larry R. Herold, Paul A. Lenz, Sevim Trusty, Vincent Sergi, Kenneth Bell, and Patricia Rogers
pp 4672 - 4677; DOI:
10.1021/ja00510a038
PDF
Separation of polar and resonance substituent effects in the reaction of benzaldehydes with hydrocyanic acid. A correlation between .rho.r/.rho.req ratios and central atom rehybridization
Paul R. Young and Patrick E. McMahon
pp 4678 - 4681; DOI:
10.1021/ja00510a039
PDF
Energy barriers for isomerization of gaseous C3H5+ ions
Richard D. Bowen, Dudley H. Williams, Helmut Schwarz, and Chysostomos Wesdemiotis
pp 4681 - 4683; DOI:
10.1021/ja00510a040
PDF
Excited-state energy distribution between dissimilar carbonyl molecules produced from 1,2-dioxetanes
William H. Richardson, Merylin B. Lovett, Mary E. Price, and James H. Anderegg
pp 4683 - 4687; DOI:
10.1021/ja00510a041
PDF
Electron spin resonance and CIDNP studies on 1,3-cyclopentadiyls. A localized 1,3 carbon biradical system with a triplet ground state. Tunneling in carbon-carbon bond formation
S. L. Buchwalter and G. L. Closs
pp 4688 - 4694; DOI:
10.1021/ja00510a042
PDF
Matrix effect on the photochemistry of cyclopropyl ketones. Photochemistry of the triplet state of 2-spirocyclopropyl-1-indanone at 77 K
Rafik O. Loutfy and Peter Yates
pp 4694 - 4698; DOI:
10.1021/ja00510a043
PDF
Carbanions, electron transfer vs. proton capture. 6. Determination of the effect of ion pairing on the electron-transfer equilibrium between fluoradenide ion and nitrobenzene
Robert D. Guthrie and Nam S. Cho
pp 4698 - 4705; DOI:
10.1021/ja00510a044
PDF
Generation of butatrienone (vinylideneketene) by flash vacuum pyrolysis and measurement of its microwave spectrum
Ronald D. Brown, Roger F. C. Brown, Frank W. Eastwood, Peter D. Godfrey, and Donald McNaughton
pp 4705 - 4708; DOI:
10.1021/ja00510a045
PDF
Kinetic studies on the nucleophilic addition to double bonds. 1. Addition of amines to electrophilic carbon-carbon double bonds
B. Schreiber, H. Martinek, P. Wolschann, and P. Schuster
pp 4708 - 4713; DOI:
10.1021/ja00510a046
PDF
Comparative chemistry of the bay- and non-bay-region tetrahydro epoxides of phenanthrene
Donald Z. Rogers and Thomas C. Bruice
pp 4713 - 4719; DOI:
10.1021/ja00510a047
PDF
Structure of cleomeolide, a novel diterpene lactone from Cleome icosandra Linn
S. B. Mahato, B. C. Pal, T. Kawasaki, K. Miyahara, O. Tanaka, and K. Yamasaki
pp 4720 - 4723; DOI:
10.1021/ja00510a048
PDF
Structure and conformation of pyrimidine lyxofuranosides. 1-.beta.-D-Lyxofuranosyluracil, 1-.beta.-D-lyxofuranosylcytosine, and some O'-methyl derivatives
Irena Ekiel, Edward Darzynkiewicz, George I. Birnbaum, and David Shugar
pp 4724 - 4729; DOI:
10.1021/ja00510a049
PDF
Nuclear analogs of .beta.-lactam antibiotics. 6. 3-Oxa-1-azabicyclo[4.2.0]octan-8-one-2-carboxylic acids
John G. Gleason, T. F. Buckley, Kenneth G. Holden, D. Boles Bryan, and P. Siler
pp 4730 - 4732; DOI:
10.1021/ja00510a050
PDF
Progress toward the total synthesis of maytansinoids. Synthesis of (.+-.)-4,5-deoxymaysine (N-methylmaysenine)
A. I. Meyers, Dennis M. Roland, Daniel L. Comins, Rainer Henning, Michael P. Fleming, and Kimihiro Shimizu
pp 4732 - 4734; DOI:
10.1021/ja00510a051
PDF
Molecular beam electric deflection analysis of (SN)x vapor. Evidence for a nonpolar tetramer
R. R. Cavanagh, R. S. Altman, D. R. Herschbach, and W. Klemperer
pp 4734 - 4735; DOI:
10.1021/ja00510a052
PDF
Cyclic peroxides. 87. A stable bisdioxetane
Waldemar Adam, Chen-Chih Cheng, Omar Cueto, Ihsan Erden, and Klaus Zinner
pp 4735 - 4736; DOI:
10.1021/ja00510a053
PDF
Unification of the carbenic selectivity spectrum. The ambiphilicity of methoxychlorocarbene
Robert A. Moss, Michal Fedorynski, and Wen-Chung Shieh
pp 4736 - 4738; DOI:
10.1021/ja00510a054
PDF
Carbene rearrangements of 2-vinylcyclobutylidene
Udo H. Brinker and Lothar Koenig
pp 4738 - 4739; DOI:
10.1021/ja00510a055
PDF
Absolute configuration of (-)n-tris(2,2'-bipyridine)cobalt(III)
Y. Ohashi, K. Yanagi, Y. Mitsuhashi, K. Nagata, Y. Kaizu, Y. Sasada, and H. Kobayashi
pp 4739 - 4740; DOI:
10.1021/ja00510a056
PDF
Reductive coupling of carbonyl or imino functional groups by dicarbonylbis(cyclopentadienyl)titanium(II): model reactions for carbon dioxide dimerization and a novel metallacycle formation
Marco Pasquali, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 4740 - 4742; DOI:
10.1021/ja00510a057
PDF
MNDO study of tetra-tert-butyltetrahedrane and tetra-tert-butylcyclobutadiene and of their thermal interconversion
Armin Schweig and Walter Thiel
pp 4742 - 4743; DOI:
10.1021/ja00510a058
PDF
Enol thioethers in synthesis. Regiocontrolled arylation via organopalladium chemistry
Barry M. Trost and Yoshio Tanigawa
pp 4743 - 4745; DOI:
10.1021/ja00510a059
PDF
Structure and dynamic behavior of propyllithium from carbon-13, lithium-7, and lithium-6 NMR
Gideon Fraenkel, Alice M. Fraenkel, Michael J. Geckle, and Frank Schloss
pp 4745 - 4747; DOI:
10.1021/ja00510a060
PDF
A new class of highly conducting organic materials: charge-transfer salts of the tetrathiafulvalenes with the tetrahalo-p-benzoquinones
J. B. Torrance, J. J. Mayerle, V. Y. Lee, and K. Bechgaard
pp 4747 - 4748; DOI:
10.1021/ja00510a061
PDF
Cyclophane porphyrin. 2. Models for steric hindrance to carbon monoxide ligation in hemoproteins
T. G. Traylor, Dwane Campbell, and Shinji Tsuchiya
pp 4748 - 4749; DOI:
10.1021/ja00510a062
PDF
Macrolide antibiotics. 1. Total synthesis of the Prelog-Djerassi lactone and methynolide
Paul A. Grieco, Yasufumi Ohfune, Yuusaku Yokoyama, and William Owens
pp 4749 - 4752; DOI:
10.1021/ja00510a063
PDF
One-step joining reaction of thiolate anions, activated olefins, and carbonyl compounds
Tatsuya Shono, Yoshihiro Matsumura, Shigenori Kashimura, and Kouhei Hatanaka
pp 4752 - 4753; DOI:
10.1021/ja00510a064
PDF
Saturation-transfer study of the mechanism of proton exchange in amides
Charles L. Perrin and Eric R. Johnston
pp 4753 - 4754; DOI:
10.1021/ja00510a065
PDF
Simple generation of thiocarbonyl ylides
Tim B. Cameron and Harold W. Pinnick
pp 4755 - 4755; DOI:
10.1021/ja00510a066
PDF
Polyene chain conformations of 13-demethylretinals
Robert Rowan
pp 4755 - 4757; DOI:
10.1021/ja00510a067
PDF
Photoinduced reactions. 108. 1,2-dioxetane formation in an indole system
Isao Saito, Seiichi Matsugo, and Teruo Matsuura
pp 4757 - 4759; DOI:
10.1021/ja00510a068
PDF
Cyclodextrin having an amino group as a rhodopsin model
Iwao Tabushi, Yasuhisa Kuroda, and Kazuhiro Shimokawa
pp 4759 - 4760; DOI:
10.1021/ja00510a069
PDF
The iron(II) "homologous cap" porphyrin. A novel dioxygen binder
John R. Budge, Paul E. Ellis, Robert D. Jones, Jack E. Linard, Fred Basolo, Jack E. Baldwin, and Robert L. Dyer
pp 4760 - 4762; DOI:
10.1021/ja00510a070
PDF
The iron(II) and cobalt(II) "cap" and "homologous cap" porphyrins. Base and oxygenation equilibriums studies of relevance to hemoglobin cooperativity
John R. Budge, Paul E. Ellis, Robert D. Jones, Jack E. Linard, Thomas Szymanski, Fred Basolo, Jack E. Baldwin, and Robert L. Dyer
pp 4762 - 4763; DOI:
10.1021/ja00510a071
PDF
Optically active poly(triphenylmethyl methacrylate) with one-handed helical conformation
Yoshio Okamoto, Koichi Suzuki, Koji Ohta, Koichi Hatada, and Heimei Yuki
pp 4763 - 4765; DOI:
10.1021/ja00510a072
PDF
Onium ions. 19. Chloromethylhalonium ions
George A. Olah and Mark R. Bruce
pp 4765 - 4766; DOI:
10.1021/ja00510a073
PDF
Reaction of a bridged binuclear dialkylcobalt complex with carbon monoxide and phosphines. Observation of competing inter- and intramolecular metal to metal methyl transfer
Henry E. Bryndza and Robert G. Bergman
pp 4766 - 4768; DOI:
10.1021/ja00510a074
PDF
Ipso nitration. Use of ipso nitration products as sources of carbon electrophiles in regiospecific syntheses of aromatic derivatives
K. S. Feldman and P. C. Myhre
pp 4768 - 4769; DOI:
10.1021/ja00510a075
PDF
Protonation of aromatic .pi. carbocations in strong acid. Direct observation of protonated carbocations by proton NMR spectroscopy
Robert J. Smith and Richard M. Pagni
pp 4769 - 4770; DOI:
10.1021/ja00510a076
PDF
High-resolution carbon-13 NMR spectra of carbonium ions in the solid state
J. R. Lyerla, C. S. Yannoni, D. Bruck, and C. A. Fyfe
pp 4770 - 4772; DOI:
10.1021/ja00510a077
PDF
Extended unsaturated carbenes. Generation and reaction of allenylidene carbenes, (R)2C:C:C:C:, with olefins
Peter J. Stang and Thomas E. Fisk
pp 4772 - 4773; DOI:
10.1021/ja00510a078
PDF
Twofold cation-olefin cyclization. Synthesis of syn-[3.2.1]2- and [2.2.2]2geminane
Hokoon Park, Patrick F. King, and Leo A. Paquette
pp 4773 - 4774; DOI:
10.1021/ja00510a079
PDF
Book Reviews

pp 4775 - 4778; DOI:
10.1021/ja00510a600
PDF

Issue 17


Phthalocyanine thin films as semiconductor electrodes
Fu-Ren Fan and Larry R. Faulkner
pp 4779 - 4787; DOI:
10.1021/ja00511a001
PDF
Molecular beam electric deflection behavior and polarity of hydrogen-bonded complexes of ROH, RSH, and RNH
J. A. Odutola, R. Viswanathan, and T. R. Dyke
pp 4787 - 4792; DOI:
10.1021/ja00511a002
PDF
Structure-basicity relationships in carbonyl compounds
C. Laurence, G. Guiheneuf, and B. Wojtkowiak
pp 4793 - 4801; DOI:
10.1021/ja00511a003
PDF
Acidity function of solid-bound acids
Paul Rys and Werner J. Steinegger
pp 4801 - 4806; DOI:
10.1021/ja00511a004
PDF
Quantum-chemical considerations on the acidity of thiamin pyrophosphate and related systems
Miek M. E. Scheffers-Sap and Henk M. Buck
pp 4807 - 4811; DOI:
10.1021/ja00511a005
PDF
Thermal rearrangement of cyclobutylidene to methylenecyclopropane. Intermediacy of a novel nonclassical carbene
Wolfgang W. Schoeller
pp 4811 - 4815; DOI:
10.1021/ja00511a006
PDF
Estimation of excited-state redox potentials by electron-transfer quenching. Application of electron-transfer theory to excited-state redox processes
C. R. Bock, J. A. Connor, A. R. Gutierrez, Thomas J. Meyer, D. G. Whitten, B. P. Sullivan, and J. K. Nagle
pp 4815 - 4824; DOI:
10.1021/ja00511a007
PDF
Application of force field calculations to organic chemistry. 8. Internal rotation in simple to congested hydrocarbons including 2,3-dimethylbutane, 1,1,2,2-tetra-tert-butylethane, 2,2,4,4,5,5,7,7-octamethyloctane, cholestane
Eiji Osawa, Haruhisa Shirahama, and Takeshi Matsumoto
pp 4824 - 4832; DOI:
10.1021/ja00511a008
PDF
Direct calculation of resonance energies of conjugated hydrocarbons with ab initio MO methods
Herbert Kollmar
pp 4832 - 4840; DOI:
10.1021/ja00511a009
PDF
In situ resonance Raman spectroscopic investigation of the tetrathiafulvalene-tetracyanoquinodimethan electrode surface
William L. Wallace, Calvin D. Jaeger, and Allen J. Bard
pp 4840 - 4843; DOI:
10.1021/ja00511a010
PDF
Molecular orbital theory of the electronic structure of molecules. 39. Highly unusual structures of electron-deficient carbon compounds. Reversal of van't Hoff stereochemistry in BBC ring systems
K. Krogh-Jespersen, D. Cremer, D. Poppinger, J. A. Pople, Paul v. R. Schleyer, and J. Chandrasekhar
pp 4843 - 4851; DOI:
10.1021/ja00511a011
PDF
Determination of the .beta.-anomeric configuration of cytidine 5'-monophospho-N-acetylneuraminic acid by carbon-13 NMR spectroscopy
Johan Haverkamp, Tom Spoormaker, Lambertus Dorland, Johannes F. G. Vliegenthart, and Roland Schauer
pp 4851 - 4853; DOI:
10.1021/ja00511a012
PDF
Carbon-13 NMR relaxation mechanisms in methyl-transition metal compounds
Richard F. Jordan and Jack R. Norton
pp 4853 - 4858; DOI:
10.1021/ja00511a013
PDF
Metal ion complexes of .alpha.-amido acids. 1. Structure and magnetic properties of the nickel and cobalt hippurates. Pseudo-one-dimensional magnetic systems
Maurice M. Morelock, Mary L. Good, Louis M. Trefonas, David Karraker, Lutfollah Maleki, Helen R. Eichelberger, Richard Majeste, and John Dodge
pp 4858 - 4866; DOI:
10.1021/ja00511a014
PDF
Organocobalt cluster complexes. 28. Highly stabilized (nonacarbonyltricobalt)carbon-substituted carbonium ions
Dietmar Seyferth, Gary H. Williams, C. Scott Eschbach, Mara Ozolins Nestle, Joseph S. Merola, and John E. Hallgren
pp 4867 - 4878; DOI:
10.1021/ja00511a015
PDF
Metal clusters. 21. Synthesis of rhodium phosphite clusters
Andrew J. Sivak and E. L. Muetterties
pp 4878 - 4887; DOI:
10.1021/ja00511a016
PDF
Catalyzed dimerization of a diquinoethylene and formation of diquinoethylene-rhodium complexes
Leon Hagelee, Robert West, Joseph Calabrese, and John Norman
pp 4888 - 4892; DOI:
10.1021/ja00511a017
PDF
Alkylrhodium tetracarbonyl derivatives as catalytic intermediates in homogeneous hydroformylation reactions. An infrared spectroscopic study
R. B. King, A. D. King, and M. Z. Iqbal
pp 4893 - 4896; DOI:
10.1021/ja00511a018
PDF
Fluxional behavior and substituent site preferences in cationic monosubstituted tropyliumiron tricarbonyl complexes
C. P. Lewis, W. Kitching, A Eisenstadt, and M. Brookhart
pp 4896 - 4906; DOI:
10.1021/ja00511a019
PDF
Hexakis(pyridine)ruthenium(II) tetrafluoroborate. Molecular structure and spectroscopic properties
Joseph L. Templeton
pp 4906 - 4917; DOI:
10.1021/ja00511a020
PDF
Hydrolysis mechanism of tetrahydroborate(1-) ion in moist acetonitrile. 2. The nature of the intermediate
B. Spencer Meeks and M. M. Kreevoy
pp 4918 - 4921; DOI:
10.1021/ja00511a021
PDF
A tris(dialkylamino)phosphine with pyramidal nitrogens
D. W. White, B. A. Karcher, R. A. Jacobson, and J. G. Verkade
pp 4921 - 4925; DOI:
10.1021/ja00511a022
PDF
An unusual twist-boat conformation for a six-membered ring phosphorus heterocycle
David G. Gorenstein and Robert Rowell
pp 4925 - 4928; DOI:
10.1021/ja00511a023
PDF
Host-guest complexation. 18. Effects on cation binding of convergent ligand sites appended to macrocyclic polyethers
Roger C. Helgeson, Gary R. Weisman, John L. Toner, Thomas L. Tarnowski, Y. Chao, James M. Mayer, and Donald J. Cram
pp 4928 - 4941; DOI:
10.1021/ja00511a024
PDF
Host-guest complexation. 20. Chiral recognition in transport as a molecular basis for a catalytic resolving machine
Martin Newcomb, John L. Toner, Roger C. Helgeson, and Donald J. Cram
pp 4941 - 4947; DOI:
10.1021/ja00511a025
PDF
Host-guest complexation. 21. Catalysis and chiral recognition through designed complexation of transition states in transacylations of amino ester salts
Y. Chao, G. R. Weisman, G. D. Y. Sogah, and D. J. Cram
pp 4948 - 4958; DOI:
10.1021/ja00511a026
PDF
Ground states of molecules. 55. MINDO/3 study of rearrangements of C4H7 radicals
Michael J. S. Dewar and Santiago Olivella
pp 4958 - 4962; DOI:
10.1021/ja00511a027
PDF
Unstable carbanions. General acid catalysis of the cleavage of 1-phenylcyclopropanol and 1-phenyl-2-arylcyclopropanol anions
Alf Thibblin and William P. Jencks
pp 4963 - 4973; DOI:
10.1021/ja00511a028
PDF
Structures of [C4H4O]+.cntdot.ions produced from 2- and 4-pyrone
John L. Holmes and Johan K. Terlouw
pp 4973 - 4975; DOI:
10.1021/ja00511a029
PDF
Kinetic applications of electron paramagnetic resonance spectroscopy. 34. Rate constants for spin trapping. 2. Secondary alkyl radicals
Y. Maeda and K. U. Ingold
pp 4975 - 4981; DOI:
10.1021/ja00511a030
PDF
Mechanism of reductive elimination. Reaction of alkylpalladium(II) complexes with tetraorganotin, organolithium, and Grignard reagents. Evidence for palladium(IV) intermediacy
D. Milstein and J. K. Stille
pp 4981 - 4991; DOI:
10.1021/ja00511a031
PDF
Palladium-catalyzed coupling of tetraorganotin compounds with aryl and benzyl halides. Synthetic utility and mechanism
D. Milstein and J. K. Stille
pp 4992 - 4998; DOI:
10.1021/ja00511a032
PDF
Reactions of atomic metal ions with alkyl halides and alcohols in the gas phase
J. Allison and D. P. Ridge
pp 4998 - 5009; DOI:
10.1021/ja00511a033
PDF
Coal chemistry. 8. Reactions of tetralin with coal and with some carbon-14-containing model compounds
Clair J. Collins, Vernon F. Raaen, Ben M. Benjamin, P. H. Maupin, and W. Howard Roark
pp 5009 - 5014; DOI:
10.1021/ja00511a034
PDF
Molecular structure of a stable N-methylimidazole-magnesium 2,4-dinitrophenoxide complex. A model for histidine and N.tau.-methylhistidine coordination in MgATPases and their uncouplers
Raghupathy Sarma, Fausto Ramirez, Poojappan Narayanan, Brian McKeever, and James F. Marecek
pp 5015 - 5019; DOI:
10.1021/ja00511a035
PDF
Structure and photochemistry of lumiprednisone and lumiprednisone acetate
John R. Williams, Richard H. Moore, Rosita Li, and John F. Blount
pp 5019 - 5025; DOI:
10.1021/ja00511a036
PDF
Physical, chemical, and enzymological characterization of enolpyruvate
Donald J. Kuo, Edward L. O'Connell, and Irwin A. Rose
pp 5025 - 5030; DOI:
10.1021/ja00511a037
PDF
Chromopeptides from C-phycocyanin. Structure and linkage of a phycocyanobilin bound to the .beta. subunit
J. Clark Lagarias, Alexander N. Glazer, and Henry Rapoport
pp 5030 - 5037; DOI:
10.1021/ja00511a038
PDF
Spectroscopic studies of Rhus vernicifera and Polyporus versicolor laccase. Electronic structures of the copper sites
David M. Dooley, Jill Rawlings, John H. Dawson, Philip J. Stephens, Lars-Erik Andreasson, B. G. Malmstrom, and Harry B. Gray
pp 5038 - 5046; DOI:
10.1021/ja00511a039
PDF
Spectroscopic studies of ceruloplasmin. Electronic structures of the copper sites
John H. Dawson, David M. Dooley, R. Clark, Philip J. Stephens, and Harry B. Gray
pp 5046 - 5053; DOI:
10.1021/ja00511a040
PDF
Bis(dipicolinate) complexes of cobalt(III) and iron(II) as new probes of metalloprotein electron-transfer reactivity. Analysis of reactions involving cytochrome c and cytochrome c551
A. Grant Mauk, Catherine L. Coyle, Emilio Bordignon, and Harry B. Gray
pp 5054 - 5056; DOI:
10.1021/ja00511a041
PDF
Quest for an observable model for the SN2 transition state. Pentavalent pentacoordinate carbon
T. R. Forbus and J. C. Martin
pp 5057 - 5059; DOI:
10.1021/ja00511a042
PDF
Synthesis of 2,7-di-tert-butyl-4-ethoxycarbonyl-5-methylthiepin. A remarkably stable and simple monocyclic thiepin
Keitaro Nishino, Shigeo Yano, Yasuji Kohashi, Kagetoshi Yamamoto, and Ichiro Murata
pp 5059 - 5060; DOI:
10.1021/ja00511a043
PDF
A total synthesis of gascardic acid
Robert K. Boeckman, David M. Blum, and Samuel D. Arthur
pp 5060 - 5062; DOI:
10.1021/ja00511a044
PDF
Intermolecular energy exchange of infrared-laser excited chlorodifluoromethane or silicon tetrafluoride with bromine at excitation energies of 70-200 kJ/mol
Ernest Grunwald, Charles M. Lonzetta, and Steven Popok
pp 5062 - 5064; DOI:
10.1021/ja00511a045
PDF
Oxidation of carbon monoxide to carbon dioxide by nickel-nitrogen dioxide complexes: a mechanistic study
Robert D. Feltham and Jeanne C. Kriege
pp 5064 - 5065; DOI:
10.1021/ja00511a046
PDF
Total synthesis of dl-aplysistatin
Thomas R. Hoye and Mark J. Kurth
pp 5065 - 5067; DOI:
10.1021/ja00511a047
PDF
Oxidation of ruthenium coordinated alcohols by molecular oxygen to ketones and hydrogen peroxide
Benjamin S. Tovrog, Steven E. Diamond, and Frank Mares
pp 5067 - 5069; DOI:
10.1021/ja00511a048
PDF
Berninamycin biosynthesis. 1. Origin of the dehydroalanine residues
Cedric J. Pearce and Kenneth L. Rinehart
pp 5069 - 5070; DOI:
10.1021/ja00511a049
PDF
A new bisannulation reagent easily prepared from a butadiene telomer, and its application to steroid synthesis
Jiro Tsuji, Isao Shimizu, Hirohisa Suzuki, and Yoichiro Naito
pp 5070 - 5072; DOI:
10.1021/ja00511a050
PDF
A simple total synthesis of (.+-.)-zearalenone by intramolecular alkylation using a butadiene telomer as a building block
Takashi Takahashi, Kazuyuki Kasuga, Mitsuo Takahashi, and Jiro Tsuji
pp 5072 - 5073; DOI:
10.1021/ja00511a051
PDF
Alkaloid synthesis by the intramolecular imino Diels-Alder reaction. .delta.-Coniceine and tylophorine
Steven M. Weinreb, Nazir A. Khatri, and Jayant Shringarpure
pp 5073 - 5074; DOI:
10.1021/ja00511a052
PDF
Titanium-catalyzed olefin metathesis
F. N. Tebbe, G. W. Parshall, and D. W. Ovenall
pp 5074 - 5075; DOI:
10.1021/ja00511a053
PDF
Pentamethylcyclopentadienyl organoactinides. Trivalent uranium organometallic chemistry and the unusual structure of bis(pentamethylcyclopentadienyl)uranium monochloride
Juan M. Manriquez, Paul J. Fagan, Tobin J. Marks, Sara H. Vollmer, Cynthia Secaur Day, and Victor W. Day
pp 5075 - 5078; DOI:
10.1021/ja00511a054
PDF
Doubly hindered 7,11-dicis isomers of retinal. Synthesis, properties, and interaction with cattle opsin
Aravinda Kini, Hiroyuki Matsumoto, and R. S. H. Liu
pp 5078 - 5079; DOI:
10.1021/ja00511a055
PDF
Structure and reactivity of the first hafnium carbonyl, bis(.eta.5-cyclopentadienyl)dicarbonylhafnium
David J. Sikora, Marvin D. Rausch, Robin D. Rogers, and Jerry L. Atwood
pp 5079 - 5081; DOI:
10.1021/ja00511a056
PDF
Concerted intramolecular displacement with rearrangement in allylic systems. Displacement of an allylic ester with a carbanion
Gilbert Stork and Alain R. Schoofs
pp 5081 - 5082; DOI:
10.1021/ja00511a057
PDF
Roles of multiplicity and electronic excitation on intramolecular reactions of alkylcarbenes in condensed phase
K. T. Chang and H. Shechter
pp 5082 - 5084; DOI:
10.1021/ja00511a058
PDF
Total synthesis of tryptoquivaline G
George Buchi, Philip R. DeShong, Shigeo Katsumura, and Yukio Sugimura
pp 5084 - 5086; DOI:
10.1021/ja00511a059
PDF
General acid catalysis in the hydrolysis of benzo[a]pyrene 7,8-diol 9,10-epoxides
Dale L. Whalen, Angela M. Ross, Jean A. Montemarano, Dhiren R. Thakker, Harukiko Yagi, and Donald M. Jerina
pp 5086 - 5088; DOI:
10.1021/ja00511a060
PDF
Reactivity of cyclopropylchlorocarbene: an interactive experimental and theoretical analysis
Robert A. Moss, Margherita Vezza, Wenjeng Guo, Ramesh C. Munjal, K. N. Houk, and Nelson G. Rondan
pp 5088 - 5090; DOI:
10.1021/ja00511a061
PDF
Conformation of ligated tris(dimethylamino)phosphine
A. H. Cowley, R. E. Davis, M. Lattman, M. McKee, and K. Remadna
pp 5090 - 5092; DOI:
10.1021/ja00511a062
PDF
Anion-radical crystal lattice energies
Gerald R. Stevenson and Charles R. Wiedrich
pp 5092 - 5094; DOI:
10.1021/ja00511a063
PDF
Reactions of tantalum(III) with alkynes and nitriles
F. Albert Cotton and William T. Hall
pp 5094 - 5095; DOI:
10.1021/ja00511a064
PDF
The importance of hyperconjugation in nucleophilic vinylic substitution
Yitzhak Apeloig and Zvi Rappoport
pp 5095 - 5098; DOI:
10.1021/ja00511a065
PDF
m-Quinomethane: synthesis of a covalent-biradicaloid pair of valence tautomers
Mark Rule, Albert R. Matlin, Edwin F. Hilinski, Dennis A. Dougherty, and Jerome A. Berson
pp 5098 - 5099; DOI:
10.1021/ja00511a066
PDF
Rapid selective dimerization of ethylene to 1-butene by a tantalum catalyst and a new mechanism for ethylene oligomerization
Jere D. Fellmann, Gregory A. Rupprecht, and Richard R. Schrock
pp 5099 - 5101; DOI:
10.1021/ja00511a067
PDF
.alpha.-Chloroalkenylalanates. Their preparation and conversion into (E)-1-chloro-1-alkenes and mixed 1,1-dihalo-1-alkenes
George Zweifel, William Lewis, and Harry P. On
pp 5101 - 5102; DOI:
10.1021/ja00511a068
PDF
Biosynthesis of vitamin B1 in yeast. Origin of the thiazole unit
Robert L. White and Ian D. Spenser
pp 5102 - 5104; DOI:
10.1021/ja00511a069
PDF
Quenching of the fluorescent state of rubrene directly to the ground state
W. Atom Yee, V. A. Kuzmin, David S. Kliger, George S. Hammond, and Allen J. Twarowski
pp 5104 - 5106; DOI:
10.1021/ja00511a070
PDF
Photooxidation of azines. Evidence for a free-radical oxidation initiated by singlet oxygen
Michael E. Landis and David C. Madoux
pp 5106 - 5107; DOI:
10.1021/ja00511a071
PDF
Book Reviews

pp 5108 - 5110; DOI:
10.1021/ja00511a600
PDF

Issue 18


Consistent force field studies of intermolecular forces in hydrogen-bonded crystals. 1. Carboxylic acids, amides, and the C:O.cntdot..cntdot..cntdot.H- hydrogen bonds
S. Lifson, A. T. Hagler, and P. Dauber
pp 5111 - 5121; DOI:
10.1021/ja00512a001
PDF
Consistent force field studies of intermolecular forces in hydrogen-bonded crystals. 2. A benchmark for the objective comparison of alternative force fields
A. T. Hagler, S. Lifson, and P. Dauber
pp 5122 - 5130; DOI:
10.1021/ja00512a002
PDF
Consistent force field studies of intermolecular forces in hydrogen-bonded crystals. 3. The C:O.cntdot..cntdot..cntdot.H-O hydrogen bond and the analysis of the energetics and packing of carboxylic acids
A. T. Hagler, P. Dauber, and S. Lifson
pp 5131 - 5141; DOI:
10.1021/ja00512a003
PDF
Bond orbitals and intramolecular interactions. 1. Barriers to rotation and nonbonded interactions
A. Gavezzotti and L. S. Bartell
pp 5142 - 5146; DOI:
10.1021/ja00512a004
PDF
Pseudorotational intersystem crossing in d6 complexes
Keith F. Purcell
pp 5147 - 5152; DOI:
10.1021/ja00512a005
PDF
Time development of nuclear Overhauser effects in multispin systems
Aksel A. Bothner-By and J. H. Noggle
pp 5152 - 5155; DOI:
10.1021/ja00512a006
PDF
Optical rotatory dispersion studies. 127. Chirality due to carbon-13 substitution. Synthesis and chiroptical properties of (1S)-2-adamantanone-4-13C and (1S)-2,4-adamantanedione-4-13C
Y. Lawrence Sing, H. Numan, Hans Wynberg, and Carl Djerassi
pp 5155 - 5158; DOI:
10.1021/ja00512a007
PDF
Far-ultraviolet circular dichroism of solutions, gels, and films of chitins
L. A. Buffington and E. S. Stevens
pp 5159 - 5162; DOI:
10.1021/ja00512a008
PDF
Effect of external pressure on the spectroscopic and conformational properties of the visual chromophores
Robert R. Birge, Charles T. Berge, Lesly L. Noble, and Robert C. Neuman
pp 5162 - 5170; DOI:
10.1021/ja00512a009
PDF
Co-oligopeptides containing two aromatic residues spaced by glycyl residues. 11. A conformational study of tryptophan- and glycine-containing oligopeptides based on the temperature dependence of proton NMR spectra
Antonio Baici, Vincenzo Rizzo, Peter Skrabal, and Pier Luigi Luisi
pp 5170 - 5178; DOI:
10.1021/ja00512a010
PDF
NMR studies of enolate anions. 6. A carbon-13 NMR study of alkali metal chelation by 3-alkylacetylacetonates
Morton Raban and Demitris P. Haritos
pp 5178 - 5182; DOI:
10.1021/ja00512a011
PDF
Electronic structure and photoelectron spectrum of 1,5,9-cyclododecatriyne
K. N. Houk, Robert W. Strozier, Cielo Santiago, Ruth Wells Gandour, and K. Peter C. Vollhardt
pp 5183 - 5185; DOI:
10.1021/ja00512a012
PDF
Optically active amines. 28. Spectral observations on chiral N-substituted p-nitroanilines
Howard E. Smith, William I. Cozart, Tomas De Paulis, and Fu-Ming Chen
pp 5186 - 5193; DOI:
10.1021/ja00512a013
PDF
Influence of self-association on the solubility of phenol in isooctane and cyclohexane
Bradley D. Anderson, J. Howard Rytting, and Takeru Higuchi
pp 5194 - 5197; DOI:
10.1021/ja00512a014
PDF
Ab initio studies of the electronic structure and geometry of uranium pentafluoride using relativistic effective core potentials
Willard R. Wadt and P. Jeffrey Hay
pp 5198 - 5206; DOI:
10.1021/ja00512a015
PDF
Generalized transition state theory. Canonical variational calculations using the bond energy-bond order method for bimolecular reactions of combustion products
Bruce C. Garrett and Donald G. Truhlar
pp 5207 - 5217; DOI:
10.1021/ja00512a016
PDF
Doubly bridged species as transition states or intermediates in transition metal redox reactions
Jeremy K. Burdett
pp 5217 - 5221; DOI:
10.1021/ja00512a017
PDF
Structure of the disilene ground state: singlet silylsilylene
Lawrence C. Snyder and Zelda R. Wasserman
pp 5222 - 5223; DOI:
10.1021/ja00512a018
PDF
A molecular orbital study of the conformational consequences of stabilizing and destabilizing orbital interactions in hydrazine, diphosphine, and aminophosphine
Alan H. Cowley, David John Mitchell, Myung-Hwan Whangbo, and Saul Wolfe
pp 5224 - 5231; DOI:
10.1021/ja00512a019
PDF
Formation of stable monolayer membranes and related structures in dilute aqueous solution from two-headed ammonium amphiphiles
Yoshio Okahata and Toyoki Kunitake
pp 5231 - 5234; DOI:
10.1021/ja00512a020
PDF
Cadmium(I) and dicadmium(I). Crystal structures of cadmium(II)-exchanged zeolite A evacuated at 500.degree.C and of its cadmium sorption complex
Lynne B. McCusker and Karl Seff
pp 5235 - 5239; DOI:
10.1021/ja00512a021
PDF
Comparison of thermodynamic parameters obtained by gas chromatographic and spectrophotometric methods for the interaction of a Lewis acid transition metal complex with a Lewis base
Craig S. Chamberlain and Russell S. Drago
pp 5240 - 5245; DOI:
10.1021/ja00512a022
PDF
Characterization and reaction studies of dimeric molybdenum(III) complexes with bridging dithiolate ligands. Catalytic reduction of acetylene to ethylene
M. Rakowski DuBois, R. Curtis Haltiwanger, Douglas J. Miller, and Gregory Glatzmaier
pp 5245 - 5252; DOI:
10.1021/ja00512a023
PDF
Low-temperature electronic spectra of solid tetrakis(dimethyldimethylenephosphonium)dimolybdenum and -dichromium
F. Albert Cotton and Phillip E. Fanwick
pp 5252 - 5255; DOI:
10.1021/ja00512a024
PDF
Electronic structure of Ru2(O2CR)4+ and Rh2(O2CR)4+ complexes
Joe G. Norman, George E. Renzoni, and David A. Case
pp 5256 - 5267; DOI:
10.1021/ja00512a025
PDF
Stereochemically rigid seven-coordinate complexes. Synthesis, structure, and dynamic stereochemistry of chlorotris(N,N-dialkylmonothiocarbamato)titanium(IV) complexes
Stephen L. Hawthorne and Robert C. Fay
pp 5268 - 5277; DOI:
10.1021/ja00512a026
PDF
Olefin formation from platinacyclobutanes
Thomas H. Johnson and Sheng-San Cheng
pp 5277 - 5280; DOI:
10.1021/ja00512a027
PDF
Rearrangement in the palladium-catalyzed cyclization of .alpha.-substituted N-acryloyl-o-bromoanilines
Marc O. Terpko and Richard F. Heck
pp 5281 - 5283; DOI:
10.1021/ja00512a028
PDF
Lewis acid catalyzed reactions of methyl propiolate with unactivated alkenes
Barry B. Snider, David J. Rodini, Robin S. E. Conn, and Stuart Sealfon
pp 5283 - 5293; DOI:
10.1021/ja00512a029
PDF
Synthesis and reactions of stable alkoxyaryltrifluoroperiodinanes. A "tamed" analog of iodine pentafluoride for use in oxidations of amines, alcohols, and other species
Ronald L. Amey and J. C. Martin
pp 5294 - 5299; DOI:
10.1021/ja00512a030
PDF
Hydrogen transfer reactions of arenes in molten antimony trichloride
A. S. Dworkin, M. L. Poutsma, J. Brynestad, L. L. Brown, L. O. Gilpatrick, and G. P. Smith
pp 5299 - 5303; DOI:
10.1021/ja00512a031
PDF
Solvolysis of alkyl p-hydroxybenzoates in fused lithium-sodium-potassium acetate
Ernest H. Braue, V. T. Alexander, Louis L. Burton, Thomas I. Crowell, and Christopher P. Devlin
pp 5303 - 5309; DOI:
10.1021/ja00512a032
PDF
Stable carbocations. 219. Patterns of carbon-13 chemical shift response to substituent effects in arylcarbenium ions. The 2-furyl, 2-thienyl, 2-benzofuryl, and 2-benzothienyl systems
David A. Forsyth and George A. Olah
pp 5309 - 5316; DOI:
10.1021/ja00512a033
PDF
Onium ions. 20. Ambident reactivity of the nitronium ion. Nitration vs. oxidation of heteroorganic (sulfur, selenium, phosphorus, arsenic, antimony) compounds. Preparation and NMR spectroscopic (carbon-13, nitrogen-15, phosphorus-31) study of nitro and nitrito onium ions
George A. Olah, B. G. Balaram Gupta, and Subhash C. Narang
pp 5317 - 5322; DOI:
10.1021/ja00512a034
PDF
Structure and stability of radical cations from cyclic and open-chain dithia compounds in aqueous solutions
K. D. Asmus, D. Bahnemann, C. H. Fischer, and D. Veltwisch
pp 5322 - 5329; DOI:
10.1021/ja00512a035
PDF
Disproportionation among aryloxyphosphoranes
Irving S. Sigal and F. H. Westheimer
pp 5329 - 5334; DOI:
10.1021/ja00512a036
PDF
Ionization of aryloxyphosphoranes in acetonitrile: rates and equilibriums
Irving S. Sigal and F. H. Westheimer
pp 5334 - 5338; DOI:
10.1021/ja00512a037
PDF
Photochemical generation of aryl phosphonium ylides
Marye Anne Fox
pp 5339 - 5343; DOI:
10.1021/ja00512a038
PDF
Solid state photochemistry of N,N-dialkyl-.alpha.-oxoamides. Type II reactions in the crystalline state
Hiromu Aoyama, Tadashi Hasegawa, and Yoshimori Omote
pp 5343 - 5347; DOI:
10.1021/ja00512a039
PDF
Chemiluminescent reactions of lucigenin. 1. Reactions of lucigenin with hydrogen peroxide
Richard Maskiewicz, Dotsevi Sogah, and Thomas C. Bruice
pp 5347 - 5354; DOI:
10.1021/ja00512a040
PDF
Chemiluminescent reactions of lucigenin. 2. Reactions of lucigenin with hydroxide ion and other nucleophiles
Richard Maskiewicz, Dotsevi Sogah, and Thomas C. Bruice
pp 5355 - 5364; DOI:
10.1021/ja00512a041
PDF
Total synthesis of (.+-.)-pederamide
Michael A. Adams, Angelina J. Duggan, Joel Smolanoff, and Jerrold Meinwald
pp 5364 - 5370; DOI:
10.1021/ja00512a042
PDF
Total synthesis of the yohimbines
Ernest Wenkert, Timothy D. J. Halls, Gerhard Kunesch, Kazuhiko Orito, Richard L. Stephens, Wayne A. Temple, and Jhillu S. Yadav
pp 5370 - 5376; DOI:
10.1021/ja00512a043
PDF
Kinetics and mechanisms of carbon monoxide dissociation from chelated heme-carbon monoxide complexes. Models for hemoprotein reactions
T. G. Traylor, Dwane Campbell, V. Sharma, and Jon Geibel
pp 5376 - 5383; DOI:
10.1021/ja00512a044
PDF
Preparation and characterization of beaded poly(N-acrylylpyrrolidine): bidirectional synthesis of Cys-, His-, Gln-, or Glu-containing polypeptides
Glenn L. Stahl, Roderich Walter, and Clark W. Smith
pp 5383 - 5394; DOI:
10.1021/ja00512a045
PDF
Laser photolysis of hemochromes. Kinetics of nitrogenous bases binding to four-coordinated and five-coordinated iron(II) tetraphenylporphine
Daniel Lavalette, Catherine Tetreau, and Michel Momenteau
pp 5395 - 5401; DOI:
10.1021/ja00512a046
PDF
Ferric ion sequestering agents. 2. Kinetics and mechanism of iron removal from transferrin by enterobactin and synthetic tricatechols
Carl J. Carrano and Kenneth N. Raymond
pp 5401 - 5404; DOI:
10.1021/ja00512a047
PDF
Enzymes in organic synthesis. 16. Heterocyclic ketones as substrates of horse liver alcohol dehydrogenase. Stereospecific reductions of 2-substituted tetrahydrothiopyran-4-ones
John Davies and J. Bryan Jones
pp 5405 - 5410; DOI:
10.1021/ja00512a048
PDF
Dianion mediated cycloreversions. A novel pyrimidinedione to pyridone conversion
Robert N. Comber, John S. Swenton, and Allan J. Wexler
pp 5411 - 5412; DOI:
10.1021/ja00512a049
PDF
Stereoselective hydrogenation of dehydrophenylalanine in a cyclic tetrapeptide. Synthesis of [Ala4]-chlamydocin
Daniel H. Rich and Ronald D. Jasensky
pp 5412 - 5414; DOI:
10.1021/ja00512a050
PDF
Synthetic reactions using organotin and sulfur compounds. 3. Regioselective desulfonylation of allylic sulfones with organotin hydride involving double migration of the double bond
Y. Ueno, S. Aoki, and M. Okawara
pp 5414 - 5415; DOI:
10.1021/ja00512a051
PDF
Nitrogen-15 NMR of cis-diamine-platinum(II) complexes in aqueous solution
Mohammed Alei, Phillip J. Vergamini, and William E. Wageman
pp 5415 - 5417; DOI:
10.1021/ja00512a052
PDF
Reactions at the rhodium vertex of a rhodacarborane cluster. Preparation, crystal and solution structure, and reactions of 3,3-(Ph3P)2-3-(HSO4)-3,1,2-RhC2B9H11.cntdot.O(C2H5)2
W. C. Kalb, R. G. Teller, and M. F. Hawthorne
pp 5417 - 5419; DOI:
10.1021/ja00512a053
PDF
Novel applications of chiral polymer and liquid crystalline polymer hosts for the characterization of intramolecular charge-transfer and exciton bands in dicesium tetracyanoplatinate by circular dichroism spectropolarimetry
F. D. Saeva, G. R. Olin, R. F. Ziolo, and P. Day
pp 5419 - 5421; DOI:
10.1021/ja00512a054
PDF
Reaction of carbon monoxide with (.eta.5-pentamethylcyclopentadienyl)tetramethyltantalum. Intramolecular reductive coupling of carbon monoxide via an ".eta.2-acetone" intermediate
C. D. Wood and R. R. Schrock
pp 5421 - 5422; DOI:
10.1021/ja00512a055
PDF
Coupling of acetylenes held proximate to a metal: alkyne-alkyne interactions in cis-phosphinoacetylene complexes
Arthur J. Carty, Nicholas J. Taylor, and David K. Johnson
pp 5422 - 5424; DOI:
10.1021/ja00512a056
PDF
Barriers against configurational isomerization at tetrahedral nickel(II)
Rudolf Knorr and Friedrich Ruf
pp 5424 - 5425; DOI:
10.1021/ja00512a057
PDF
Time-resolved CIDEP and ESR studies of heavy metal-organic radical complexes. The uranyl-phenanthroquinone radical ions
J. W. M. DeBoer, K. S. Chen, Y. C. Chan Chung, and J. K. S. Wan
pp 5425 - 5427; DOI:
10.1021/ja00512a058
PDF
Dimethylsilylene, (CH3)2Si
Timothy J. Drahnak, Josef Michl, and Robert West
pp 5427 - 5428; DOI:
10.1021/ja00512a059
PDF
Kinetics and mechanism of the reaction of palladium(II) complexes of o-diphenylphosphinothioanisole and o-diphenylphosphinoselenoanisole with the nucleophiles thiocyanate and iodide
D. Max Roundhill, William B. Beaulieu, and Uttarayan Bagchi
pp 5428 - 5430; DOI:
10.1021/ja00512a060
PDF
Protonation of some arenes in an aprotic medium
A. C. Buchanan, A. S. Dworkin, J. Brynestad, L. O. Gilpatrick, M. L. Poutsma, and G. Pedro Smith
pp 5430 - 5431; DOI:
10.1021/ja00512a061
PDF
3,3,4,4-Tetraphenyl-1,2-oxathiolan-5-one 2-oxide. Synthesis, structure, and selected chemistry
Harold Kohn, P. Charumilind, and S. H. Simonsen
pp 5431 - 5432; DOI:
10.1021/ja00512a062
PDF
An example of alkyl group transfer in a Truce-Smiles rearrangement
Donald M. Snyder and William E. Truce
pp 5432 - 5433; DOI:
10.1021/ja00512a063
PDF
Unequivocal determination of the site of metal-carbonyl bond breaking in tetracarbonylchromium(0) complexes of o-phenanthroline and 2,2'-dipyridyl
Gerard R. Dobson and Khalil J. Asali
pp 5433 - 5435; DOI:
10.1021/ja00512a064
PDF
Cyanoketenes. Cycloadditions of halocyanoketenes to benzaldehydes
Harold W. Moore, Frank Mercer, Donna Kunert, and Pamela Albaugh
pp 5435 - 5436; DOI:
10.1021/ja00512a065
PDF
Preparation and catalytic properties of polymer- and silica-supported bimetallic clusters
Ronald Pierantozzi, Kevin J. McQuade, Bruce C. Gates, Margit Wolf, Helmut Knoezinger, and Werner Ruhmann
pp 5436 - 5438; DOI:
10.1021/ja00512a066
PDF
Structural order in liquid calcium chloride hexahydrate
G. Licheri, G. Piccaluga, and G. Pinna
pp 5438 - 5439; DOI:
10.1021/ja00512a067
PDF
An unexpected blue shift caused by differential solvation of a chromophore oriented in a lipid bilayer
Leslie M. Loew, Logan Simpson, Alfred Hassner, and Vazken Alexanian
pp 5439 - 5440; DOI:
10.1021/ja00512a068
PDF
Electrophile-induced disproportionation of the neutral formyl (.eta.-C5H5)Re(PPh3)(NO)(CHO). Generation of cationic rhenium carbenes of the formula [(.eta.-C5H5)Re(PPh3)(NO)(CHX)]+ (X = hydrogen, methoxy, hydroxy)
Wai-Kwok Wong, Wilson Tam, and J. A. Gladysz
pp 5440 - 5442; DOI:
10.1021/ja00512a069
PDF
Direct measurement of the rate of intramolecular electron transfer in a diruthenium mixed-valence complex
Carol Creutz, Peter Kroger, Tadashi Matsubara, Thomas L. Netzel, and Norman Sutin
pp 5442 - 5444; DOI:
10.1021/ja00512a070
PDF
Design, stabilization, and efficiency of organometallic "electron reservoirs". 19-Electron sandwiches .eta.5-C5R5FeI-.eta.6-C6R'6, a key class active in redox catalysis
Didier Astruc, Jean Rene Hamon, Gisela Althoff, Enrique Roman, Patrick Batail, Pascal Michaud, Jean Pierre Mariot, Francois Varret, and Daniel Cozak
pp 5445 - 5447; DOI:
10.1021/ja00512a071
PDF
Mechanism of the reaction between organo transition metal alkyls and hydrides. A model for the aldehyde-forming step in the oxo process
William D. Jones and Robert G. Bergman
pp 5447 - 5449; DOI:
10.1021/ja00512a072
PDF
Intrinsic steric deuterium isotope effects on proton and carbon-13 chemical shifts
Frank A. L. Anet and Armenag H. Dekmezian
pp 5449 - 5451; DOI:
10.1021/ja00512a073
PDF
Metallacyclopentane to metallacyclobutane ring contraction
Stephan J. McLain, Jose Sancho, and Richard R. Schrock
pp 5451 - 5453; DOI:
10.1021/ja00512a074
PDF
The x-ray photoelectron spectra of inorganic molecules. 24. Satellite structure in the x-ray photoelectron spectra of metal complexes of alkyl isocyanides
Patrick Brant, William S. Mialki, and Richard A. Walton
pp 5453 - 5454; DOI:
10.1021/ja00512a075
PDF
Self-assembly of molybdenum-iron-sulfur clusters as a synthetic approach to the molybdenum site in nitrogenase. Identification of the major products formed by the system FeCl3/MS42-/C2H5SH (M = Molybdenum, tungsten)
Thomas E. Wolff, Jeremy M. Berg, Philip P. Power, Keith O. Hodgson, R. H. Holm, and Richard B. Frankel
pp 5454 - 5456; DOI:
10.1021/ja00512a076
PDF
Additions and Corrections - Synthesis Using Transition Metal Diatomic Molecules. Dirhodium Octacarbonyl Rh2(CO)8, and Diiridium Octacabonyl, Ir2(CO)8
L. A. Hanlan, and G. A. Ozin
pp 5456 - 5456; DOI:
10.1021/ja00512a600
PDF
Additions and Corrections - The Structure of 1,3,6,8-Tetra-tert-butylnapththalene
Jady Handal, John G. White, Richard W. Franck, Y. H .Yuh, and Norman L. Allinger
pp 5456 - 5456; DOI:
10.1021/ja00512a601
PDF
Additions and Corrections - Catalytic Homogenous Hydrogenation of Arenes. 6. Reaction Scope for the η3-C3H5Co[P(OCH3)3]3 Catalyst
L. S. Stuhl, M. Rakowski DuBois, F. J. Hirsekorn, J. R. Bleeke, S. E. Stevens, and E. L. Muetterties
pp 5456 - 5456; DOI:
10.1021/ja00512a602
PDF
Additions and Corrections - "Increased Valence" When the Octet Rule is Obeyed. A Reply to a Challenge.
Richard D. Harcourt
pp 5456 - 5456; DOI:
10.1021/ja00512a603
PDF
Additions and Corrections - Intramolecular Dibromo Ketone-Iron Carbonyl Reaction in Terpene Synthesis
R. Noyori, M. Nishizawa, F. Shimizu, Y. Hayakawa, Keiji Maruoka, Shinsaku Hashimoto, Hishashi Yamamoto, and Hitosi Nozaki
pp 5456 - 5456; DOI:
10.1021/ja00512a604
PDF
Additions and Corrections - Biomimetic Polyene Cyclizations. A Comparison of the Phenylacetylenic and Styryl Terminators in Influencing the Stereoselectivity of Processes Leading to Steroidal Products
William S. Johnson, Leslie R. Hughes, and Janet L. Carlson
pp 5457 - 5457; DOI:
10.1021/ja00512a605
PDF
Additions and Corrections - Cyclization of Olefinic Tosylhydrazones under Acidic Conditions. A Facile Synthesis of Bicyclic Azo Compounds.
R. Marshall Wilson, and John W. Rekers
pp 5457 - 5457; DOI:
10.1021/ja00512a606
PDF
Book Reviews

pp 5457 - 5458; DOI:
10.1021/ja00512a607
PDF

Issue 19


Rotational barriers of allyl anions in solution
Tyler B. Thompson and Warren T. Ford
pp 5459 - 5464; DOI:
10.1021/ja00513a001
PDF
The cubic phase of monoglyceride-water systems. Arguments for a structure based upon lamellar bilayer units
Goeran Lindblom, Kaare Larsson, Lennart Johansson, Krister Fontell, and Sture Forsen
pp 5465 - 5470; DOI:
10.1021/ja00513a002
PDF
Use of paramagnetic probes for the study of liquid adsorbed on porous supports. Copper(II) in water solution
Valerio Bassetti, Leo Burlamacchi, and Giacomo Martini
pp 5471 - 5477; DOI:
10.1021/ja00513a003
PDF
Free energies of solution of rare gases and alkanes in water and nonaqueous solvents. A quantitative assessment of the hydrophobic effect
Michael H. Abraham
pp 5477 - 5484; DOI:
10.1021/ja00513a004
PDF
Consequences of charge reversal in gaseous alkoxide ions. Oxenium ions
Maurice M. Bursey, J. Ronald Hass, Donald J. Harvan, and Carol E. Parker
pp 5485 - 5489; DOI:
10.1021/ja00513a005
PDF
Consequences of charge reversal of gaseous formate and acetate ions. Acyloxy ions
Maurice M. Bursey, Donald J. Harvan, Carol E. Parker, Lee G. Pedersen, and J. Ronald Hass
pp 5489 - 5493; DOI:
10.1021/ja00513a006
PDF
Gas-phase ion-molecule association reactions. A statistical phase space theory approach
Lewis Bass, Walter J. Chesnavich, and Michael T. Bowers
pp 5493 - 5502; DOI:
10.1021/ja00513a007
PDF
Molecular activation with low-intensity CW infrared laser radiation. Multiphoton dissociation of ions derived from diethyl ether
D. S. Bomse, R. L. Woodin, and J. L. Beauchamp
pp 5503 - 5512; DOI:
10.1021/ja00513a008
PDF
Thermodynamics of hydrolysis of aliphatic ketals. An entropy component of steric effects
Kenneth B. Wiberg and Robert R. Squires
pp 5512 - 5515; DOI:
10.1021/ja00513a009
PDF
Linear and circular dichroism studies of .pi. .fwdarw. .pi.* transitions in steroidal dienes and .alpha.,.beta.-unsaturated ketones
Jacek Gawronski, Tommy Liljefors, and Bengt Norden
pp 5515 - 5522; DOI:
10.1021/ja00513a010
PDF
Application of force field calculations to organic chemistry. 9. Possibilities of correlated conformational processes among mobile ethano bridges of polycyclic hydrocarbons by bond drive calculations
Eiji Osawa
pp 5523 - 5529; DOI:
10.1021/ja00513a011
PDF
The inductive effect in molecules and ions
A. F. Marchington, S. C. R. Moore, and W. G. Richards
pp 5529 - 5532; DOI:
10.1021/ja00513a012
PDF
Role of hyperconjugation in secondary .beta.-deuterium isotope effects
D. J. DeFrees, M. Taagepera, B. A. Levi, S. K. Pollack, K. D. Summerhays, R. W. Taft, M. Wolfsberg, and W. J. Hehre
pp 5532 - 5536; DOI:
10.1021/ja00513a013
PDF
Structure of C4H7+
Beverly A. Levi, Edward S. Blurock, and Warren J. Hehre
pp 5537 - 5539; DOI:
10.1021/ja00513a014
PDF
An ab initio molecular orbital study of the structures and stabilities of the C2H4O+.cntdot. isomers
Willem J. Bouma, John K. MacLeod, and Leo Radom
pp 5540 - 5545; DOI:
10.1021/ja00513a015
PDF
Molecular mechanics and ab initio studies of the structures, heats of formation, conformations, and strain energies of azoalkanes
James Kao and Tai-Nang Huang
pp 5546 - 5557; DOI:
10.1021/ja00513a016
PDF
An addendum to a recent paper by Halgren, Lipscomb, and their co-workers concerning the relative accuracies of several current MO methods
Michael J. S. Dewar and George P. Ford
pp 5558 - 5561; DOI:
10.1021/ja00513a017
PDF
Theory of hyperfine fields at iron-57 and nitrogen-14 sites in metmyoglobin and related compounds
S. K. Mun, Jane C. Chang, and T. P. Das
pp 5562 - 5569; DOI:
10.1021/ja00513a018
PDF
Laser photoelectron spectrometry of the negative ions of iron and iron carbonyls. Electron affinity determination for the series Fe(CO)n, n = 0,1,2,3,4
P. C. Engelking and W. C. Lineberger
pp 5569 - 5573; DOI:
10.1021/ja00513a019
PDF
Electric dichroism spectroscopy in the vacuum ultraviolet. 2. Formaldehyde, acetaldehyde, an acetone
G. C. Causley and B. R. Russell
pp 5573 - 5578; DOI:
10.1021/ja00513a020
PDF
Theory and application of photoelectron spectroscopy. 80. Photoelectron spectra of 2,5-dehydrotropylidene, 3,6-dehydrooxepin, and fulvenallene
Claus Mueller, Armin Schweig, Walter Thiel, Walter Grahn, Robert G. Bergman, and K. Peter C. Vollhardt
pp 5579 - 5581; DOI:
10.1021/ja00513a021
PDF
Competitive photoelectrochemical oxidation of reducing agents at the titanium dioxide photoanode
Akira Fujishima, Tooru Inoue, and Kenichi Honda
pp 5582 - 5588; DOI:
10.1021/ja00513a022
PDF
High pressure NMR kinetics. 8. High-pressure kinetic evidence for an associative-dissociative changeover for solvent exchange mechanism on the divalent metal ions along the first-row transition metals
Felix K. Meyer, Kenneth E. Newman, and Andre E. Merbach
pp 5588 - 5592; DOI:
10.1021/ja00513a023
PDF
Electron transfer with organometals. Steric effects as probes for outer-sphere and inner-sphere oxidations of homoleptic alkylmetals with iron(III) and iridate(IV) complexes
C. L. Wong and J. K. Kochi
pp 5593 - 5603; DOI:
10.1021/ja00513a024
PDF
Reactions of the SH- and S2- groups in W(CO)5(SH)- and .mu.-S[W(CO)5]22-
Richard G. W. Gingerich and Robert J. Angelici
pp 5604 - 5608; DOI:
10.1021/ja00513a025
PDF
Metal ion coordination to the exocyclic amine in a pyrimidine complex. Structure of (1-methylcytosinato)pentaammineruthenium(III) hexafluorophosphate,[Ru(NH3)5(1-MeCyt-)](PF6)2
Bradford J. Graves and Derek J. Hodgson
pp 5608 - 5612; DOI:
10.1021/ja00513a026
PDF
Synthesis and phosphorus-31 NMR studies of unsymmetrical cis-diphosphinoalkenes and their complexes with nickel(II), palladium(II), and platinum(II)
A. J. Carty, D. K. Johnson, and S. E. Jacobson
pp 5612 - 5619; DOI:
10.1021/ja00513a027
PDF
Molecular structure of bis(dimethylamino)difluorosulfurane. The first x-ray crystal structure of a fluorosulfurane
A. H. Cowley, P. E. Riley, J. S. Szobota, and M. L. Walker
pp 5620 - 5624; DOI:
10.1021/ja00513a028
PDF
EXAFS studies of proteins and model compounds containing dimeric and tetrameric iron-sulfur clusters
Boon-Keng Teo, R. G. Shulman, G. S. Brown, and A. E. Meixner
pp 5624 - 5631; DOI:
10.1021/ja00513a029
PDF
Neutron diffraction analysis of the structure of tetrakis(.eta.-cyclopentadienyl)trihydrotetranickel
Thomas F. Koetzle, Joern Mueller, Donald L. Tipton, Donald W. Hart, and Robert Bau
pp 5631 - 5637; DOI:
10.1021/ja00513a030
PDF
Analysis of the oscillations in "beating mercury heart" systems
Joel Keizer, Peter A. Rock, and Shu-Wai Lin
pp 5637 - 5649; DOI:
10.1021/ja00513a031
PDF
Reactions of methyl cations with ethylsilanes
G. W. Goodloe and F. W. Lampe
pp 5649 - 5653; DOI:
10.1021/ja00513a032
PDF
Stereoselective formation and electrophilic substitution of aldehyde hydrazone lithio anions
Kenneth G. Davenport, Herbert Eichenauer, Dieter Enders, Martin Newcomb, and David E. Bergbreiter
pp 5654 - 5659; DOI:
10.1021/ja00513a033
PDF
1,5-Hydride shifts in vinyl cation intermediates produced upon the acylation of acetylenes
M. I. Kanishchev, A. A. Shegolev, W. A. Smit, Ronald Caple, and Michael J. Kelner
pp 5660 - 5671; DOI:
10.1021/ja00513a034
PDF
Crystal structure and solid-state behavior of a diazonium iodide: 3-carboxy-2-naphthalenediazonium iodide hydrate
J. Z. Gougoutas
pp 5672 - 5675; DOI:
10.1021/ja00513a035
PDF
In situ nitrogen-15 nuclear magnetic resonance observation of the Fischer indolization reaction. Nitrogen-15 NMR characterization of amide-imine intermediates
A. W. Douglas
pp 5676 - 5678; DOI:
10.1021/ja00513a036
PDF
Solution chemistry of the syn- and anti-tetrahydrodiol epoxides, the syn- and anti-tetrahydrodimethoxy epoxides, and the 1,2- and 1,4-tetrahydro epoxides of naphthalene
Allyn R. Becker, John M. Janusz, and Thomas C. Bruice
pp 5679 - 5687; DOI:
10.1021/ja00513a037
PDF
Oxidation of amines with sulfonyl peroxides. 5. Base-promoted, imine-forming eliminations in N-benzyl-O-arylsulfonylhydroxylamines produced from benzylamines and sulfonyl peroxides
Robert V. Hoffman and Edward L. Belfoure
pp 5687 - 5692; DOI:
10.1021/ja00513a038
PDF
Cyclic peroxides. 86. .alpha.-Pyrone endoperoxides. Synthesis, thermal decomposition, and chemiluminescence
Waldemar Adam and Ihsan Erden
pp 5692 - 5696; DOI:
10.1021/ja00513a039
PDF
Multiphase fluorescence quenching by a surfactant nitroxyl radical
Samir S. Atik, C. L. Kwan, and Lawrence A. Singer
pp 5696 - 5702; DOI:
10.1021/ja00513a040
PDF
Photooxidation of 1,1,1-trimethyl-2,2,2-triphenyldisilane by dimethyl sulfoxide
Robert E. Swaim and William P. Weber
pp 5703 - 5706; DOI:
10.1021/ja00513a041
PDF
Photochemical transformations. 24. Comparison of ionic intermediates produced photochemically with corresponding ground-state intermediates. Initial studies in some chlorobenzooctadienyl systems
Stanley J. Cristol and Robert M. Strom
pp 5707 - 5716; DOI:
10.1021/ja00513a042
PDF
Thermal, photochemical, and photonucleated thermal dehydration of p-hydroxytriarylmethanols in solids. (3,5-Dimethyl-4-hydroxyphenyl)diphenylmethanol and (3,5-dibromo-4-hydroxyphenyl)diphenylmethanol. X-ray crystal structures of (4-hydroxyphenyl)diphenylmethanol and its 3,5-dimethyl derivative
Terry W. Lewis, David Y. Curtin, and Iain C. Paul
pp 5717 - 5725; DOI:
10.1021/ja00513a043
PDF
Photochemical synthesis. 78. Thione photochemistry. 29. Mechanism of photocyclization of aralkyl thiones
K. W. Ho and P. De Mayo
pp 5725 - 5732; DOI:
10.1021/ja00513a044
PDF
Evaluation of addition rates of the thiyl radicals to vinyl monomers by flash photolysis. 2. Substituent effect on addition of substituted benzenethiyl radicals to methyl methacrylate or styrene
Osamu Ito and Minoru Matsuda
pp 5732 - 5735; DOI:
10.1021/ja00513a045
PDF
Intramolecular excimer formation in saturated amines. A probe of linear chain alkane conformational distribution
Arthur M. Halpern, Michael W. Legenza, and B. R. Ramachandran
pp 5736 - 5743; DOI:
10.1021/ja00513a046
PDF
Photochemical transformations of small ring compounds. 107. Studies dealing with the intramolecular hydrogen atom transfer reaction of tetrasubstituted cyclopropenes
Albert Padwa, Thomas J. Blacklock, Chuen S. Chou, and Naoto Hatanaka
pp 5743 - 5759; DOI:
10.1021/ja00513a047
PDF
Crystal structure of 9-hydroxyphenalenone: a very short intramolecular hydrogen bond system
C. Svensson, S. C. Abrahams, J. L. Bernstein, and R. C. Haddon
pp 5759 - 5764; DOI:
10.1021/ja00513a048
PDF
Decarboxylation of 6-nitrobenzisoxazole-3-carboxylate in benzene catalyzed by crown ethers and their polymers
Johannes Smid, Anjani J. Varma, and Shailesh C. Shah
pp 5764 - 5769; DOI:
10.1021/ja00513a049
PDF
Cation effects on the equilibrium acidity of carbon acids in methanol
Robert D. Guthrie and M. Govindan
pp 5769 - 5773; DOI:
10.1021/ja00513a050
PDF
Mechanism of the base-catalyzed cleavage of imido esters to nitriles
H. F. Gilbert and W. P. Jencks
pp 5774 - 5779; DOI:
10.1021/ja00513a051
PDF
Reactions of cyanide with cobalamins
William W. Reenstra and William P. Jencks
pp 5780 - 5791; DOI:
10.1021/ja00513a052
PDF
Heat of formation for tert-butyl cation in the gas phase
R. G. McLoughlin and J. C. Traeger
pp 5791 - 5792; DOI:
10.1021/ja00513a053
PDF
Effect of alkyl substitution on the ease of oxidation of bicyclo[1.1.0]butanes. Experimental verification of PRDDO calculations for the nature of the HOMO of bicyclo[1.1.0]butane
Paul G. Gassman, Michael J. Mullins, Steven Richtsmeier, and David A. Dixon
pp 5793 - 5797; DOI:
10.1021/ja00513a054
PDF
Synthesis of .alpha.-(1 .fwdarw. 3)-branched dextrans by copolymerization and .alpha.-D-glucosidation
Hiroshi Ito and Conrad Schuerch
pp 5797 - 5806; DOI:
10.1021/ja00513a055
PDF
Temperature-dependent spin-state equilibrium in an azide-ferric heme octapeptide complex. A model system for the spin equilibriums of ferric heme proteins
Ya-Ping Huang and Richard J. Kassner
pp 5807 - 5810; DOI:
10.1021/ja00513a056
PDF
Crystal structure and molecular conformation of the cyclic hexapeptide cyclo-(Gly-L-Pro-Gly)2
E. C. Kostansek, W. E. Thiessen, D. Schomburg, and W. N. Lipscomb
pp 5811 - 5815; DOI:
10.1021/ja00513a057
PDF
Selenium-77 relaxation time studies on compounds of biological importance: dialkyl selenides, dialkyl diselenides, selenols, selenonium compounds, and seleno oxyacids
J. D. Odom, W. H. Dawson, and P. D. Ellis
pp 5815 - 5822; DOI:
10.1021/ja00513a058
PDF
Laser temperature jump study of solvent effects on proflavin stacking
T. G. Dewey, Dorothy A. Raymond, and Douglas H. Turner
pp 5822 - 5826; DOI:
10.1021/ja00513a059
PDF
Biosynthesis of the boron-containing macrodiolide antibiotic aplasmomycin
Tom S. S. Chen, Ching-Jer Chang, and Heinz G. Floss
pp 5826 - 5827; DOI:
10.1021/ja00513a060
PDF
A unique triple atom bridge: x-ray structure of the .mu.-selenido-.mu.-diselenido-bis(tetrachloro)tungstate(V) ion
Michael G. B. Drew, Gerald W. A. Fowles, Elizabeth M. Page, and David A. Rice
pp 5827 - 5828; DOI:
10.1021/ja00513a061
PDF
Enzymic synthesis of sn-glycerol 3-phosphate
Victor M. Rios-Mercadillo and George M. Whitesides
pp 5828 - 5829; DOI:
10.1021/ja00513a062
PDF
Conversion of the adenosine moieties of RNA into ATP for use in cofactor recycling
Hans Juergen Leuchs, Jerome M. Lewis, Victor M. Rios-Mercadillo, and George M. Whitesides
pp 5829 - 5830; DOI:
10.1021/ja00513a063
PDF
Photoreaction of hexacarbonylmolybdenum(0) and tricarbonyl(.eta.5-cyclopentadienyl)hydridomolybdenum(II) in the presence of cyclopentadiene. Substitution, oxidative addition, and hydrometalation
William C. Mills and Mark S. Wrighton
pp 5830 - 5832; DOI:
10.1021/ja00513a064
PDF
Monte Carlo computer simulation of hydrophobic bonding
S. Swaminathan and David L. Beveridge
pp 5832 - 5833; DOI:
10.1021/ja00513a065
PDF
Evidence for the synthesis of a stable .sigma.-bonded xenon-carbon compound: bis(trifluoromethyl)xenon
Laura J. Turbini, Robert E. Aikman, and Richard J. Lagow
pp 5833 - 5834; DOI:
10.1021/ja00513a066
PDF
Evidence of vibronic state "selectivity" in the photoracemization of tris(1,10-phenanthroline)chromium(III) ion in solution
Roger Sasseville and Cooper H. Langford
pp 5834 - 5836; DOI:
10.1021/ja00513a067
PDF
Ordered structure in dilute solutions of ionic biopolymers. 1. Preliminary small-angle x-ray scattering study of aqueous solutions of sodium polyacrylate
N. Ise, T. Okubo, Y. Hiragi, H. Kawai, T. Hashimoto, M. Fujimura, A. Nakajima, and H. Hayashi
pp 5836 - 5837; DOI:
10.1021/ja00513a068
PDF
Diels-Alder reactions of "pull-push" activated isoprenes
M. Gillard, C. T'Kint, E. Sonveaux, and L. Ghosez
pp 5837 - 5839; DOI:
10.1021/ja00513a069
PDF
Synthesis of (+)-spectinomycin
Stephen Hanessian and Rene Roy
pp 5839 - 5841; DOI:
10.1021/ja00513a070
PDF
Total synthesis of picrotoxinin
E. J. Corey and Homer L. Pearce
pp 5841 - 5843; DOI:
10.1021/ja00513a071
PDF
Asymmetric synthesis via axially dissymetric molecules. 2. A highly efficient synthesis of prostaglandin intermediates possessing the 15S configuration
R. Noyori, I. Tomino, and M. Nishizawa
pp 5843 - 5844; DOI:
10.1021/ja00513a072
PDF
Detection of localized conformational flexibility in horse heart cytochrome c by proton nuclear magnetic resonance
Phillip D. Burns and Gerd N. La Mar
pp 5844 - 5846; DOI:
10.1021/ja00513a073
PDF
Simultaneous emissions including intraligand emission and charge-transfer emission from [bis(triphenylphosphine)(phenanthroline)copper](1+)
Michael T. Buckner, Thomas G. Matthews, Fred E. Lytle, and David R. McMillin
pp 5846 - 5848; DOI:
10.1021/ja00513a074
PDF
Lanthanoids in organic synthesis. 5. Selective reductions of ketones in the presence of aldehydes
Jean Louis Luche and Andre Luis Gemal
pp 5848 - 5849; DOI:
10.1021/ja00513a075
PDF
An ab initio approach to organic reaction rates. Kinetic isotope effects in the reaction H + C2H4 .fwdarw. C2H5
Shigeru Nagase, Takayuki Fueno, and Keiji Morokuma
pp 5849 - 5851; DOI:
10.1021/ja00513a076
PDF
Correlation of the kinetics of electron-transfer processes with the change in reaction free energy. Application to electron-exchanged-initiated chemiluminescence reactions
Gary B. Schuster
pp 5851 - 5853; DOI:
10.1021/ja00513a077
PDF
Synthesis and reactivity of compounds with cyclobutane rings(s). 13. A simple, stereoselective, highly versatile synthesis of dichlorovinylcyclopropanecarboxylic acids via 2-chlorocyclobutanones
P. Martin, H. Greuter, and D. Bellus
pp 5853 - 5854; DOI:
10.1021/ja00513a078
PDF
Selection of nonprotonated carbon resonances in solid-state nuclear magnetic resonance
S. J. Opella and M. H. Frey
pp 5854 - 5856; DOI:
10.1021/ja00513a079
PDF
Detection of individual carbon resonances in solid proteins
S. J. Opella, M. H. Frey, and T. A. Cross
pp 5856 - 5857; DOI:
10.1021/ja00513a080
PDF
Chemistry of hypervalent sulfur. 9. Bond switch with participation of .pi.-bonded SIV in a thiadiazole ring system
Kinya Akiba, Takashi Kobayashi, and Shinichi Arai
pp 5857 - 5858; DOI:
10.1021/ja00513a081
PDF
Structure of (3-chloro-2-hydroxy-5-nitrophenyl)(2'-chlorophenyl)iodonium hydroxide inner salt
Samuel W. Page, Eugene P. Mazzola, Alan D. Mighell, Vicky L. Himes, and Camden R. Hubbard
pp 5858 - 5860; DOI:
10.1021/ja00513a082
PDF
Aluminum atom-benzene molecular complex: matrix isolation electron spin resonance study
Paul H. Kasai and D. McLeod
pp 5860 - 5862; DOI:
10.1021/ja00513a083
PDF
Hydrogenation and degradation of carbon disulfide by organometallic cluster hydride complexes. Reaction of carbon disulfide with (.mu.-dihydro)nonacarbonyl[dimethylphenylphosphine]triosmium
Richard D. Adams, Nancy M. Golembeski, and John P. Selegue
pp 5862 - 5863; DOI:
10.1021/ja00513a084
PDF
Intersystem crossing in hexahelicene
S. S. Kim and S. I. Weissman
pp 5863 - 5864; DOI:
10.1021/ja00513a085
PDF
Kinetic and thermodynamic control of the methyl migration (carbon monoxide insertion) reaction by strong Lewis acids
Susan Beda Butts, Elizabeth M. Holt, Steven H. Strauss, Nathaniel W. Alcock, Rebecca E. Stimson, and Duward F. Shriver
pp 5864 - 5866; DOI:
10.1021/ja00513a086
PDF
Book Reviews

pp 5866 - 5868; DOI:
10.1021/ja00513a600
PDF

Issue 20


Stereoelectronic effects in the reactions of phosphate diesters. Ab initio molecular orbital calculations of reaction surfaces. 2
David G. Gorenstein, Bruce A. Luxon, and John B. Findlay
pp 5869 - 5875; DOI:
10.1021/ja00514a001
PDF
Electronic properties of and reductive elimination from dimethylnickel. An ab initio MO-SCF-CI study
Bjoern Aakermark, Helge Johansen, Bjoern Roos, and Ulf Wahlgren
pp 5876 - 5883; DOI:
10.1021/ja00514a002
PDF
Molecular orbital constrained electron diffraction studies. Conformational behavior of 1,2-dimethylhydrazine
N. S. Chiu, H. L. Sellers, Lothar Schaefer, and K. Kohata
pp 5883 - 5889; DOI:
10.1021/ja00514a003
PDF
Stereochemistry in trivalent nitrogen compounds. 35. The electrosteric effect on sulfenamide torsional barriers. Barriers in trinitrobenzenesulfenamides and perhalobenzenesulfenamides
Morton Raban and Gaku Yamamoto
pp 5890 - 5895; DOI:
10.1021/ja00514a004
PDF
Spectroscopic and theoretical studies of metal cluster complexes. 1. The helium (He I) photoelectron spectrum of nonachlorotrirhenium. Calculations by the SCC DV X.alpha. method of nonachlorotrirhenium
William C. Trogler, Donald E. Ellis, and Joseph Berkowitz
pp 5896 - 5901; DOI:
10.1021/ja00514a005
PDF
An NMR investigation of the kinetics of dissociation of the zinc(II) complex of bleomycin antibiotics
R. E. Lenkinski and J. L. Dallas
pp 5902 - 5906; DOI:
10.1021/ja00514a006
PDF
Solvent effects on the photophysics of dibromoanthracene
Kam-Chu Wu and William R. Ware
pp 5906 - 5909; DOI:
10.1021/ja00514a007
PDF
Solvation enthalpies of organic anion radicals
Gerald R. Stevenson and Elmer Williams
pp 5910 - 5913; DOI:
10.1021/ja00514a008
PDF
Graph-theoretical formulation of London diamagnetism
Junichi Aihara
pp 5913 - 5917; DOI:
10.1021/ja00514a009
PDF
Use of configuration selection methods to study the sudden polarization effect
Vlasta Bonacic-Koutecky, Robert J. Buenker, and Sigrid D. Peyerimhoff
pp 5917 - 5922; DOI:
10.1021/ja00514a010
PDF
Homogeneous catalysis of the water gas shift reaction by ruthenium and other metal carbonyls. Studies in alkaline solutions
Charles Ungermann, Vincent Landis, Sergio A. Moya, Haim Cohen, Howard Walker, Ralph G. Pearson, Robert G. Rinker, and Peter C. Ford
pp 5922 - 5929; DOI:
10.1021/ja00514a011
PDF
Autoxidation of transition-metal complexes. Reaction of a 1:1 cobalt-molecular oxygen complex with acids to yield hydrogen peroxide. Kinetics and mechanism
Joseph J. Pignatello and Frederick R. Jensen
pp 5929 - 5939; DOI:
10.1021/ja00514a012
PDF
Thiolato-bridged dinuclear d8 iridium(I) complexes and their hydrogenation to form dihydridodiiridium(II)(Ir-Ir) complexes. Crystal and molecular structures of [Ir(.mu.-SBu-t)(CO)(P(OMe)3)]2 and of [Ir(H)(.mu.-SBu-t)(CO)(P(OMe)3)]2
J. J. Bonnet, A. Thorez, A. Maisonnat, J. Galy, and R. Poilblanc
pp 5940 - 5949; DOI:
10.1021/ja00514a013
PDF
A comparative study of the reactions of F-(tert-butyl) hypochlorite and F-methyl hypochlorite with simple sulfur compounds
Qui-Chee Mir, Kirk A. Laurence, Robert W. Shreeve, Daniel P. Babb, and Jean'ne M. Shreeve
pp 5949 - 5953; DOI:
10.1021/ja00514a014
PDF
Novel meso-substitution reactions of metalloporphyrins
Kevin M. Smith, Graham H. Barnett, Brian Evans, and Zoya Martynenko
pp 5953 - 5961; DOI:
10.1021/ja00514a015
PDF
A unified mechanism for thermal and photochemical activation of charge-transfer processes with organometals. Steric effects in the insertion of tetracyanoethylene
S. Fukuzumi, K. Mochida, and J. K. Kochi
pp 5961 - 5972; DOI:
10.1021/ja00514a016
PDF
Control of regioselectivity in the di-.pi.-methane rearrangements. Triplet-sensitized photoisomerization of benzonorbornadienes carrying cyano substituents in the aryl and vinyl segments
Leo A. Paquette, Audrey Yeh Ku, Cielo Santiago, Melvin D. Rozeboom, and K. N. Houk
pp 5972 - 5980; DOI:
10.1021/ja00514a017
PDF
Polar effects on di-.pi.-methane rearrangements. Regiospecificity in the triplet-sensitized photoisomerizations of 2-cyanobenzonorbornadienes carrying methoxy aryl substituents
Audrey Yeh Ku, Leo A. Paquette, Melvin D. Rozeboom, and K. N. Houk
pp 5981 - 5985; DOI:
10.1021/ja00514a018
PDF
Kinetics and mechanism of the hydrolysis of aryloxyphosphonium salts. Salt effects
Steven J. Kubisen and F. H. Westheimer
pp 5985 - 5990; DOI:
10.1021/ja00514a019
PDF
Kinetics and mechanism of the methanolysis of aryloxyphosphonium salts
Steven J. Kubisen and F. H. Westheimer
pp 5991 - 5994; DOI:
10.1021/ja00514a020
PDF
Mechanism of urea participation in phosphonate ester hydrolysis. Mechanistic and stereochemical criteria for enzymic formation and reaction of phosphorylated biotin
Ronald Kluger, Paul Percy Davis, and P. D. Adawadkar
pp 5995 - 6000; DOI:
10.1021/ja00514a021
PDF
Mechanism in electrophilic aliphatic substitution: a kinetic and stereochemical study of bromodemercuration with bromide ion catalysis
Lawrence M. Sayre and Frederick R. Jensen
pp 6001 - 6008; DOI:
10.1021/ja00514a022
PDF
Effect of precursor structures on arylcarbene processes in low-temperature matrices. Importance of topochemically controlled processes
Hideo Tomioka, Gary W. Griffin, and Kazuyoshi Nishiyama
pp 6009 - 6012; DOI:
10.1021/ja00514a023
PDF
Electrochemically induced aromatic nucleophilic substitution in liquid ammonia. Competition with electron transfer
Christian Amatore, Jacques Chaussard, Jean Pinson, Jean Michel Saveant, and Andre Thiebault
pp 6012 - 6020; DOI:
10.1021/ja00514a024
PDF
Nucleophilic catalysis by polyethylenimines with covalently attached 4-dialkylaminopyridine
Michael A. Hierl, Edward P. Gamson, and Irving M. Klotz
pp 6020 - 6022; DOI:
10.1021/ja00514a025
PDF
Intramolecular reactions of 1-allylic 2,2-dimethyl ethylenetricarboxylates
Barry B. Snider, David M. Roush, and Thomas A. Killinger
pp 6023 - 6027; DOI:
10.1021/ja00514a026
PDF
Reactions of ethyl, propyl, and butyl cations with methyl- and ethylsilanes
G. W. Goodloe and F. W. Lampe
pp 6028 - 6032; DOI:
10.1021/ja00514a027
PDF
Methyl-substituted allyl cations. A comparison of experimental stability, rotational barrier, and solvolysis data with ab initio calculations
Herbert Mayr, Wolfgang Foerner, and Paul von Rague Schleyer
pp 6032 - 6040; DOI:
10.1021/ja00514a028
PDF
Isopropylation of halobenzenes by sec-C3H7+ cations. Evidence for a participation of the substituent in a gas-phase alkylation
Marina Attina and Pierluigi Giacomello
pp 6040 - 6045; DOI:
10.1021/ja00514a029
PDF
Scale of acidities in the gas phase from methanol to phenol
John E. Bartmess, Judith A. Scott, and Robert T. McIver
pp 6046 - 6056; DOI:
10.1021/ja00514a030
PDF
Substituent and solvation effects on gas-phase acidities
John E. Bartmess, Judith A. Scott, and Robert T. McIver
pp 6056 - 6063; DOI:
10.1021/ja00514a031
PDF
Alkylation reactions of mitomycin C at acid pH
Maria Tomasz and Roselyn Lipman
pp 6063 - 6067; DOI:
10.1021/ja00514a032
PDF
Studies on 6-methyl-5-deazatetrahydropterin and its 4a adducts
Graeme Moad, Connie L. Luthy, Patricia A. Benkovic, and Stephen J. Benkovic
pp 6068 - 6076; DOI:
10.1021/ja00514a033
PDF
Synthesis of sesquiterpene antitumor lactones. 5. Total synthesis of vernolepin. 2. Stereocontrolled synthesis of (.+-.)-vernolepin
Hideo Iio, Minoru Isobe, Tatsuhiko Kawai, and Toshio Goto
pp 6076 - 6081; DOI:
10.1021/ja00514a034
PDF
Studies on polypeptides. 54. The synthesis of a peptide corresponding to positions 24-104 of the peptide chain of ribonuclease T1
Hana Romovacek, Susan R. Dowd, Koichi Kawasaki, Norio Nishi, and Klaus Hofmann
pp 6081 - 6091; DOI:
10.1021/ja00514a035
PDF
Proton NMR study of high-spin ferric natural porphyrin derivatives as models of methemoproteins
David L. Budd, Gerd N. La Mar, Kevin C. Langry, Kevin M. Smith, and R. Nayyir-Mazhir
pp 6091 - 6096; DOI:
10.1021/ja00514a036
PDF
Coordination chemistry of microbial iron transport compounds. 19. Stability constants and electrochemical behavior of ferric enterobactin and model complexes
Wesley R. Harris, Carl J. Carrano, Stephen R. Cooper, Stephen R. Sofen, Alex E. Avdeef, James V. McArdle, and Kenneth N. Raymond
pp 6097 - 6104; DOI:
10.1021/ja00514a037
PDF
EPR, ENDOR, CD, and MCD spectra of [63Cu]cobalamin
Kenneth A. Rubinson
pp 6105 - 6110; DOI:
10.1021/ja00514a038
PDF
Synthesis, structure, and stereochemical implication of the [Pt19(CO)12(.mu.2-CO)10]4- tetraanion: a bicapped triple-decker all-metal sandwich of idealized fivefold (D5h) geometry
Don M. Washecheck, Edward J. Wucherer, Lawrence F. Dahl, Alessandro Ceriotti, Giuliano Longoni, Mario Manassero, Mirella Sansoni, and Paolo Chini
pp 6110 - 6112; DOI:
10.1021/ja00514a039
PDF
Generation of the onocerin system by lanosterol 2,3-oxidosqualene cyclase - implications for the cyclization process
E. E. Van Tamelen and R. E. Hopla
pp 6112 - 6114; DOI:
10.1021/ja00514a040
PDF
Absolute configuration of biological tetrahydrofolates. A crystallographic determination
Juan C. Fontecilla-Camps, Charles E. Bugg, Carroll Temple, Jerry D. Rose, John A. Montgomery, and Roy L. Kisliuk
pp 6114 - 6115; DOI:
10.1021/ja00514a041
PDF
Pentacarbonyl(7-.eta.1-cycloheptatrienyl)rhenium. Synthesis and fluxional behavior of a monohaptocycloheptatrienyl derivative of a transition metal
D. Michael Heinekey and William A. G. Graham
pp 6115 - 6116; DOI:
10.1021/ja00514a042
PDF
A new, stereocontrolled synthesis of cis,anti,cis-tricyclo[6.3.0.02,6]undecanes. Total synthesis of (.+-.)-hirsutene
Kuniaki Tatsuta, Kohji Akimoto, and Mitsuhiro Kinoshita
pp 6116 - 6118; DOI:
10.1021/ja00514a043
PDF
A nuclear magnetic resonance study of the bis(2,2'-bipyridine)platinum(II) cation in basic solution
O. Farver, O. Moensted, and G. Nord
pp 6118 - 6120; DOI:
10.1021/ja00514a044
PDF
Stereoselective aldol condensations via boron enolates
D. A. Evans, E. Vogel, and J. V. Nelson
pp 6120 - 6123; DOI:
10.1021/ja00514a045
PDF
Annulated pyranosides as chiral synthons for carbocyclic systems. Enantiospecific routes to both (+)- and (-)-chrysanthemumdicarboxylic acids from a single progenitor
Brian J. Fitzsimmons and Bert Fraser-Reid
pp 6123 - 6125; DOI:
10.1021/ja00514a046
PDF
The carboranylcarbene rearrangement
Sarangan Chari, Garabed K. Agopian, and Maitland Jones
pp 6125 - 6127; DOI:
10.1021/ja00514a047
PDF
A total synthesis of pentostatin, the potent inhibitor of adenosine deaminase
David C. Baker and S. R. Putt
pp 6127 - 6128; DOI:
10.1021/ja00514a048
PDF
Asymmetric addition of hydrogen cyanide to alkenes catalyzed by a zerovalent palladium compound
Patricia S. Elmes and W. Roy Jackson
pp 6128 - 6129; DOI:
10.1021/ja00514a049
PDF
Peptides and their retro enantiomers are topologically nonidentical
Roger M. Freidinger and Daniel F. Veber
pp 6129 - 6131; DOI:
10.1021/ja00514a050
PDF
A new view of the dynamics of singlet cis-trans photoisomerization
R. M. Weiss and A. Warshel
pp 6131 - 6133; DOI:
10.1021/ja00514a051
PDF
Catalysis of hydrogen production in irradiated aqueous solutions by gold sols
D. Meisel
pp 6133 - 6135; DOI:
10.1021/ja00514a052
PDF
A convenient one-step synthesis of 2,2-disubstituted oxetanes from ketones
Steven C. Welch and A. S. C. Prakasa Rao
pp 6135 - 6136; DOI:
10.1021/ja00514a053
PDF
Marine natural products. 18. Iodinated sesquiterpenes from the red algal genus Laurencia
Richard R. Izac and James J. Sims
pp 6136 - 6137; DOI:
10.1021/ja00514a054
PDF
Evidence further substantiating the SRN1 mechanism of aromatic substitution
Carlo Galli and J. F. Bunnett
pp 6137 - 6139; DOI:
10.1021/ja00514a055
PDF
Spectral sensitization of the heterogeneous photocatalytic oxidation of hydroquinone in aqueous solutions at phthalocyanine-coated titanium dioxide powders
Fu-Ren F. Fan and Allen J. Bard
pp 6139 - 6140; DOI:
10.1021/ja00514a056
PDF
Free-energy relationships for electron-transfer processes
F. Scandola and V. Balzani
pp 6140 - 6142; DOI:
10.1021/ja00514a057
PDF
Kinetics of the thermal decomposition of a 1,1-dialkyldiazene, N-(2,2,6,6-tetramethylpiperidyl)nitrene
William D. Hinsberg and Peter B. Dervan
pp 6142 - 6144; DOI:
10.1021/ja00514a058
PDF
Generation and thiol reduction of a "quinonoid" dihydropterin and an oxidized pyrimidine analog
Robert Dietrich and Stephen J. Benkovic
pp 6144 - 6145; DOI:
10.1021/ja00514a059
PDF
Book Reviews

pp 6146 - 6150; DOI:
10.1021/ja00514a600
PDF

Issue 21


Water solvent exchange rates of primary amides. Acid-catalyzed NMR saturation transfer as an indicator of rotation and structure of the protonated form
A. G. Redfield and S. Waelder
pp 6151 - 6162; DOI:
10.1021/ja00515a001
PDF
Hyperconjugation and homohyperconjugation in the 1-adamantyl cation. Qualitative models for .gamma.-deuterium isotope effects
Dionis E. Sunko, S. Hirsl-Starcevic, Steven K. Pollack, and Warren J. Hehre
pp 6163 - 6170; DOI:
10.1021/ja00515a002
PDF
Conformational effects upon the charge-transfer transitions of the hexamethylbenzene-tetracyanoethylene crystalline complex
C. J. Eckhardt and R. J. Hood
pp 6170 - 6174; DOI:
10.1021/ja00515a003
PDF
Electronic structure of the lowest 1A1 and 3B1 states of cyclopropenylidene
Ron Shepard, Ajit Banerjee, and Jack Simons
pp 6174 - 6178; DOI:
10.1021/ja00515a004
PDF
Chemically derivatized n-type semiconducting gallium arsenide photoelectrodes. Thermodynamically uphill oxidation of surface-attached ferrocene centers
Jeffrey M. Bolts and Mark S. Wrighton
pp 6179 - 6184; DOI:
10.1021/ja00515a005
PDF
An ab initio molecular orbital study of 2- and 4-monosubstituted pyridines
Janet E. Del Bene
pp 6184 - 6189; DOI:
10.1021/ja00515a006
PDF
Intramolecular electron transfer from pentacyanoferrate(II) to pentaamminecobalt(III) mediated by various 4,4'-bipyridines
Jing-Jer Jwo, P. L. Gaus, and Albert Haim
pp 6189 - 6197; DOI:
10.1021/ja00515a007
PDF
Synthesis and properties of .pi.-bonded olefin and acetylene complexes of ruthenium(II). Crystal and molecular structure of the pentaammineruthenium(II) fumaric acid complex, [(NH3)5Ru(C4H4O4)]S2O6.2H2O
H. Lehmann, K. J. Schenk, G. Chapuis, and A. Ludi
pp 6197 - 6202; DOI:
10.1021/ja00515a008
PDF
Mechanism of ligand substitution on high-spin iron(III) by hydroxamic acid chelators. Thermodynamic and kinetic studies on the formation and dissociation of a series of monohydroxamatoiron(III) complexes
Bruce Monzyk and Alvin L. Crumbliss
pp 6203 - 6213; DOI:
10.1021/ja00515a009
PDF
Molecular transformations in the solid state. Crystallographic resolution of the spin isomers of tris(2-picolylamine)iron(II) dichloride and the structural relationship between the methanol and ethanol solvates
Bradley A. Katz and Charles E. Strouse
pp 6214 - 6221; DOI:
10.1021/ja00515a010
PDF
Formation of hydridocyclotriphosphazenes via the reactions of organocopper reagents with halocyclotriphosphazenes. Reaction mechanism
Harry R. Allcock and Paul J. Harris
pp 6221 - 6229; DOI:
10.1021/ja00515a011
PDF
Nickel-boron "hybrid" clusters. Synthesis of polyhedral nickelaboranes and nickelacarboranes from small borane and carborane anions. Crystal structure of (.eta.5-C5H5)4Ni4B4H4
James R. Bowser, Alan Bonny, J. Robert Pipal, and Russell N. Grimes
pp 6229 - 6236; DOI:
10.1021/ja00515a012
PDF
Substituent effects in cluster species. 2. Photoelectron spectra of 2- and 2,4-substituted 1,6-dicarba-closo-hexaborane(6)
G. A. Beltram and T. P. Fehlner
pp 6237 - 6244; DOI:
10.1021/ja00515a013
PDF
Strong metal-to-metal quadruple bonds in a series of five isostructural compounds as indicated by photoelectron spectroscopy
Bruce E. Bursten, F. Albert Cotton, Alan H. Cowley, Brian E. Hanson, Michael Lattman, and George G. Stanley
pp 6244 - 6249; DOI:
10.1021/ja00515a014
PDF
Bimetal vapor-polymer chemistry at close to room temperature. A new synthetic pathway to mononuclear and cluster bimetallic polymers
Colin G. Francis, Helmut Huber, and Geoffrey A. Ozin
pp 6250 - 6254; DOI:
10.1021/ja00515a015
PDF
Resolutions using metal complexes. Synthesis, separation into diastereoisomers, and resolution of o-phenylenebis(methylphenylphosphine) using palladium complexes containing optically active ortho-metalated dimethyl(.alpha.-methylbenzyl)amines
Nicholas K. Roberts and Stanley Bruce Wild
pp 6254 - 6260; DOI:
10.1021/ja00515a016
PDF
Model compounds for the interaction of silver(I) with polyuridine. Crystal structure of a 1:1 silver complex with 1-methylthymine
France Guay and Andre L. Beauchamp
pp 6260 - 6263; DOI:
10.1021/ja00515a017
PDF
Synthesis, crystal structure, and properties of the hexa(.mu.-benzenethiolato)tetra(benzenethiolatocobaltate(II)) dianion, the prototype cobalt(II)-thiolate molecular cluster
Ian G. Dance
pp 6264 - 6273; DOI:
10.1021/ja00515a018
PDF
A calorimetric titration study of the reaction of several organic ammonium cations with 18-crown-6 in methanol
R. M. Izatt, J. D. Lamb, N. E. Izatt, B. E. Rossiter, J. J. Christensen, and B. L. Haymore
pp 6273 - 6276; DOI:
10.1021/ja00515a019
PDF
Concurrent general acid and general base catalysis in the hydrolysis of an imidate ester. 3. Ethyl N-p-nitrophenylformimidate
Yin-Nan Lee and Gaston L. Schmir
pp 6277 - 6282; DOI:
10.1021/ja00515a020
PDF
Carbon-carbon bond homolysis in hexakis(trifluoromethylmercapto)ethane at room temperature. Thermodynamic, kinetic, and electron spin resonance results
A. Haas, K. Schlosser, and S. Steenken
pp 6282 - 6284; DOI:
10.1021/ja00515a021
PDF
Cyclic peroxides. 88. Reaction of 7-substituted cycloheptatrienes with singlet oxygen and 4-phenyl-1,2,4-triazoline-3,5-dione
Waldemar Adam, Metin Balci, and Barbara Pietrzak
pp 6285 - 6291; DOI:
10.1021/ja00515a022
PDF
Acyclic mechanism in the cleavage of benzils with alkaline hydrogen peroxide
Yasuhiko Sawaki and Christopher S. Foote
pp 6292 - 6296; DOI:
10.1021/ja00515a023
PDF
The penems, a new class of .beta.-lactam antibiotics. 2. Total synthesis of racemic 6-unsubstituted representatives
M. Lang, K. Prasad, W. Holick, J. Gosteli, I. Ernest, and R. B. Woodward
pp 6296 - 6301; DOI:
10.1021/ja00515a024
PDF
The penems, a new class of .beta.-lactam antibiotics. 3. Synthesis of optically active 2-methyl-(5R)-penem-3-carboxylic acid
I. Ernest, J. Gosteli, and R. B. Woodward
pp 6301 - 6305; DOI:
10.1021/ja00515a025
PDF
The penems, a new class of .beta.-lactam antibiotics. 4. Syntheses of racemic and enantiomeric penem carboxylic acids
H. R. Pfaendler, J. Gosteli, and R. B. Woodward
pp 6306 - 6310; DOI:
10.1021/ja00515a026
PDF
Three-electron oxidations. 16. Chromic acid oxidation of mandelic acid
Dominic Ip and Jan Rocek
pp 6311 - 6319; DOI:
10.1021/ja00515a027
PDF
Mechanism of oxidative addition. Reaction of nickel(0) complexes with aromatic halides
T. T. Tsou and J. K. Kochi
pp 6319 - 6332; DOI:
10.1021/ja00515a028
PDF
Photochemical oxidation and rearrangement of dibenzobarrelene and dehydrojanusene
Paul D. Bartlett, Michio Kimura, Jyuzo Nakayama, and William H. Watson
pp 6332 - 6337; DOI:
10.1021/ja00515a029
PDF
Photochemical electron transfer in monolayer assemblies. 1. Spectroscopic study of radicals produced in chlorophyll a/acceptor systems
A. Frederick Janzen, James R. Bolton, and Martin J. Stillman
pp 6337 - 6341; DOI:
10.1021/ja00515a030
PDF
Photochemical electron transfer in monolayer assemblies. 2. Photoelectric behavior in chlorophyll a/acceptor systems
A. Frederick Janzen and James R. Bolton
pp 6342 - 6348; DOI:
10.1021/ja00515a031
PDF
Triplet state photophysical properties and intersystem crossing quantum efficiencies of homologs of retinals in various solvents
Paritosh K. Das and Ralph S. Becker
pp 6348 - 6353; DOI:
10.1021/ja00515a032
PDF
Reactions of ketones and related compounds with solid supported phosphoric acid catalyst. 5. Mechanisms of acid-catalyzed aliphatic ketone rearrangements and relationships between ketone structure and oxygen function rearrangement.
Arthur Fry and Mitsuo Oka
pp 6353 - 6363; DOI:
10.1021/ja00515a033
PDF
Photodissociation spectroscopy of alkane radical cations
Robert C. Benz and Robert C. Dunbar
pp 6363 - 6366; DOI:
10.1021/ja00515a034
PDF
Unusual organic photochemistry effected by cyano and methoxy substitution. Exploratory and mechanistic organic photochemistry
Howard E. Zimmerman, Diego Armesto, Mercedes G. Amezua, Thomas P. Gannett, and Richard P. Johnson
pp 6367 - 6383; DOI:
10.1021/ja00515a035
PDF
Photochemistry of cis-1-phenylcyclohexene. Proof of involvement of trans isomer in reaction processes
W. G. Dauben, H. C. H. A. Van Riel, J. D. Robbins, and G. J. Wagner
pp 6383 - 6389; DOI:
10.1021/ja00515a036
PDF
Organic photochemistry with 6.7-eV photons: irradiation of molecular oxygen in hydrocarbon solution
R. Srinivasan and Lloyd S. White
pp 6389 - 6392; DOI:
10.1021/ja00515a037
PDF
Photochemical decomposition of trimethylsilyl diazoacetates in alcohols
Wataru Ando, Akira Sekiguchi, Tsuneo Hagiwara, Toshihiko Migita, Vinay Chowdhry, F. H. Westheimer, Seetha L. Kammula, Marilyn Green, and Maitland Jones
pp 6393 - 6398; DOI:
10.1021/ja00515a038
PDF
A method for effecting the equivalent of a de Mayo reaction with formyl acetic ester
Bruce A. Pearlman
pp 6398 - 6404; DOI:
10.1021/ja00515a039
PDF
A total synthesis of reserpine
Bruce A. Pearlman
pp 6404 - 6408; DOI:
10.1021/ja00515a040
PDF
Studies on transfer ribonucleic acids and related compounds. 29. Synthesis of a decaribonucleotide of Escherichia coli tRNAfMet (bases 11-20) using a new phosphorylating reagent
Eiko Ohtsuka, Toshiki Tanaka, and Morio Ikehara
pp 6409 - 6414; DOI:
10.1021/ja00515a041
PDF
Synthesis of the nontryptamine moiety of the Aspidosperma-type indole alkaloids via cleavage of a cyclic .alpha.-diketone monothioketal. An efficient synthesis of (.+-.)-quebrachamine and a formal synthesis of (.+-.)-tabersonine
Seiichi Takano, Susumi Hatakeyama, and Kunio Ogasawara
pp 6414 - 6420; DOI:
10.1021/ja00515a042
PDF
Lactone annulation of .beta.-keto esters with .beta.-vinylbutenolide and the total synthesis of racemic frullanolide
Fusao Kido, Kentaro Tsutsumi, Riichiro Maruta, and Akira Yoshikoshi
pp 6420 - 6424; DOI:
10.1021/ja00515a043
PDF
Chemical synthesis of a proposed enzyme-generated "reactive intermediate analog" derived from thiamin diphosphate. Self-activation of pyruvate dehydrogenase by conversion of the analog to its components
Ronald Kluger and David C. Pike
pp 6425 - 6428; DOI:
10.1021/ja00515a044
PDF
Studies in nuclear magnetic resonance spectroscopy. 16. Nonsymmetry of the hydrogen bond in 1-phenylamino-7-phenylimino-1,3,5-cycloheptatriene
L. M. Jackman and J. C. Trewella
pp 6428 - 6429; DOI:
10.1021/ja00515a045
PDF
New conjunctive reagents. 2-Acetoxymethyl-3-allyltrimethylsilane for methylenecyclopentane annulations catalyzed by palladium(0)
Barry M. Trost and Dominic M. T. Chan
pp 6429 - 6432; DOI:
10.1021/ja00515a046
PDF
2-Acetoxymethyl-3-allyltrimethylsilane and palladium(0): a source of trimethylenemethane-palladium complex?
Barry M. Trost and Dominic M. T. Chan
pp 6432 - 6433; DOI:
10.1021/ja00515a047
PDF
Reactions of benzaldehyde with trialkylsilyl metal carbonyl complexes
Dennis Lee Johnson and J. A. Gladysz
pp 6433 - 6435; DOI:
10.1021/ja00515a048
PDF
Enhancement of decomposition quantum yields of reluctant azoalkanes
Paul S. Engel, Christopher J. Nalepa, Roy A. Leckonby, and Woo-Ki Chae
pp 6435 - 6437; DOI:
10.1021/ja00515a049
PDF
One-electron oxidation of vinylidene-carbene complexes of iron porphyrins. Isolation of complexes spectrally analogous to catalase and horseradish peroxidase compounds I
D. Mansuy, M. Lange, and J. C. Chottard
pp 6437 - 6439; DOI:
10.1021/ja00515a050
PDF
Solid catalyst treated with anion. 2. Reactions of butane and isobutane catalyzed by zirconium oxide treated with sulfate ion. Solid superacid catalyst
Makoto Hino, Sakari Kobayashi, and Kazushi Arata
pp 6439 - 6441; DOI:
10.1021/ja00515a051
PDF
Use of tetraphenylborate as a phase transfer agent for acid catalysis
Stephen Snipes and Arthur W. Herriott
pp 6441 - 6441; DOI:
10.1021/ja00515a052
PDF
Elucidation of chemical exchange networks by two-dimensional NMR spectroscopy: the heptamethylbenzenonium ion
B. H. Meier and R. R. Ernst
pp 6441 - 6442; DOI:
10.1021/ja00515a053
PDF
Generation of specific isomeric carbanions in the gas phase
C. H. DePuy, Veronica M. Bierbaum, L. A. Flippin, Joseph J. Grabowski, Gary K. King, and Robert J. Schmitt
pp 6443 - 6443; DOI:
10.1021/ja00515a054
PDF
Gas-phase reactions of carbanions with triplet and singlet molecular oxygen
Robert J. Schmitt, Veronica M. Bierbaum, and C. H. DePuy
pp 6443 - 6445; DOI:
10.1021/ja00515a055
PDF
Photoreaction of valence-bond isomers of hexakis(trifluoromethyl)oxepin. Synthesis of a stable oxetene derivative
Yoshiro Kobayashi, Yuji Hanzawa, Wakako Miyashita, Takashi Kashiwagi, Takaharu Nakano, and Itsumaro Kumadaki
pp 6445 - 6446; DOI:
10.1021/ja00515a056
PDF
Helium (He I) photoelectron spectrum of benzocyclobutadiene
T. Koenig, Daniel Imre, and James A. Hoobler
pp 6446 - 6447; DOI:
10.1021/ja00515a057
PDF
Intramolecular rearrangement of carbonyl ligands in the octahedral complex pentacarbonyl(trimethyl phosphite) tungsten by a nondissociative process: an example of the utility of the oxygen-18 isotope shift on the carbon-13 NMR of the carbonyl ligand
Donald J. Darensbourg and Brenda J. Baldwin
pp 6447 - 6449; DOI:
10.1021/ja00515a058
PDF
Properties and reactions of manganese methylene complexes in the gas phase. The importance of strong metal-carbene bonds for effective olefin metathesis catalysts
Amy E. Stevens and J. L. Beauchamp
pp 6449 - 6450; DOI:
10.1021/ja00515a059
PDF
Dihydrogen reduction of isocyanides promoted by permethylzirconocene dihydride. A modeling study of carbon monoxide reduction
Peter T. Wolczanski and John E. Bercaw
pp 6450 - 6452; DOI:
10.1021/ja00515a060
PDF
Methylides from trimethylsilylmethylsulfonium, -ammonium, -immonium, and -phosphonium salts
E. Vedejs and G. R. Martinez
pp 6452 - 6454; DOI:
10.1021/ja00515a061
PDF
Reversible loss of metal ions from the zinc binding site of copper-zinc superoxide dismutase. The low pH transition
Michael W. Pantoliano, Peter J. McDonnell, and Joan S. Valentine
pp 6454 - 6456; DOI:
10.1021/ja00515a062
PDF
P-450 type oxygen activation by porphyrin-manganese complex
Iwao Tabushi and Noboru Koga
pp 6456 - 6458; DOI:
10.1021/ja00515a063
PDF
Arylcyclopropane photochemistry. Electron-transfer-mediated photochemical addition of methanol to arylcyclopropanes
V. Ramachandra Rao and Stephen S. Hixson
pp 6458 - 6459; DOI:
10.1021/ja00515a064
PDF
Hydridic reactivity of hydropentacarbonylmanganese stabilization of a nearly coordinatively unsaturated metal carbonyl cation in trifluoromethanesulfonic acid
William C. Trogler
pp 6459 - 6460; DOI:
10.1021/ja00515a065
PDF
Energy deposition in polyatomic ions upon high energy collision by angle-resolved mass spectrometry
J. A. Laramee, P. H. Hemberger, and R. G. Cooks
pp 6460 - 6462; DOI:
10.1021/ja00515a066
PDF
X-ray crystallographic results on tantallacyclopentane complexes derived from ethylene and 1,6-heptadiene: Ta(.eta.5-C5Me5)(C4H8)Cl2 and Ta(.eta.5-C5Me5)(C7H12)Cl2
Melvyn Rowen Churchill and Wiley J. Youngs
pp 6462 - 6463; DOI:
10.1021/ja00515a067
PDF
Onium ions. 21. Cyclopropylhalonium ions
George A. Olah, G. K. Surya Prakash, and Mark R. Bruce
pp 6463 - 6465; DOI:
10.1021/ja00515a068
PDF
Chemistry of exciplexes. 8. The role of conservation of orbital symmetry in cycloadditions of olefins to aromatic hydrocarbons
Nien-chu C. Yang, John Masnovi, and Wei-long Chiang
pp 6465 - 6466; DOI:
10.1021/ja00515a069
PDF
Facile hydroxymethylation of an acyloxymethyl ligand with synthesis gas or hydrogen. A model for catalytic reactions yielding methanol and ethylene glycol
B. Duane Dombek
pp 6466 - 6468; DOI:
10.1021/ja00515a070
PDF
Reactions of vinylcyclopropane induced by multiphoton absorption of infrared radiation
William E. Farneth, Marcus W. Thomsen, and Mark A. Berg
pp 6468 - 6470; DOI:
10.1021/ja00515a071
PDF
Fast radical reactions in a mass spectrometer ion source: radical addition to 7,7,8,8-tetracyanoquinodimethane
C. N. McEwen and M. A. Rudat
pp 6470 - 6472; DOI:
10.1021/ja00515a072
PDF
Dioxygen complexes of rhodium porphyrins
Bradford B. Wayland and Alan R. Newman
pp 6472 - 6473; DOI:
10.1021/ja00515a073
PDF
Cyclopropanation of olefins with a stable, iron-containing methylene transfer reagent
Steven Brandt and Paul Helquist
pp 6473 - 6475; DOI:
10.1021/ja00515a074
PDF
[1:2,9:10]Bismethano[2.2]paracyclophane
E. A. Truesdale and R. S. Hutton
pp 6475 - 6476; DOI:
10.1021/ja00515a075
PDF
Book Reviews

pp 6477 - 6480; DOI:
10.1021/ja00515a600
PDF

Issue 22


Conformational characteristics of poly(methyl vinyl ketone)s and of simple model ketones
Ulrich W. Suter
pp 6481 - 6496; DOI:
10.1021/ja00516a001
PDF
Flat-band potential of n-type semiconducting molybdenum disulfide by cyclic voltammetry of two-electron reductants: interface energetics and the sustained photooxidation of chloride
Lynn F. Schneemeyer and Mark S. Wrighton
pp 6496 - 6500; DOI:
10.1021/ja00516a002
PDF
Derivatization of surfaces via reaction of strained silicon-carbon bonds. Characterization by photoacoustic spectroscopy
Alan B. Fischer, John B. Kinney, Ralph H. Staley, and Mark S. Wrighton
pp 6501 - 6506; DOI:
10.1021/ja00516a003
PDF
Photodissociation spectroscopy of halogen-substituted benzene ions
Robert C. Dunbar, Harry Ho I. Teng, and Emil W. Fu
pp 6506 - 6510; DOI:
10.1021/ja00516a004
PDF
Cyclic peroxides. 81. Fluorescer-enhanced chemiluminescence of .alpha.-peroxylactones via electron exchange
Waldemar Adam and Omar Cueto
pp 6511 - 6515; DOI:
10.1021/ja00516a005
PDF
Proton affinity, ionization energy, and the nature of frontier orbital electron density
Roger L. DeKock and Michael R. Barbachyn
pp 6516 - 6519; DOI:
10.1021/ja00516a006
PDF
Proton affinities and preferred protonation sites in 3- and 4-substituted pyridines. Prediction from 1s orbital energies
J. Catalan, O. Mo, P. Perez, and M. Yanez
pp 6520 - 6524; DOI:
10.1021/ja00516a007
PDF
Vertical excitation energy to the lowest 1.pi..pi.* state of acrolein
Ernest R. Davidson and Larry E. Nitzsche
pp 6524 - 6526; DOI:
10.1021/ja00516a008
PDF
Collisional activation and metastable ion characteristics. 65. Collisional activation and theoretical studies of gaseous CSH3+ ions
James D. Dill and Fred W. McLafferty
pp 6526 - 6531; DOI:
10.1021/ja00516a009
PDF
Collisional activation and theoretical studies of gaseous COH3+ ions
James D. Dill, Carmel L. Fischer, and Fred W. McLafferty
pp 6531 - 6534; DOI:
10.1021/ja00516a010
PDF
Ferric ion sequestering agents. 3. The spectrophotometric and potentiometric evaluation of two new enterobactin analogs: 1,5,9-N,N',N''-tris(2,3-dihydroxybenzoyl)cyclotriazatridecane and 1,3,5-N,N',N''-tris(2,3-dihydroxybenzoyl)triaminomethylbenzene
Wesley H. Harris and Kenneth N. Raymond
pp 6534 - 6541; DOI:
10.1021/ja00516a011
PDF
Organometallic chemistry of carbon-nitrogen multiple bonds. 2. Reactions of cyclopentadienyldicarbonyliron anion with iminium salts; chemistry of the products
E. Kent Barefield and D. J. Sepelak
pp 6542 - 6549; DOI:
10.1021/ja00516a012
PDF
The (metal-metal)-nonbonding[Fe2(CO)6(.mu.2-PPh2)2]2- dianion. Synthesis, structural analysis of its unusual dimeric geometry, and stereochemical-bonding implications
Robert E. Ginsburg, Richard K. Rothrock, Richard G. Finke, James P. Collman, and Lawrence F. Dahl
pp 6550 - 6562; DOI:
10.1021/ja00516a013
PDF
Demonstration of the generality of the [Fe4S4(SR)4]2- (compressed D2d)/[Fe4S4(SR)4]3- (elongated D2d) structural change in electron-transfer reactions of ferredoxin 4-Fe site analogs. A model for unconstrained structural changes in ferredoxin proteins
Edward J. Laskowski, John G. Reynolds, Richard B. Frankel, S. Foner, G. C. Papaefthymiou, and R. H. Holm
pp 6562 - 6570; DOI:
10.1021/ja00516a014
PDF
Excited-state acid-base reactions of dicyanobis(2,2'-bipyridine)ruthenium(II) and dicyanobis(1,10-phenanthroline)ruthenium(II)
Steven H. Peterson and J. N. Demas
pp 6571 - 6577; DOI:
10.1021/ja00516a015
PDF
Preparation and reactivity of some .eta.2-S2 and .eta.2-Se2 complexes of osmium and the x-ray crystal structure of Os(.eta.2-Se2)(CO)2(PPh3)2
D. H. Farrar, K. R. Grundy, N. C. Payne, W. R. Roper, and A. Walker
pp 6577 - 6582; DOI:
10.1021/ja00516a016
PDF
A novel class of thioketone complexes. Crystal structure of bis(.eta.5-cyclopentadienyl)(thiocamphor)tetracarbonyldimolybdenum
Howard Alper, Ned D. Silavwe, George I. Birnbaum, and Farid R. Ahmed
pp 6582 - 6588; DOI:
10.1021/ja00516a017
PDF
Dimolybdenum tetraacetate and the octachlorodimolybdate(II) anion as reagents for preparing mononuclear molybdenum(II) complexes. Geometry of the hepta(methylisocyano)molybdenum(II) cation
Patrick Brant, F. Albert Cotton, Janine C. Sekutowski, Thomas E. Wood, and Richard A. Walton
pp 6588 - 6593; DOI:
10.1021/ja00516a018
PDF
Group IB organometallic chemistry. 30. Stereochemistry of arylmetal-1B, aryllithium, and arylmetal-1B-lithium clusters Ar4M2Li2(M = copper, silver, or gold). Detection of rotation of three-center two-electron bonded aryl groups around the C(1)-C(4) axis
Gerard Van Koten and Jan G. Noltes
pp 6593 - 6599; DOI:
10.1021/ja00516a019
PDF
Mechanism of base-catalyzed methane formation from methyl(aquo)cobaloxime
Kenneth L. Brown
pp 6600 - 6606; DOI:
10.1021/ja00516a020
PDF
Synthesis, catalytic activity, and behavior of phase-transfer catalysts supported on silica gel. Strong influence of substrate adsorption on the polar polymeric matrix on the efficiency of the immobilized phosphonium salts
Pietro Tundo and Paolo Venturello
pp 6606 - 6613; DOI:
10.1021/ja00516a021
PDF
Platinum(II) dimethyl complexes of chelating polyphosphine ligands. A phosphorus-31 NMR investigation of their dynamic behavior
Kwoliang D. Tau, Richard Uriarte, Terry J. Mazanec, and Devon W. Meek
pp 6614 - 6619; DOI:
10.1021/ja00516a022
PDF
Photochemical reactivity in organized assemblies. 15. Photoreactions of metalloporphyrins in supported monolayer assemblies and at assembly-solution interfaces. Reductive addition of palladium complexes with surfactant and water-soluble dialkylanilines
Janet A. Mercer-Smith and David G. Whitten
pp 6620 - 6625; DOI:
10.1021/ja00516a023
PDF
Mechanism of hydrogen transfer from metal hydrides
R. J. Klingler, K. Mochida, and J. K. Kochi
pp 6626 - 6637; DOI:
10.1021/ja00516a024
PDF
Selenium stabilized carbanions. Preparation of .alpha.-lithio selenides and applications to the synthesis of olefins by reductive elimination of .beta.-hydroxy selenides and selenoxide syn elimination
Hans J. Reich, Flora Chow, and Shrenik K. Shah
pp 6638 - 6648; DOI:
10.1021/ja00516a025
PDF
Selenium stabilized carbanions. .alpha.-Lithio selenoxides as reagents for the synthesis of olefins, allyl alcohols, and dienes
Hans J. Reich, Shrenik K. Shah, and Flora Chow
pp 6648 - 6656; DOI:
10.1021/ja00516a026
PDF
Molecular beam method for preparing stable solutions of carbonium ions
Martin Saunders, Daniel Cox, and John R. Lloyd
pp 6656 - 6658; DOI:
10.1021/ja00516a027
PDF
1,4,5,8-Tetramethylnaphthalene dication and related radical cations
Koop Lammertsma, George A. Olah, Carl M. Berke, and Andrew Streitwieser
pp 6658 - 6659; DOI:
10.1021/ja00516a028
PDF
Preparation and Diels-Alder reactions of the [n](1,4)naphthalenophanes. Isolation of a paddlane derivative containing the tricyclo[14.2.2.21,6]docosane ring system
Kenneth B. Wiberg and Martin J. O'Donnell
pp 6660 - 6666; DOI:
10.1021/ja00516a029
PDF
Stereochemistry of electrophilic attack on the putative carbanion intermediate in the base-catalyzed ketonization of 3,7-dimethyltricyclo[3.3.0.03,7]octan-1-ol. Evidence against an SE1 mechanism for ketonization
Anne Bird Crow and Weston Thatcher Borden
pp 6666 - 6670; DOI:
10.1021/ja00516a030
PDF
Fragmentation reaction of ylide. 7. Reaction of oxaziridines with nucleophilic reagents
Yoshiteru Hata and Masamichi Watanabe
pp 6671 - 6676; DOI:
10.1021/ja00516a031
PDF
Synthesis and study of N-substituted 1,2-dihydropyridines
Paul Beeken, John N. Bonfiglio, Iltifat Hasan, John J. Piwinski, Barry Weinstein, Kenneth A. Zollo, and Frank W. Fowler
pp 6677 - 6682; DOI:
10.1021/ja00516a032
PDF
Chemistry of singlet oxygen. 31. Low-temperature nuclear magnetic resonance studies of dye-sensitized photooxygenation of imidazoles: direct observation of unstable 2,5-endoperoxide intermediates
Hong-Son Ryang and Christopher S. Foote
pp 6683 - 6687; DOI:
10.1021/ja00516a033
PDF
Interdependence of solvolysis rate and aryl-aryl dihedral angle in a series of 4-biphenylyldimethylcarbinyl p-nitrobenzoates
Katsuo Ohkata, Ronald L. Paquette, and Leo A. Paquette
pp 6687 - 6693; DOI:
10.1021/ja00516a034
PDF
Variable transition state structure in 3,3-sigmatropic shifts from .alpha.-secondary deuterium isotope effects
Joseph J. Gajewski and Neal D. Conrad
pp 6693 - 6704; DOI:
10.1021/ja00516a035
PDF
Deuterium isotope exchange between molecular hydrogen and cyclohexylamine
E. Allan Symons, Michael F. Powell, Joseph B. Schnittker, and Michel J. Clermont
pp 6704 - 6709; DOI:
10.1021/ja00516a036
PDF
A novel total synthesis of (2R,4'R,8'R)-.alpha.-tocopherol (vitamin E). Construction of chiral chromans from an optically active, nonaromatic precursor
Noal Cohen, Rocco J. Lopresti, and Gabriel Saucy
pp 6710 - 6716; DOI:
10.1021/ja00516a037
PDF
Syntheses and NMR characterization of chelated heme models of hemoproteins
T. G. Traylor, C. K. Chang, J. Geibel, A. Berzinis, T. Mincey, and J. Cannon
pp 6716 - 6731; DOI:
10.1021/ja00516a038
PDF
Enzyme catalysis in water pools
F. M. Menger and K. Yamada
pp 6731 - 6734; DOI:
10.1021/ja00516a039
PDF
Rate of exchange of water from the active site of human carbonic anhydrase C
D. N. Silverman, C. K. Tu, S. Lindskog, and G. C. Wynns
pp 6734 - 6740; DOI:
10.1021/ja00516a040
PDF
Structure of cuauchichicine. Its chemical correlation with (-)-".beta."-dihydrokaurene
S. William Pelletier, Haridutt K. Desai, Janet Finer-Moore, and Naresh V. Mody
pp 6741 - 6742; DOI:
10.1021/ja00516a041
PDF
Asymmetric synthesis of allo-heteroyohimbine alkaloids
Milan R. Uskokovic, Ronald L. Lewis, John J. Partridge, Carl W. Despreaux, and David L. Pruess
pp 6742 - 6744; DOI:
10.1021/ja00516a042
PDF
Reduction of water to hydrogen by reduced polypyridine complexes of ruthenium
Hector D. Abruna, Annette Y. Teng, George J. Samuels, and Thomas J. Meyer
pp 6745 - 6746; DOI:
10.1021/ja00516a043
PDF
Design of reaction systems exhibiting overshoot-undershoot kinetics
G. Rabai, G. Bazsa, and M. T. Beck
pp 6746 - 6748; DOI:
10.1021/ja00516a044
PDF
Total synthesis of (.+-.)-5,6-oxido-7,9-trans,11,14-cis-eicosapentaenoic acid, a possible precursor of SRSA
E. J. Corey, Yoshinobu Arai, and Charles Mioskowski
pp 6748 - 6749; DOI:
10.1021/ja00516a045
PDF
Contribution of tunneling to relative reactivity in an elimination reaction
David J. Miller and William H. Saunders
pp 6749 - 6750; DOI:
10.1021/ja00516a046
PDF
Silicon-29 NMR studies of relatively stable silaethylenes
Adrian G. Brook, Stanley C. Nyburg, William F. Reynolds, Yiu C. Poon, Yau-Min Chang, Jung-Si Lee, and Jean-Paul Picard
pp 6750 - 6752; DOI:
10.1021/ja00516a047
PDF
Spherands - ligands whose binding of cations relieves enforced electron-electron repulsions
Donald J. Cram, Takahiro Kaneda, Roger C. Helgeson, and George M. Lein
pp 6752 - 6754; DOI:
10.1021/ja00516a048
PDF
An unusually long cobalt-carbon bond. Molecular structure of trans-bis(dimethylglyoximato)(isopropyl)(pyridine)cobalt(III). Implications with regard to the conformational trigger mechanism of cobalt-carbon bond cleavage in coenzyme B12
Luigi G. Marzilli, Paul J. Toscano, Lucio Randaccio, Nevenka Bresciani-Pahor, and Mario Calligaris
pp 6754 - 6756; DOI:
10.1021/ja00516a049
PDF
A stereocontrolled approach to acyclic systems. Stereorelay in charge-directed alkylations via organopalladium templates
Barry M. Trost and Thomas P. Klun
pp 6756 - 6758; DOI:
10.1021/ja00516a050
PDF
Chemistry of singlet oxygen. 32. Unusual products from low-temperature photooxygenation of indenes and trans-stilbene
Jack D. Boyd and Christopher S. Foote
pp 6758 - 6759; DOI:
10.1021/ja00516a051
PDF
Spectroscopic studies on small aggregates of amphipathic molecules in aqueous solution
Samir S. Atik and Lawrence A. Singer
pp 6759 - 6761; DOI:
10.1021/ja00516a052
PDF
Farnesyl pyrophosphate synthetase. Mechanistic studies of the 1'-4 coupling reaction in the terpene biosynthetic pathway
C. Dale Poulter, Eugene A. Mash, J. Craig Argyle, Oliver J. Muscio, and Hans C. Rilling
pp 6761 - 6763; DOI:
10.1021/ja00516a053
PDF
Thermal interconversion of naphthobarrelene- and naphthosemibullvalene-like compounds. Ground-state counterpart of a di-.pi.-methane photorearrangement
Martin Demuth, Ulrich Burger, Hans W. Mueller, and Kurt Schaffner
pp 6763 - 6765; DOI:
10.1021/ja00516a054
PDF
Stereoselective synthesis of (.+-.)-gymnomitrol
Robert M. Coates, Shrenik K. Shah, and Robert W. Mason
pp 6765 - 6767; DOI:
10.1021/ja00516a055
PDF
Synthesis of gymnomitrol
George Buchi and Ping-Sun Chu
pp 6767 - 6768; DOI:
10.1021/ja00516a056
PDF
A stereoselective total synthesis of (.+-.)-gymnomitrol
Steven C. Welch and Suthep Chayabunjonglerd
pp 6768 - 6769; DOI:
10.1021/ja00516a057
PDF
Photoactivation of cobalt carbonyl catalysts: generation of reactive mononuclear fragments from dinuclear, metal-metal bonded complexes
Carol L. Reichel and Mark S. Wrighton
pp 6769 - 6772; DOI:
10.1021/ja00516a058
PDF
.alpha.-Hydroxynitrosamines: transportable metabolites of dialkylnitrosamines
Barry Gold and Wendy B. Linder
pp 6772 - 6773; DOI:
10.1021/ja00516a059
PDF
.mu.-(.eta.6:.eta.6-Biphenyl)-bis[(.eta.6-benzene)chromium] and bis[.mu.-(.eta.6:.eta.6-biphenyl)]-dichromium. Novel species to explore mixed-valence sandwich complex chemistry
C. Elschenbroich and J. Heck
pp 6773 - 6776; DOI:
10.1021/ja00516a060
PDF
Homonuclear and heteronuclear coupling in 5'-AMP as probed by two-dimensional proton nuclear magnetic resonance spectroscopy
Jeremy R. Everett, Donald W. Hughes, Alex D. Bain, and Russell A. Bell
pp 6776 - 6777; DOI:
10.1021/ja00516a061
PDF
An investigation of the fluidity of alkyl benzenesulfonate aqueous micelles by fluorescence spectroscopy
M. Aoudia and M. A. J. Rodgers
pp 6777 - 6779; DOI:
10.1021/ja00516a062
PDF
Dual wavelength fluorescence from acenaphthylene and derivatives in fluid media
Benjamin F. Plummer, M. J. Hopkinson, and J. H. Zoeller
pp 6779 - 6781; DOI:
10.1021/ja00516a063
PDF
Selected fragment scans of mass spectrometers in direct mixture analysis
D. Zakett, A. E. Schoen, R. W. Kondrat, and R. G. Cooks
pp 6781 - 6783; DOI:
10.1021/ja00516a064
PDF
Para-directed aromatic reactions over shape-selective molecular sieve zeolite catalysts
N. Y. Chen, W. W. Kaeding, and F. G. Dwyer
pp 6783 - 6784; DOI:
10.1021/ja00516a065
PDF
Intriguing aspects of 1,2-dialkyldimolybdenum and -ditungsten (M.tplbond.M) chemistry
Malcolm H. Chisholm and Deborah A. Haitko
pp 6784 - 6786; DOI:
10.1021/ja00516a066
PDF
Stereospecific total synthesis of dl-austamide
Alan J. Hutchison and Yoshito Kishi
pp 6786 - 6788; DOI:
10.1021/ja00516a067
PDF
A novel synthesis of 7-fluorobenzo[a]pyrene involving two new molecular rearrangements
Melvin S. Newman, V. K. Khanna, and K. Kanakarajan
pp 6788 - 6789; DOI:
10.1021/ja00516a068
PDF
Polyether antibiotics synthesis. Total synthesis and absolute configuration of the ionophore A-23187
D. A. Evans, C. E. Sacks, W. A. Kleschick, and T. R. Taber
pp 6789 - 6791; DOI:
10.1021/ja00516a069
PDF
Preparation and properties of a chlorophyllide-apomyoglobin complex
Steven G. Boxer and Karen A. Wright
pp 6791 - 6794; DOI:
10.1021/ja00516a070
PDF
Book Reviews

pp 6794 - 6796; DOI:
10.1021/ja00516a600
PDF

Issue 23


Barriers to thermally allowed reactions and the elusiveness of neutral homoaromaticity
K. N. Houk, Ruth Wells Gandour, Robert W. Strozier, Nelson G. Rondan, and Leo A. Paquette
pp 6797 - 6802; DOI:
10.1021/ja00517a001
PDF
Calculations of rotatory strengths in chiral chromophores. Sensitivity to structural parameters in dienes
Elliot Charney, Che-Hung Lee, and Joan S. Rosenfield
pp 6802 - 6804; DOI:
10.1021/ja00517a002
PDF
A quadrant rule for the prediction of chiroptical effects of optically active homoannular cisoid dienes
Robert M. Moriarty, Herbert E. Paaren, U. Weiss, and W. Basil Whalley
pp 6804 - 6810; DOI:
10.1021/ja00517a003
PDF
Tunneling corrections to unimolecular rate constants, with application to formaldehyde
William H. Miller
pp 6810 - 6814; DOI:
10.1021/ja00517a004
PDF
Substituent effects on strain energies
James D. Dill, Arthur Greenberg, and Joel F. Liebman
pp 6814 - 6826; DOI:
10.1021/ja00517a005
PDF
Circular dichroism of charge transfer and magnetic dipole forbidden d-d transitions. Application to chiral chelate complexes
Pieter E. Schipper
pp 6826 - 6829; DOI:
10.1021/ja00517a006
PDF
Vibrational circular dichroism in amino acids and peptides. 3. Solution- and solid-phase spectra of alanine and serine
Max Diem, Euphemia Photos, Hani Khouri, and Laurence A. Nafie
pp 6829 - 6837; DOI:
10.1021/ja00517a007
PDF
Contribution of minor species to paramagnetic line broadening of proton nuclear magnetic resonance spectra in peptide-copper(II) system
Yoshihiro Kuroda and Hiroji Aiba
pp 6837 - 6842; DOI:
10.1021/ja00517a008
PDF
Computer simulation of the conformational properties of oligopeptides. Comparison of theoretical methods and analysis of experimental results
A. T. Hagler, P. S. Stern, R. Sharon, J. M. Becker, and F. Naider
pp 6842 - 6852; DOI:
10.1021/ja00517a009
PDF
A theoretical study of the disproportionation reactions of diimide (N2H2) species
Daniel J. Pasto
pp 6852 - 6857; DOI:
10.1021/ja00517a010
PDF
Question of the relationship of nitrogen-15 chemical shifts to barriers to carbon-nitrogen internal rotation. Dynamic nuclear magnetic resonance of urea and aniline derivatives
Frank A. L. Anet and Mehran Ghiaci
pp 6857 - 6860; DOI:
10.1021/ja00517a011
PDF
Carbon-13 magnetic relaxation in micellar solutions. Influence of aggregate motion on T1
Haakan Wennerstroem, Bjoern Lindman, Olle Soederman, Torbjoern Drakenberg, and Jarl B. Rosenholm
pp 6860 - 6864; DOI:
10.1021/ja00517a012
PDF
CIDNP-assisted assignment of carbon-13 NMR lines. Alkyl phenyl ketones
H. Michael Maurer and Joachim Bargon
pp 6865 - 6868; DOI:
10.1021/ja00517a013
PDF
Electronic structures of ion radicals of nitrogen-heteroaromatic hydrocarbons as studied by ESR and optical spectroscopy
Tatsuhisa Kato and Tadamasa Shida
pp 6869 - 6876; DOI:
10.1021/ja00517a014
PDF
Model studies of the electronic structure of solid-state beryllium borohydride
Dennis S. Marynick
pp 6876 - 6880; DOI:
10.1021/ja00517a015
PDF
X-ray photoemission study of platinum carbonyl dianions [Pt3(CO)6]n2-(n = 2,3,4,5,6, .apprx. 10)
G. Apai, S. T. Lee, M. G. Mason, L. J. Gerenser, and S. A. Gardner
pp 6880 - 6883; DOI:
10.1021/ja00517a016
PDF
Mechanistic photochemistry of transition metal .beta.-diketonate complexes. The case of trans-tris(1,1,1-trifluoro-2,4-pentanedionato)rhodium(III)
Charles Kutal, Paul A. Grutsch, and Guillermo Ferraudi
pp 6884 - 6890; DOI:
10.1021/ja00517a017
PDF
Intercalation of catalytically active metal complexes in mica-type silicates. Rhodium hydrogenation catalysts
Thomas J. Pinnavaia, Rasik Raythatha, John Guo-Shuh Lee, Leon J. Halloran, and James F. Hoffman
pp 6891 - 6897; DOI:
10.1021/ja00517a018
PDF
Preparation of arsinocobaloximes and the crystal structure of [(CH3)(C6H5)As(O)CoIII(dmgH)(dmg)]2CoII
William R. Cullen, David Dolphin, Frederick W. B. Einstein, Lynn M. Mihichuk, and Anthony C. Willis
pp 6898 - 6904; DOI:
10.1021/ja00517a019
PDF
Protonation of iron diene tris(phosphite) complexes
S. D. Ittel, F. A. Van-Catledge, and J. P. Jesson
pp 6905 - 6911; DOI:
10.1021/ja00517a020
PDF
Kinetic studies on reactions of iron-sulfur proteins. 2. An extension of the range of oxidants in the reaction of reduced parsley 2-Fe ferredoxin and identification of specific binding sites using redox inactive Cr(NH3)63+ (and Cr(en)33+)
Fraser A. Armstrong, Richard A. Henderson, and A. Geoffrey Sykes
pp 6912 - 6917; DOI:
10.1021/ja00517a021
PDF
Unusual structural and reactivity types for copper(I). Synthesis and structural and redox properties of binuclear copper(I) complexes which are probably three coordinate in solution and experience intermolecular metal-metal interactions in the solid state
Robert R. Gagne, Robert P. Kreh, and John A. Dodge
pp 6917 - 6927; DOI:
10.1021/ja00517a022
PDF
Metalation of bis(cyclopentadienyl)metal hydrides by n-butyllithium in the presense of pentamethyldiethylenetriamine. Synthesis of bis(cyclopentadienyl)rhenium alkyls and the mixed metal complexes: (.eta.5-C5H5)2M(.mu.-CO)2Re(CO)(.eta.5-C5H5) (M = molybdenum, tungsten)
R. I. Mink, J. J. Welter, P. R. Young, and G. D. Stucky
pp 6928 - 6933; DOI:
10.1021/ja00517a023
PDF
A dimeric naphthyl hydride derivative of zirconocene. Synthesis, structure, and chemical properties
Guido P. Pez, Charles F. Putnik, Steven L. Suib, and Galen D. Stucky
pp 6933 - 6937; DOI:
10.1021/ja00517a024
PDF
Biphase and triphase catalysis. Arsonated polystyrenes as catalysts in the Baeyer-Villiger oxidation of ketones by aqueous hydrogen peroxide
Stephen E. Jacobson, Frank Mares, and Patrick M. Zambri
pp 6938 - 6946; DOI:
10.1021/ja00517a025
PDF
Biphase and triphase catalysis. Arsonated polystyrenes as catalysts for epoxidation of olefins by aqueous hydrogen peroxide
Stephen E. Jacobson, Frank Mares, and Patrick M. Zambri
pp 6946 - 6950; DOI:
10.1021/ja00517a026
PDF
Studies of the reactions of molecular fluorine with methane, acetylene, ethylene, allene, and other small hydrocarbons in matrices at low temperatures
R. H. Hauge, S. Gransden, J. L. F. Wang, and J. L. Margrave
pp 6950 - 6954; DOI:
10.1021/ja00517a027
PDF
Electron transfer from ascorbic acid to various phenothiazine radicals
E. Pelizzetti, D. Meisel, W. A. Mulac, and P. Neta
pp 6954 - 6959; DOI:
10.1021/ja00517a028
PDF
Activation parameters in the photocycloaddition of phenanthrene to dimethyl fumarate
R. A. Caldwell and D. Creed
pp 6960 - 6965; DOI:
10.1021/ja00517a029
PDF
Photoenolization of o-alkyl-substituted carbonyl compounds. Use of electron transfer processes to characterize transient intermediates
P. K. Das, M. V. Encinas, R. D. Small, and J. C. Scaiano
pp 6965 - 6970; DOI:
10.1021/ja00517a030
PDF
Enthalpies of acetolysis of tricyclo[3.2.1.01,5]octane ([3.2.1]propellane) and 1,3-dehydroadamantane
Kenneth B. Wiberg, Helen A. Connon, and William E. Pratt
pp 6970 - 6972; DOI:
10.1021/ja00517a031
PDF
Hydrolysis of strained bridgehead bicyclic vinyl ethers and sulfides
W. K. Chwang, A. J. Kresge, and J. R. Wiseman
pp 6972 - 6975; DOI:
10.1021/ja00517a032
PDF
Carboxylic acid participation in amide hydrolysis. Reactivity of intermediates in the internally catalyzed hydrolysis of N-substituted 2,3-dimethylmaleamic acids
Ronald Kluger, Jik Chin, and W. W. Choy
pp 6976 - 6980; DOI:
10.1021/ja00517a033
PDF
Structure and reactivity in intramolecular catalysis. Catalysis of sulfonamide hydrolysis by the neighboring carboxyl group
Teun Graafland, Anno Wagenaar, Anthony J. Kirby, and Jan B. F. N. Engberts
pp 6981 - 6991; DOI:
10.1021/ja00517a034
PDF
Topologically spherical molecules. An efficient synthesis of C16-hexaquinacene and its lack of neutral homoaromatic character
Leo A. Paquette, Robert A. Snow, Jean L. Muthard, and Tadeusz Cynkowski
pp 6991 - 6996; DOI:
10.1021/ja00517a035
PDF
Diels-Alder reactions of trans-1-methoxy-3-trimethylsilyloxy-1,3-butadiene
S. Danishefsky, T. Kitahara, C. F. Yan, and J. Morris
pp 6996 - 7000; DOI:
10.1021/ja00517a036
PDF
Derivatives of 1-methoxy-3-trimethylsilyloxy-1,3-butadiene for Diels-Alder reactions
Samuel Danishefsky, Cheng-Feng Yan, Rajendra K. Singh, Ronald B. Gammill, Patrick M. McCurry, Nancy Fritsch, and Jon Clardy
pp 7001 - 7008; DOI:
10.1021/ja00517a037
PDF
Use of .beta.-phenylsulfinyl-.alpha.,.beta.-unsaturated carbonyl dienophiles in Diels-Alder reactions
S. Danishefsky, T. Harayama, and R. K. Singh
pp 7008 - 7012; DOI:
10.1021/ja00517a038
PDF
Synthesis of disodium prephenate and disodium epiprephenate. Stereochemistry of prephenic acid and an observation on the base-catalyzed rearrangement of prephenic acid to p-hydroxyphenyllactic acid
Samuel Danishefsky, Masahiro Hirama, Nancy Fritsch, and Jon Clardy
pp 7013 - 7018; DOI:
10.1021/ja00517a039
PDF
A stereospecific synthesis of griseofulvin
Samuel Danishefsky and Frederick J. Walker
pp 7018 - 7020; DOI:
10.1021/ja00517a040
PDF
Total synthesis of dl-pentalenolactone
Samuel Danishefsky, Masahiro Hirama, Kerry Gombatz, Takashi Harayama, Ellen Berman, and Paul F. Schuda
pp 7020 - 7031; DOI:
10.1021/ja00517a041
PDF
Stereochemistry of the Robinson-Schoepf reaction. A stereospecific total synthesis of the ladybug defense alkaloids precoccinelline and coccinelline
Robert V. Stevens and Albert W. M. Lee
pp 7032 - 7035; DOI:
10.1021/ja00517a042
PDF
Reduction by a model of NAD(P)H. 25. A chiral model which induces high asymmetry
Atsuyoshi Ohno, Masahiko Ikeguchi, Takahide Kimura, and Shinzaburo Oka
pp 7036 - 7040; DOI:
10.1021/ja00517a043
PDF
Antitumor agents from the bohemic acid complex. 4. Structures of rudolphomycin, mimimycin, collinemycin, and alcindoromycin
Terrence W. Doyle, Donald E. Nettleton, Robert E. Grulich, David M. Balitz, David L. Johnson, and Albert L. Vulcano
pp 7041 - 7049; DOI:
10.1021/ja00517a044
PDF
Unfolding of ribonuclease A by guanidinium chloride. Protein internal motions studied by nuclear magnetic resonance spin-lattice relaxation in an off-resonance rotating frame
Thomas L. James and Samuel P. Sawan
pp 7050 - 7055; DOI:
10.1021/ja00517a045
PDF
Synthesis and properties of tetraphenylporphyrin molecules containing heteroatoms other than nitrogen. 5. High resolution nuclear magnetic resonance studies of inner and outer aromaticity
Abraham Ulman, Joost Manassen, Felix Frolow, and Dov Rabinovich
pp 7055 - 7059; DOI:
10.1021/ja00517a046
PDF
Reduced nicotinamide adenine dinucleotide (NADH) models. 14. Metal ion catalysis of the reduction of .alpha.,.beta.-unsaturated ketones by 1,4-dihydropyridines. A model of .DELTA.4-3-ketosteroid reductases
Ronald A. Gase and Upendra K. Pandit
pp 7059 - 7064; DOI:
10.1021/ja00517a047
PDF
Lithiation of cyclopropylcarbinols
G. W. Klumpp, M. Kool, M. Schakel, R. F. Schmitz, and C. Boutkan
pp 7065 - 7066; DOI:
10.1021/ja00517a048
PDF
Bis(borabenzene)iron. Nucleophilic and electrophilic substitution in borabenzene-iron complexes
Arthur J. Ashe, William Butler, and Harold F. Sandford
pp 7066 - 7067; DOI:
10.1021/ja00517a049
PDF
7-Phenoxy-3,4-benzotropone: chemistry and spectroscopy of an isobenzotropone
O. L. Chapman, S. C. Busman, and K. N. Trueblood
pp 7067 - 7069; DOI:
10.1021/ja00517a050
PDF
Investigation of the system carbon dioxide-bicarbonate(1-) ion in the presence of copper(II) bovine carbonic anhydrase B
I. Bertini, E. Borghi, and C. Luchinat
pp 7069 - 7071; DOI:
10.1021/ja00517a051
PDF
Conductive polymers consisting of partially oxidized, face-to-face linked metallomacrocycles
Karl F. Schoch, Bhagyashree R. Kundalkar, and Tobin J. Marks
pp 7071 - 7073; DOI:
10.1021/ja00517a052
PDF
1,3-Dipolar interactions in acyclic systems. NMR evidence for a strong conformational preference in 1,3-dibromo-2,2-dimethylpropane
C. Hackett Bushweller, Michael R. Whalon, Stephen H. Fleischman, Christopher D. Rithner, and John S. Sturges
pp 7073 - 7074; DOI:
10.1021/ja00517a053
PDF
Nuclear magnetic resonance studies of the effects of pressure on the heme environmental structure of hemoproteins
Isao Morishima, Satoshi Ogawa, and Hiroaki Yamada
pp 7074 - 7076; DOI:
10.1021/ja00517a054
PDF
Acyclic stereoselection. 5. Use of double stereodifferentiation to enhance 1,2 diastereoselection in aldol condensations of chiral aldehydes
Clayton H. Heathcock and Charles T. White
pp 7076 - 7077; DOI:
10.1021/ja00517a055
PDF
Acyclic stereoselection. 6. A reagent for achieving high 1,2-diastereoselection in the aldol conversion of chiral aldehydes into 3-hydroxy-2-methylcarboxylic acids
Clayton H. Heathcock, Michael C. Pirrung, Charles T. Buse, James P. Hagen, Steven D. Young, and John E. Sohn
pp 7077 - 7079; DOI:
10.1021/ja00517a056
PDF
The intermolecular .pi.-amphoteric character of p-tricyanovinyldimethylaniline
D. J. Sandman and A. F. Richter
pp 7079 - 7080; DOI:
10.1021/ja00517a057
PDF
Oxygenation of cobalt(II) carboranylporphyrinates: solid-state, nonaqueous, and aqueous solutions
Robert C. Haushalter and Ralph W. Rudolph
pp 7080 - 7082; DOI:
10.1021/ja00517a058
PDF
Hydroretinals and hydrorhodopsins
Maria Arnaboldi, Michael G. Motto, Kazuo Tsujimoto, Valeria Balogh-Nair, and Koji Nakanishi
pp 7082 - 7084; DOI:
10.1021/ja00517a059
PDF
An external point-charge model for wavelength regulation in visual pigments
Barry Honig, Uri Dinur, Koji Nakanishi, Valeria Balogh-Nair, Mary Ann Gawinowicz, Maria Arnaboldi, and Michael G. Motto
pp 7084 - 7086; DOI:
10.1021/ja00517a060
PDF
Through-space electrostatic effects in electronic spectra. Experimental evidence for the external point-charge model of visual pigments
Mordechai Sheves, Koji Nakanishi, and Barry Honig
pp 7086 - 7088; DOI:
10.1021/ja00517a061
PDF
Anti, longitudinal conformational isomerism in metacyclophanes
George R. Newkome and Toshio Kawato
pp 7088 - 7089; DOI:
10.1021/ja00517a062
PDF
Solid-state NMR spectroscopy. Distinction of diastereomers and determination of optical purity
Howard D. W. Hill, A. P. Zens, and John Jacobus
pp 7090 - 7091; DOI:
10.1021/ja00517a063
PDF
5-Alkylidenebicyclo[2.1.0]pentanes. On the question of a negative bond dissociation energy
Mark Rule, Michael G. Lazzara, and Jerome A. Berson
pp 7091 - 7092; DOI:
10.1021/ja00517a064
PDF
Stereoisomerization by bridgehead double inversion and olefinic torsion in 5-alkylidenebicyclo[2.1.0]pentanes
Michael G. Lazzara, James J. Harrison, Mark Rule, and Jerome A. Berson
pp 7092 - 7094; DOI:
10.1021/ja00517a065
PDF
Mechanisms of dimerization and rearrangement of a bicyclo[3.1.0]hex-1-ene
Richard F. Salinaro and Jerome A. Berson
pp 7094 - 7095; DOI:
10.1021/ja00517a066
PDF
Synthesis and x-ray characterization of the [M6N(.mu.-CO)9(CO)6]-(M = cobalt, rhodium) anions. A new class of metal carbonyl cluster compounds containing an interstitial nitrogen atom
Secondo Martinengo, Gianfranco Ciani, Angelo Sironi, Brian T. Heaton, and Joan Mason
pp 7095 - 7097; DOI:
10.1021/ja00517a067
PDF
Chemiluminescence of diphenoyl peroxide. Pulsed laser spectrophotometric detection of radical ion intermediates on the CIEEL path
Keith A. Horn and Gary B. Schuster
pp 7097 - 7099; DOI:
10.1021/ja00517a068
PDF
Formation of cyclic peroxides by oxygenation of thiophenol-diene mixtures
Athelstan L. J. Beckwith and Rudolf D. Wagner
pp 7099 - 7100; DOI:
10.1021/ja00517a069
PDF
Metal-to-metal triple bonds-to cluster or not to cluster? Structural characterization of octakis(tert-butoxy)tetrakis(.mu.-fluoro)-tetramolybdenum and octakis(tert-butoxy)tris(.mu.-fluoro)-(.mu.-dimethylamido)-tetramolybdenum
Malcolm H. Chisholm, John C. Huffman, and Raymond L. Kelly
pp 7100 - 7104; DOI:
10.1021/ja00517a070
PDF
Total synthesis of (.+-.)-maysine
A. I. Meyers, Daniel L. Comins, Dennis M. Roland, Rainer Henning, and Kimihiro Shimizu
pp 7104 - 7105; DOI:
10.1021/ja00517a071
PDF
Photoinduced reactions. 109. A weakly chemiluminescent dioxetanimine
Yoshikatsu Ito, Teruo Matsuura, and Hideo Kondo
pp 7105 - 7107; DOI:
10.1021/ja00517a072
PDF
Reductive cyclization of ethynyl ketones in the construction of a significant tricyclic intermediate for the synthesis of gibberellic acid
Gilbert Stork, Robert K. Boeckmann, Douglass F. Taber, W. Clark Still, and Janak Singh
pp 7107 - 7109; DOI:
10.1021/ja00517a073
PDF
An unusually simple construction of ring A of gibberellic acid
Gilbert Stork and Janak Singh
pp 7109 - 7110; DOI:
10.1021/ja00517a074
PDF
A simple, stereospecific synthesis of the skeleton of the lycorine alkaloids
Gilbert Stork and D. J. Morgans
pp 7110 - 7111; DOI:
10.1021/ja00517a075
PDF
Synthesis and characterization of the metamagnetic 1:1 1-D phase of the decamethylferrocenium 7,7,8,8-tetracyano-p-quinodimethanide: Fe[C5(CH3)5]2+.cntdot.(TCNQ)-.cntdot.
Joel S. Miller, Arthur H. Reis, E. Gebert, J. J. Ritsko, W. R. Salaneck, L. Kovnat, Thomas W. Cape, and Richard P. Van Duyne
pp 7111 - 7113; DOI:
10.1021/ja00517a076
PDF
Electrochemistry of cytochrome c. Comparison of the electron transfer at a surface-modified gold electrode with that to cytochrome oxidase
Mark J. Eddowes, H. Allen O. Hill, and K. Uosaki
pp 7113 - 7114; DOI:
10.1021/ja00517a077
PDF
Elaeocarpus alkaloids. Synthesis using nitrones
Joseph J. Tufariello and S. Asrof Ali
pp 7114 - 7116; DOI:
10.1021/ja00517a078
PDF
Strained ring systems. 18. Determination of the rearrangement pathways in the buffered acetolysis of bicyclo[2.2.0]hex-exo-2-yl tosylate with specific deuterium labeling and optical purity probes
Richard N. McDonald and Cesin A. Curi
pp 7116 - 7118; DOI:
10.1021/ja00517a079
PDF
Strained ring systems. 19. The nature of the carbonium-ion intermediates formed in the buffered acetolysis of bicyclo[2.1.1]hex-exo-5-yl and bicyclo[2.2.0]hex-exo-2-yl derivatives: a requirement for delocalized, nonclassical carbonium ions
Richard N. McDonald and Cesin A. Curi
pp 7118 - 7119; DOI:
10.1021/ja00517a080
PDF
Stereospecificity of creatine kinase. Crystal structure of 1-carboxymethyl-2-imino-3-phosphonoimidazolidine
G. N. Phillips, J. W. Thomas, T. M. Annesley, and F. A. Quiocho
pp 7120 - 7121; DOI:
10.1021/ja00517a081
PDF
Formation of 1-ethylxanthyl-2,7-diaminomitosene and 1,10-diethylxanthyl-2,7-diaminodecarbamoylmitosene in aqueous solution upon reduction-reoxidation of mitomycin C in the presence of potassium ethylxanthate
Ulfert Hornemann, Paul J. Keller, and John F. Kozlowski
pp 7121 - 7124; DOI:
10.1021/ja00517a082
PDF
Metal-alkyl bond dissociation energies in organocobalt compounds related to vitamin B12 coenzymes
Jack Halpern, Flora T. T. Ng, and Garry L. Rempel
pp 7124 - 7126; DOI:
10.1021/ja00517a083
PDF
Heat of formation of 1,1-dimethylsilaethylene by ion cyclotron resonance spectroscopy
William J. Pietro, Steven K. Pollack, and Warren J. Hehre
pp 7126 - 7127; DOI:
10.1021/ja00517a084
PDF
Coordination chemistry of copper(I) in the gas phase
R. C. Burnier, T. J. Carlin, W. D. Reents, R. B. Cody, R. K. Lengel, and B. S. Freiser
pp 7127 - 7129; DOI:
10.1021/ja00517a085
PDF
A regiospecific and highly stereoselective approach to the synthesis of linearly fused tricyclopentanoids. Intramolecular diyl trapping reactions
R. Daniel Little and George W. Muller
pp 7129 - 7130; DOI:
10.1021/ja00517a086
PDF
Total synthesis of (.+-.)-isocomene
Michael C. Pirrung
pp 7130 - 7131; DOI:
10.1021/ja00517a087
PDF
Total synthesis of erythromycins. 5. Total synthesis of erythronolide A
E. J. Corey, Paul B. Hopkins, Sunggak Kim, Sung-Eun Yoo, Krishnan P. Nambiar, and J. R. Falck
pp 7131 - 7134; DOI:
10.1021/ja00517a088
PDF
Preferential 1,4- vs. 1,6-hydrogen transfer in a 1,5 biradical. Photochemistry of .beta.-ethoxypropiophenone
Peter J. Wagner and Cynthia Chiu
pp 7134 - 7135; DOI:
10.1021/ja00517a089
PDF
Book Reviews

pp 7136 - 7140; DOI:
10.1021/ja00517a600
PDF

Issue 24


Complete thermodynamic analysis of the hydration of thirteen pyridines and pyridinium ions. The special case of 2,6-di-tert-butylpyridine
Edward M. Arnett and B. Chawla
pp 7141 - 7146; DOI:
10.1021/ja00518a001
PDF
Molecular orbital theory of the hydrogen bond. 22. 2-Monosubstituted pyridines as proton acceptors
Janet E. Del Bene
pp 7146 - 7151; DOI:
10.1021/ja00518a002
PDF
Proton affinities of ethylidenimine and vinylamine
M. R. Ellenberger, R. A. Eades, M. W. Thomsen, W. E. Farneth, and D. A. Dixon
pp 7151 - 7154; DOI:
10.1021/ja00518a003
PDF
Intramolecular ring-to-ring proton transfer in gaseous (.omega.-phenylalkyl)benzenium ions
Dietmar Kuck, Wolfgang Baether, and Hans Friedrich Gruetzmacher
pp 7154 - 7157; DOI:
10.1021/ja00518a004
PDF
Matrix photoionization of methyl halides. Ultraviolet spectra of the parent cations and infrared evidence for intramolecular hydrogen-bonded parent anions in solid argon
Lester Andrews, J. Houston Miller, and Eleanor S. Prochaska
pp 7158 - 7161; DOI:
10.1021/ja00518a005
PDF
The multiplicity of substituted acyclic carbenes and related molecules
James F. Harrison, Richard C. Liedtke, and Joel F. Liebman
pp 7162 - 7168; DOI:
10.1021/ja00518a006
PDF
From carbene and phosphine to ylide. A symmetry-breaking allowed pathway
Georges Trinquier and Jean Paul Malrieu
pp 7169 - 7172; DOI:
10.1021/ja00518a007
PDF
Isotope enrichment and stereochemistry of the products from the reaction of electronically excited iodine monochloride with cis- and trans-1,2-dibromoethylene
Saswati Datta, John I. Brauman, and Richard N. Zare
pp 7173 - 7176; DOI:
10.1021/ja00518a008
PDF
Conformational preferences and electronic structures of bis (.eta.2-ethene)nickel(0) and tris(.eta.2-ethene)nickel(0)
Russell M. Pitzer and Henry F. Schaefer
pp 7176 - 7183; DOI:
10.1021/ja00518a009
PDF
1,1-Dilithioethylene. A ground-state triplet olefin with nearly free rotation about the double bond
William D. Laidig and Henry F. Schaefer
pp 7184 - 7188; DOI:
10.1021/ja00518a010
PDF
Angular momentum in ion-molecule reactions
G. G. Meisels, G. M. L. Verboom, M. J. Weiss, and TaCheng Hsieh
pp 7189 - 7195; DOI:
10.1021/ja00518a011
PDF
Conformational relaxation as limitation of chemical models. Empirical force field calculations and carbon-13 NMR shielding effects for some cyclohexanes, bicyclo[2.2.1]heptanes, bicyclo[3.3.1]nonane, and 11.beta.-substituted estrenes
Hans Joerg Schneider, Wolfgang Gschwendtner, and Eckehard F. Weigand
pp 7195 - 7198; DOI:
10.1021/ja00518a012
PDF
Theoretical determination of molecular structure and conformation. 6. The Criegee intermediate. Evidence for a stabilization of its syn form by alkyl substituents
Dieter Cremer
pp 7199 - 7205; DOI:
10.1021/ja00518a013
PDF
A new empirical method to calculate average molecular polarizabilities
Kenneth J. Miller and John Savchik
pp 7206 - 7213; DOI:
10.1021/ja00518a014
PDF
Projection, size factors, and reaction dynamics of colloidal redox catalysts mediating light induced hydrogen evolution from water
J. Kiwi and M. Graetzel
pp 7214 - 7217; DOI:
10.1021/ja00518a015
PDF
The geometrical influence of solid-state ion-pair interactions of alkali metal ions with a binuclear iron acyl monoanion, [Fe2(CO)5(C(O)R)(.mu.2-PPh2)2]-(where R = Ph, Me). Structural analyses of the [Li(THF)3]+, [Na(THF)2]+, and [(Ph3P)2N]+ salts
Robert E. Ginsburg, Jeremy M. Berg, Richard K. Rothrock, James P. Collman, Keith O. Hodgson, and Lawrence F. Dahl
pp 7218 - 7231; DOI:
10.1021/ja00518a016
PDF
Cationic vinylidene complexes. Preparation and structural characterization of (.eta.5-cyclopentadienyl)(2-methyl-4,5-bis(diphenylphosphino)-2-penten-3-yl)iron (II). A base-induced interligand reaction in a vinylidene complex
Richard D. Adams, Alan Davison, and John P. Selegue
pp 7232 - 7238; DOI:
10.1021/ja00518a017
PDF
Synthesis of triiron carbonyl cluster complexes containing isomeric triply bridging acimidoyl or alkylidenimido group derived from the reduction of organic nitriles
Mark A. Andrews and Herbert D. Kaesz
pp 7238 - 7244; DOI:
10.1021/ja00518a018
PDF
Crystal and molecular structures of HFe3(CH3C:NH)(CO)9 and HFe3(N:CHCH3)(CO)9, isomeric cluster complexes derived from the reduction of acetonitrile
Mark A. Andrews, Gregory Van Buskirk, Carolyn B. Knobler, and Herbert D. Kaesz
pp 7245 - 7254; DOI:
10.1021/ja00518a019
PDF
Reversible hydrogenation and dehydrogenation of cluster bound acimidoyl and alkylidenimido groups. Synthesis of complexes containing triply bridging nitrene and nitrile ligands
Mark A. Andrews and Herbert D. Kaesz
pp 7255 - 7259; DOI:
10.1021/ja00518a020
PDF
Crystal and molecular structure of Fe3(N.tplbond.CCH2CH2CH3)(CO)9. Characterization of a cluster complex with triply bridging nitrile ligand
Mark A. Andrews, Carolyn B. Knobler, and Herbert D. Kaesz
pp 7260 - 7264; DOI:
10.1021/ja00518a021
PDF
Intramolecular comparison of the .pi.-donor capability of oxo and organoimido ligands. X-ray crystal structures of N-1-adamantylimidotrioxoosmium and bis(N-tert-butylimido)dioxoosmium
William A. Nugent, Richard L. Harlow, and Ronald J. McKinney
pp 7265 - 7268; DOI:
10.1021/ja00518a022
PDF
Chemical and spectroscopic characterization of cis-diammineplatinum .alpha.-pyridone blue in aqueous solution. Comparison with other platinum blues
Jacqueline K. Barton, Carl Caravana, and Stephen J. Lippard
pp 7269 - 7277; DOI:
10.1021/ja00518a023
PDF
Molecular, electronic, and crystal structure of naphthol[1,8-cd:4,5-c'd']bis[1,2,6]thiadiazine
Alfred Gieren, Viktor Lamm, Robert C. Haddon, and Martin L. Kaplan
pp 7277 - 7281; DOI:
10.1021/ja00518a024
PDF
Reactions of benzylidene pentacarbonyltungsten with alkenes
Charles P. Casey, Stanley W. Polichnowski, Alan J. Shusterman, and Carol R. Jones
pp 7282 - 7292; DOI:
10.1021/ja00518a025
PDF
Optically active trivalent phosphorus compounds. 2. Reactivity of alkylthio- and alkylselenophosphonium salts. The first stereospecific synthesis of a chiral phosphinite
Jan Omelanczuk and Marian Mikolajczyk
pp 7292 - 7295; DOI:
10.1021/ja00518a026
PDF
Stereoselectivity of metathesis of various acyclic olefins with chromium-, molybdenum-, and tungsten-based catalysts
M. Leconte and J. M. Basset
pp 7296 - 7302; DOI:
10.1021/ja00518a027
PDF
Allenes and acetylenes. 22. Mechanistic aspects of the allene-forming reductions (SN2' reaction) of chiral propargylic derivatives with hydride reagents
Alf Claesson and Lars-Inge Olsson
pp 7302 - 7311; DOI:
10.1021/ja00518a028
PDF
Ion-pair intermediates and extreme deuterium isotope effects in partially diastereospecific base-promoted elimination competing with base-catalyzed 1,3-proton transfer
Alf Thibblin and Per Ahlberg
pp 7311 - 7318; DOI:
10.1021/ja00518a029
PDF
Cation-anion combination reactions. 17. Reactivities of alkylthiolate ions in aqueous solution
Calvin D. Ritchie and Joseph Gandler
pp 7318 - 7323; DOI:
10.1021/ja00518a030
PDF
Hydrolysis of isomeric imidate esters
Michael Caswell and Gaston L. Schmir
pp 7323 - 7329; DOI:
10.1021/ja00518a031
PDF
Mechanism of the keto-enol tautomerism in radical cations and gas-phase closed-shell systems
Janet S. Splitter and Melvin Calvin
pp 7329 - 7332; DOI:
10.1021/ja00518a032
PDF
Photoinduced reactions. 110. Mechanism of indole-singlet oxygen reactions. Interception of zwitterionic intermediates and ene reaction
Isao Saito, Seiichi Matsugo, and Teruo Matsuura
pp 7332 - 7338; DOI:
10.1021/ja00518a033
PDF
Mechanistic study of anodic intramolecular coupling reactions
John B. Kerr, Thomas C. Jempty, and Larry Miller
pp 7338 - 7346; DOI:
10.1021/ja00518a034
PDF
Conformational effects in 2,3-cycloalkyl-2,3-diazabicyclic tetraalkylhydrazines
Stephen F. Nelsen, William C. Hollinsed, Loretta A. Grezzo, and William P. Parmelee
pp 7347 - 7352; DOI:
10.1021/ja00518a035
PDF
The effect of chain length distribution on elastomeric properties. 1. Comparisons between random and highly nonrandom networks
J. R. Falender, G. S. Y. Yeh, and J. E. Mark
pp 7353 - 7356; DOI:
10.1021/ja00518a036
PDF
Dependence of bond angles upon the steric effect. 1. XMX bond angles
Marvin Charton
pp 7356 - 7362; DOI:
10.1021/ja00518a037
PDF
Quenching of intramolecular exciplexes by pyridine and methylpyridines suggesting triple exciplex (D'DA)* formation
Michiya Itoh, Nobuo Takita, and Momoe Matsumoto
pp 7363 - 7367; DOI:
10.1021/ja00518a038
PDF
Hydrocarbon analogs of the type II photoeliminations of ketones. Photochemistry of 1-substituted 4-phenyl-4-pentenes
Joseph M. Hornback and Gary S. Proehl
pp 7367 - 7373; DOI:
10.1021/ja00518a039
PDF
Cyclobutene derivatives as isoprene equivalents in terpene synthesis. 3. Bicyclo[2.2.0]hexanes
Stephen R. Wilson, Lawrence R. Phillips, Yavuz Pelister, and John C. Huffman
pp 7373 - 7379; DOI:
10.1021/ja00518a040
PDF
General-base-catalyzed intramolecular aminolysis of thiol esters. Cyclization of S-n-propyl o-(2-imidazolyl)thiolbenzoate. Relationship of the uncatalyzed and base-catalyzed nucleophilic reactions
Thomas H. Fife and B. R. DeMark
pp 7379 - 7385; DOI:
10.1021/ja00518a041
PDF
Nucleophilic substitution reactions of trans-4-(para-substituted phenoxy)-3-buten-2-ones
Paul A. Lartey and Leo Fedor
pp 7385 - 7390; DOI:
10.1021/ja00518a042
PDF
Acid- and base-catalyzed dehydration of prostaglandin E2 to prostaglandin A2 and general-base-catalyzed isomerization of prostaglandin A2 to prostaglandin B2
S. K. Perera and L. R. Fedor
pp 7390 - 7393; DOI:
10.1021/ja00518a043
PDF
Oxygen binding to myoglobins and their cobalt analogs
Ming-Yu R. Wang, Brian M. Hoffman, Steven J. Shire, and Frank R. N. Gurd
pp 7394 - 7397; DOI:
10.1021/ja00518a044
PDF
A 360-MHz photo-CIDNP study of bovine pancreatic phospholipase A2. Observation of a pH-dependent conformational change
Eugene H. J. M. Jansen, Gustaaf J. M. Van Scharrenburg, Arend J. Slotboom, Gerard H. De Haas, and Robert Kaptein
pp 7397 - 7399; DOI:
10.1021/ja00518a045
PDF
Chemical synthesis of 5'-O-triphosphoryladenylyl-(2' .fwdarw. 5')-adenylyl-(2' .fwdarw. 5')-adenosine (2-5A)
Simon S. Jones and Colin B. Reese
pp 7399 - 7401; DOI:
10.1021/ja00518a046
PDF
Models for the reduced states of cytochrome P-450 and chloroperoxidase. Structures of a pentacoordinate high-spin iron(II) mercaptide mesoporphyrin derivative and its carbonyl adduct
Christine Caron, Andre Mitschler, Georges Riviere, Louis Ricard, Michel Schappacher, and Raymond Weiss
pp 7401 - 7402; DOI:
10.1021/ja00518a047
PDF
Models for NADH coenzymes. Evidence for an electron-transfer mechanism yielding a radical-cation intermediate in the N-benzyldihydronicotinamide-N-benzylnicotinamide salt transhydrogenation reaction
Paul Van Eikeren, Paul Kenney, and Ross Tokmakian
pp 7402 - 7406; DOI:
10.1021/ja00518a048
PDF
Models for NADH coenzymes. Reactions of 2-carboxyl-substituted pyridines with N-alkyl-1,4-dihydronicotinamides
Paul Van Eikeren, David L. Grier, and Jim Eliason
pp 7406 - 7409; DOI:
10.1021/ja00518a049
PDF
Direct observation of the monomeric metaphosphate anion
Donald J. Harvan, J. Ronald Hass, Kenneth L. Busch, Maurice M. Bursey, Fausto Ramirez, and Seymour Meyerson
pp 7409 - 7410; DOI:
10.1021/ja00518a050
PDF
Synthesis of (C6H5)2PCH2Si(CH3)2C5H4Li: a novel heterodifunctional system for the directed linkage of dissimilar transition metal fragments
Neil E. Schore
pp 7410 - 7412; DOI:
10.1021/ja00518a051
PDF
Reaction between chlorophosphoranes and benzyltri-n-butylammonium or trimethylsilyl azides. Direct observation of hexacoordinate intermediates in displacement reactions at pentacoordinate phosphorus
Aleksandra Skowronska, Marek Pakulski, and Jan Michalski
pp 7412 - 7413; DOI:
10.1021/ja00518a052
PDF
Hydroxylation of benzene with .alpha.-azohydroperoxide. A novel route for generation of hydroxyl radical and its reaction in anhydrous media
T. Tezuka and N. Narita
pp 7413 - 7415; DOI:
10.1021/ja00518a053
PDF
Multiple emissions from rhenium(I) complexes: intraligand and charge-transfer emission from substituted metal carbonyl cations
Susan M. Fredericks, John C. Luong, and Mark S. Wrighton
pp 7415 - 7417; DOI:
10.1021/ja00518a054
PDF
Homogeneous carbon monoxide hydrogenation on multiple sites: a dissociative pathway to oxygenates
John S. Bradley, G. B. Ansell, and E. W. Hill
pp 7417 - 7419; DOI:
10.1021/ja00518a055
PDF
Homogeneous carbon monoxide hydrogenation to methanol catalyzed by soluble ruthenium complexes
John S. Bradley
pp 7419 - 7421; DOI:
10.1021/ja00518a056
PDF
Exciplex isomerization of Dewar benzenes. Factors controlling diabatic and adiabatic reaction paths
Guilford Jones and Sheau-Hwa Chiang
pp 7421 - 7423; DOI:
10.1021/ja00518a057
PDF
Isodehydroabietenolide
E. E. Van Tamelen, E. G. Taylor, T. M. Leiden, and A. F. Kreft
pp 7423 - 7424; DOI:
10.1021/ja00518a058
PDF
Cyclic peroxides. 74. Organic photochemistry with 6.7-eV photons: ascaridole
R. Srinivasan, Karen H. Brown, Jose A. Ors, Lloyd S. White, and W. Adam
pp 7424 - 7425; DOI:
10.1021/ja00518a059
PDF
Crystal structure and dynamic behavior of Ir4(CO)10(diars). A new pathway for carbonyl scrambling in M4(CO)12 derivatives
John R. Shapley, Gordon F. Stuntz, Melvyn Rowen Churchill, and John P. Hutchinson
pp 7425 - 7428; DOI:
10.1021/ja00518a060
PDF
Rates of deprotonation and pKa values of transition metal carbonyl hydrides
Howard W. Walker, Charles T. Kresge, Peter C. Ford, and R. G. Pearson
pp 7428 - 7429; DOI:
10.1021/ja00518a061
PDF
Palladium catalyzed hydrolysis of tertiary amines with water
Shunichi Murahashi and Tomonari Watanabe
pp 7429 - 7430; DOI:
10.1021/ja00518a062
PDF
Retention of stereochemistry during multipositional isomerization of an olefin by diiron nonacarbonyl
James C. Barborak, James W. Herndon, and Jim-Wah Wong
pp 7430 - 7432; DOI:
10.1021/ja00518a063
PDF
Absolute configuration of homomevalonate and 3-hydroxy-3-ethylglutaryl- and 3-hydroxy-3-methylglutaryl CoA, produced by cell-free extracts of insect corpora allata; cautionary note on prediction of absolute stereochemistry based on liquid chromatographic elution order of diastereomeric derivatives
B. John Bergot, Frederick Charles Baker, Eun Lee, and David A. Schooley
pp 7432 - 7434; DOI:
10.1021/ja00518a064
PDF
Addition-elimination reactions of fluoroxytrifluoromethane with activated aromatics
Timothy B. Patrick, Gary L. Cantrell, and Chung-Ying Chang
pp 7434 - 7435; DOI:
10.1021/ja00518a065
PDF
Magnetic and micellar effects on photoreactions. Micellar cage and magnetic isotope effects on quantum yields. Correlation of carbon-13 enrichment parameters with quantum yield measurements
Nicholas J. Turro, Bernard Kraeutler, and David Richard Anderson
pp 7435 - 7437; DOI:
10.1021/ja00518a066
PDF
Additions and Corrections - Crystal and Molecular Structure of the Free Base Porphyrin, Mesoprophyrin IX Dimethyl Ester
Robert G. Little, and James A. Ibers
pp 7437 - 7437; DOI:
10.1021/ja00518a600
PDF
Additions and Corrections - Ion-Solvent Interaction. Effects of Added Polar Compounds on the Conductances of Several Alkali Metal Salts in 2-Butanone at 25°C
M. D. Jackson, and W. R. Gilkerson
pp 7437 - 7437; DOI:
10.1021/ja00518a601
PDF
Additions and Corrections - Specific Inclusion Catalysis by β-Cyclodextrin in the One-Step Preparation of Vitamin K1 or K2 Analogues
Iwao Tabushi, Kazuo Yamamura, Kahee Fujita, and Hiromu Kawakubo
pp 7437 - 7438; DOI:
10.1021/ja00518a602
PDF
Additions and Corrections - Tests of Psuedophase Model of Micellar Catalysis: Its Partial Failure
Clifford A. Bunton, Laurence S. Romsted, and Gianfranco Savelli
pp 7438 - 7438; DOI:
10.1021/ja00518a603
PDF
Additions and Corrections - Deuterium-Induced Differential Isotope Shift 13C NMR. I. Resonance Reassignments of Mono- and Disaccharides
Philip E. Pfeiffer, Kathleen M. Valentine, and Frederick W. Parrish
pp 7438 - 7438; DOI:
10.1021/ja00518a604
PDF
Additions and Corrections - On "Anomalous" Selectivities in Electrophilic Aromatic Substitutions
Cielo Santiago, K. N. Houk, and Charles L. Perrin
pp 7438 - 7438; DOI:
10.1021/ja00518a605
PDF
Additions and Corrections - Electrochemical Studies on a Series of Manganese(III) Complexes Containing Symmetrical Pentadentate Ligands
W. M. Coleman, R. R. Goehring, L. T. Taylor, J. G. Mason, and R. K. Boggess
pp 7438 - 7438; DOI:
10.1021/ja00518a606
PDF
Additions and Corrections - Sex Pheromone of the American Cockroach: Absolute Configuration of Periplanone-B
Michael A. Adams, Koji Nakanishi, W. Clark Still, Edward V. Arnold, Jon Clardy, and C. J. Persoons
pp 7438 - 7438; DOI:
10.1021/ja00518a607
PDF
Additions and Corrections - Rational Synthesis of Unidimensional Mixed Valence Solids. Structural, Spectral, and Electrical Studies of Charge Distribution and Transport in Partially Oxidized Nickel and Palladium Bisdephenylglyoximates
Martin Cowie, Alain Gleizes, Gregory W. Grynkewich, Davida Webster Kalina, Malcolm S. McClure, Raymond P. Scaringe, Robert C. Teitelbaum, Stanley L. Ruby, James A. Ibers, Carl R. Kannewurf, and Tobin J. Marks
pp 7438 - 7438; DOI:
10.1021/ja00518a608
PDF
Additions and Corrections - Rational Synthesis of Unidimensional Mixed Valence Solids. Structure Oxidation State-Charge Transport Relationships in Iodinated Nickel and Palladium Bisbenzoquinonedioximates.
Leo D. Brown, Davida Webster Kalina, Malcolm S. McClure, Steven Schultz, Stanley L. Ruby, James A. Ibers, Carl R. Kannewurf, and Tobin J. Marks
pp 7438 - 7439; DOI:
10.1021/ja00518a609
PDF
Additions and Corrections - Stereoelectronic Control in the Electrochemical and Mercury-Promoted Reductive Acetoxylation of αα'-Dibromobicycloalkanones
Albert J. Fry, and Geoffrey S. Ginsburg
pp 7439 - 7439; DOI:
10.1021/ja00518a610
PDF
Additions and Corrections - 4a-Hydroperoxyflavin N-Oxidation of Tertiary Amines
Sheldon Ball, and Thomas C. Bruice
pp 7439 - 7439; DOI:
10.1021/ja00518a611
PDF
Additions and Corrections - Sterically Induced, Spontaneous Dealkylation of Secondary Alkylcobalamins Due to Axial Base Coordination and Conformational Changes of the Corrin Ligand
John H. Grate, and G. N. Schrauzer
pp 7439 - 7439; DOI:
10.1021/ja00518a612
PDF
Additions and Corrections - Optical Rotatory Dispersion Studies. 127. Chirality Due to 13C Substitution. Synthesis and Chiroptical Properties of (1S)-2-Adamantanone-413C and (1S)-2-4-Adamamantanedione-413C
Y. Lawrence Sing, N. Numan, Hans Wynberg, and Carl Djerassi
pp 7439 - 7439; DOI:
10.1021/ja00518a613
PDF
Additions and Corrections - Structure and Dynamic Behavior of n-Propyllithium from 13C, Li, and 6Li NMR
Gideon Fraenkel, Alice M. Fraenkel, Michael J. Geckle, and Frank Schloss
pp 7439 - 7439; DOI:
10.1021/ja00518a614
PDF
Additions and Corrections - Evidence of Vibronic State "Selectivity" in the Photoracemization of Tris(1,10-phenanthroline)chromium(III) Ion in Solution
Roger Sasseville, and Cooper H. Langford
pp 7439 - 7439; DOI:
10.1021/ja00518a615
PDF
Book Reviews

pp 7440 - 7440; DOI:
10.1021/ja00518a616
PDF

Issue 25


Vibrational spectra of cubane and four of its deuterated derivatives
E. W. Della, E. F. McCoy, H. K. Patney, Gerald L. Jones, and Foil A. Miller
pp 7441 - 7457; DOI:
10.1021/ja00519a001
PDF
Proton, deuteron, and carbon-13 ENDOR studies of phenalenyl radicals in nematic and smectic mesophases of liquid crystals
B. Kirste, H. Kurreck, H. J. Fey, C. Hass, and G. Schloemp
pp 7457 - 7463; DOI:
10.1021/ja00519a002
PDF
Detailed studies of trigger wave initiation and detection
Kenneth Showalter, Richard M. Noyes, and Harold Turner
pp 7463 - 7469; DOI:
10.1021/ja00519a003
PDF
Nucleic acid-methylmercury(II) interactions and the proton NMR lifetimes of nucleobase exchangeable protons
Do-Lan Hoo and Bruce McConnell
pp 7470 - 7477; DOI:
10.1021/ja00519a004
PDF
Application of photoelectron spectroscopy to biologically active molecules and their constituent parts. 6. Opiate narcotics
L. Klasinc, B. Ruscic, A. Sabljic, and N. Trinajstic
pp 7477 - 7482; DOI:
10.1021/ja00519a005
PDF
Fluorine nuclear relaxation studies of p-trifluoromethylbenzenesulfonyl-.alpha.-chymotrypsin
J. T. Gerig, D. T. Loehr, K. F. S. Luk, and D. C. Roe
pp 7482 - 7487; DOI:
10.1021/ja00519a006
PDF
Insertion of tetrafluoroethylene into the iron-iron bond of (.mu.(SCH3)Fe(CO)3)2, its thermal rearrangement to a bridging carbene ligand, and the transformation of the carbene to a perfluoromethylcarbyne ligand. Structures of .mu.(SCH3)2.mu.(C2F4)Fe2(CO)6 and .mu.(SCH3)2.mu.(FCCF3)Fe2(CO)6 at - 162.degree.C
J. J. Bonnet, R. Mathieu, R. Poilblanc, and James A. Ibers
pp 7487 - 7496; DOI:
10.1021/ja00519a007
PDF
.eta.3-Cyclooctenyltris(trimethyl phosphite)iron(I). Bonding of the .eta.3-alkenyl group to 16-, 17-, and 18-electron ML3 systems
R. L. Harlow, R. J. McKinney, and S. D. Ittel
pp 7496 - 7504; DOI:
10.1021/ja00519a008
PDF
Coordination chemistry of 7,9-disubstituted 6-oxopurine metal compounds. 1. Copper(II) coordination at N(1). Molecular and crystal structure of (glycylglycinato)(7,9-dimethylhypoxanthine)copper(II) tetrahydrate
Luigi G. Marzilli, Kenneth Wilkowski, Chian C. Chiang, and Thomas J. Kistenmacher
pp 7504 - 7510; DOI:
10.1021/ja00519a009
PDF
Heterocyclic photochemistry. 1. Phototranspositions in hydroxypyrylium cations. Permutation pattern analysis and mechanistic studies
John A. Barltrop, John C. Barrett, Roger W. Carder, A. Colin Day, John R. Harding, William E. Long, and Christopher J. Samuel
pp 7510 - 7521; DOI:
10.1021/ja00519a010
PDF
Heterocyclic photochemistry. 2. 4-Pyrones. A mechanistic study
John A. Barltrop, A. Colin Day, and Christopher J. Samuel
pp 7521 - 7528; DOI:
10.1021/ja00519a011
PDF
Cis-trans photoisomerization in a tri-o-thymotide clathrate. Crystal structure of tri-o-thymotide clathrates of cis- and trans-stilbene
Rina Arad-Yellin, Simone Brunie, Bernard S. Green, Marcel Knossow, and Georges Tsoucaris
pp 7529 - 7537; DOI:
10.1021/ja00519a012
PDF
Cyclic peroxides. 89. Photooxygenation of 1,3,5-cycloheptatriene: isolation and characterization of endoperoxides
Waldemar Adam and Metin Balci
pp 7537 - 7541; DOI:
10.1021/ja00519a013
PDF
Cyclic peroxides. 90. Photooxygenation of 1,3,5-cycloheptatriene: transformations of endoperoxides
Waldemar Adam and Metin Balci
pp 7542 - 7547; DOI:
10.1021/ja00519a014
PDF
Mechanism of biaryl synthesis with nickel complexes
T. T. Tsou and J. K. Kochi
pp 7547 - 7560; DOI:
10.1021/ja00519a015
PDF
Radicals and carbanions as intermediates in the electrochemical reduction of 1-iododecane at mercury. Effect of potential, electrolysis time, and water concentration on the mechanism
Daniel M. La Perriere, William F. Carroll, Brian C. Willett, Eric C. Torp, and Denis G. Peters
pp 7561 - 7568; DOI:
10.1021/ja00519a016
PDF
Charge transfer and partial oxidation in the conductive hydrocarbon-iodine complex "2perylene.cntdot.3I2"
Robert C. Teitelbaum, Stanley L. Ruby, and Tobin J. Marks
pp 7568 - 7573; DOI:
10.1021/ja00519a017
PDF
Liquid-phase autoxidation of organic compounds at elevated temperatures. 1. The stirred flow reactor technique and analysis of primary products from n-hexadecane autoxidation at 120-180.degree.C
R. K. Jensen, S. Korcek, L. R. Mahoney, and M. Zinbo
pp 7574 - 7584; DOI:
10.1021/ja00519a018
PDF
Effect of the oxidation number of the sulfur atom on the thioxanthone radical anions studied by electronic absorption and ESR spectra
Tamotsu Aruga, Osamu Ito, and Minoru Matsuda
pp 7585 - 7589; DOI:
10.1021/ja00519a019
PDF
Kinetics of the anodic dimerization of 4,4'-dimethoxystilbene by the rotating ring-disk electrode
Gerd Burgbacher, Hans J. Schaefer, and D. C. Roe
pp 7590 - 7593; DOI:
10.1021/ja00519a020
PDF
Mechanisms of elimination reactions. 30. The contributions of tunneling and heavy-atom motion in the reaction coordinate to deuterium kinetic isotope effects in eliminations from 2-phenylethyl derivatives
Sheena B. Kaldor and William H. Saunders
pp 7594 - 7599; DOI:
10.1021/ja00519a021
PDF
Regiocontrolled hydrogenolysis of strained .sigma. bonds. Application to the synthesis of syn- and anti-tricyclo[4.2.1.12,5]decane and two elusive cyclopentadiene dimers
Leo A. Paquette, Christopher W. Doecke, and Gerhard Klein
pp 7599 - 7604; DOI:
10.1021/ja00519a022
PDF
An electrochemical investigation of the redox properties of bacteriochlorophyll and bacteriopheophytin in aprotic solvents
Therese M. Cotton and Richard P. Van Duyne
pp 7605 - 7612; DOI:
10.1021/ja00519a023
PDF
Reversed phase chromatographic resolution of amino acid enantiomers with metal-Aspartam eluants
C. Gilon, R. Leshem, Y. Tapuhi, and Eli Grushka
pp 7612 - 7613; DOI:
10.1021/ja00519a024
PDF
Preparation and characterization of an oxoporphinatochromium(V) complex
John T. Groves and William J. Kruper
pp 7613 - 7615; DOI:
10.1021/ja00519a025
PDF
Remarkable influence of terminal alkoxy groups on carbonyl ligands as seen in the new compounds Mo(OBut)2(CO)2(py)2 and Mo2(OPri)8(CO)2
Malcolm H. Chisholm, John C. Huffman, and Raymond L. Kelly
pp 7615 - 7617; DOI:
10.1021/ja00519a026
PDF
Independent existence in the gas phase of the 1-methoxycyclopropyl and 2-methoxyallyl cations, as observed in an ion cyclotron resonance spectrometer
M. W. E. M. Van Tilborg, R. Van Doorn, and N. M. M. Nibbering
pp 7617 - 7618; DOI:
10.1021/ja00519a027
PDF
Synthesis and structure of (.eta.-C5H5)W(PPh3)(CO)(CSPh): transformation of a thiocarbonyl ligand into a carbyne ligand
William W. Greaves, Robert J. Angelici, Barbara J. Helland, Rudolph Klima, and Robert A. Jacobson
pp 7618 - 7620; DOI:
10.1021/ja00519a028
PDF
Electronic control of stereoselectivity. 2. A stereochemical method for qualitatively assessing the relative electrophilicity of various electron-deficient species
Larry W. Hertel and Leo A. Paquette
pp 7620 - 7622; DOI:
10.1021/ja00519a029
PDF
Metal core binding energy and charge delocalization in [Os(NH3)4ClN2Cl(NH3)4Os]Cl3, a binuclear mixed-valence osmium complex: an ESCA study
M. S. Lazarus and T. K. Sham
pp 7622 - 7623; DOI:
10.1021/ja00519a030
PDF
Synthesis of a 4a,5-epoxy-5-deazaflavin derivative
Donald Vargo and Marilyn S. Jorns
pp 7623 - 7626; DOI:
10.1021/ja00519a031
PDF
Total synthesis of dl-helenalin
M. R. Roberts and R. H. Schlessinger
pp 7626 - 7627; DOI:
10.1021/ja00519a032
PDF
Total syntheses of dl-confertin and dl-damsin
G. J. Quallich and R. H. Schlessinger
pp 7627 - 7629; DOI:
10.1021/ja00519a033
PDF
Impregnated reagents. Characterization of sodium cyanide on alumina
Steven L. Regen, Silvio Quici, and Michael D. Ryan
pp 7629 - 7630; DOI:
10.1021/ja00519a034
PDF
Symmetrical triamino-per-O-methyl-.alpha.-cyclodextrin: preparation and characterization of primary trisubstituted .alpha.-cyclodextrins
Joshua Boger, Daniel G. Brenner, and Jeremy R. Knowles
pp 7630 - 7631; DOI:
10.1021/ja00519a035
PDF
Symmetrical triamino-per-O-methyl-.alpha.-cyclodextrin: a host for phosphate esters exploiting both hydrophobic and electrostatic interactions in aqueous solution
Joshua Boger and Jeremy R. Knowles
pp 7631 - 7633; DOI:
10.1021/ja00519a036
PDF
7.3% Efficient thin-film, polycrystalline n-gallium arsenide semiconductor liquid junction solar cell
A. Heller, Barry Irwin Miller, Shirley S. Chu, and Y. T. Lee
pp 7633 - 7634; DOI:
10.1021/ja00519a037
PDF
Tricyclo[4.3.1.13,8]undec-3-ene (homoadamant-3-ene). Stability of bridgehead olefins
David J. Martella, Maitland Jones, Paul v. R. Schleyer, and Wilhelm F. Maier
pp 7634 - 7637; DOI:
10.1021/ja00519a038
PDF
Adamantene
Robert T. Conlin, Robert D. Miller, and Josef Michl
pp 7637 - 7638; DOI:
10.1021/ja00519a039
PDF
Mechanism of the formation of dihydrogen from the photoinduced reactions of tris(bipyridine)ruthenium(II) with tris(bipyridine)rhodium(III)
Gilbert Morris Brown, S. F. Chan, Carol Creutz, Harold A. Schwarz, and Norman Sutin
pp 7638 - 7640; DOI:
10.1021/ja00519a040
PDF
Novel N-fluoroamines via the chlorofluorination of compounds with carbon-nitrogen triple bonds
Akira Sekiya and Darryl D. DesMarteau
pp 7640 - 7641; DOI:
10.1021/ja00519a041
PDF
Oxidation of μ-oxo-bridged iron porphyrin dimers
Martin A. Phillippi and Harold M. Goff
pp 7641 - 7643; DOI:
10.1021/ja00519a042
PDF
Kinetics of penetration of a probe molecule into a reversed micelle
K. Tamura and Z. A. Schelly
pp 7643 - 7644; DOI:
10.1021/ja00519a043
PDF

Issue 26


Reactions of metal-to-metal multiple bonds. 6. Reversible carbonylation of hexakis(tert-butoxy)dimolybdenum (M.tplbond.M). A carbonyl-bridged metal-to-metal double bond, Mo2(OBu-t)6(CO) (M:M)
Malcolm H. Chisholm, F. Albert Cotton, Michael W. Extine, and Raymond L. Kelly
pp 7645 - 7650; DOI:
10.1021/ja00520a001
PDF
Radius of gyration, asymmetry, and head-group orientation in unperturbed lecithins
Wayne L. Mattice
pp 7651 - 7654; DOI:
10.1021/ja00520a002
PDF
Chemical-structural properties of tetracycline derivatives. 7. Evidence for the coexistence of the zwitterionic and nonionized forms of the free base in solution
L. J. Hughes, John J. Stezowski, and R. E. Hughes
pp 7655 - 7657; DOI:
10.1021/ja00520a003
PDF
Chemical-structural properties of tetracycline derivatives. 8. The interrelationships between oxytetracycline and 4-epioxytetracycline
Roland Prewo and John J. Stezowski
pp 7657 - 7660; DOI:
10.1021/ja00520a004
PDF
Sterically hindered, saddle-shaped complexes of palladium(II) and platinum(II) and their reaction with iodine
Alan J. Jircitano, Mark D. Timken, Kristin Bowman Mertes, and John R. Ferraro
pp 7661 - 7667; DOI:
10.1021/ja00520a005
PDF
Novel organosilicon radical cations. One-electron oxidation of permethylcyclopolysilanes
H. Bock, W. Kaim, M. Kira, and R. West
pp 7667 - 7670; DOI:
10.1021/ja00520a006
PDF
Reactions of hexyl cations with benzene in hydrofluoric acid-tantalum pentafluoride. A. Mechanism study
D. Farcasiu, M. Siskin, and R. P. Rhodes
pp 7671 - 7674; DOI:
10.1021/ja00520a007
PDF
Formation of bicyclo[2.2.0]hexane derivatives by the ring contraction of bicyclo[3.2.0]heptanones
Kenneth B. Wiberg, Bryan L. Furtek, and Larry K. Olli
pp 7675 - 7679; DOI:
10.1021/ja00520a008
PDF
Stereochemistry of nucleophilic solvent participation in the decomposition of diacyl peroxides
Cheves Walling and John P. Sloan
pp 7679 - 7683; DOI:
10.1021/ja00520a009
PDF
Photolysis, thermal decomposition, and oxidation of naphtho[1,8-de]-1,2,3-thiadiazine. Efficient synthesis of naphtho[1,8-bc]thiete and the corresponding sulfoxide and sulfone
Juzo Nakayama, Teruyo Fukushima, Etsuro Seki, and Masamatsu Hoshino
pp 7684 - 7687; DOI:
10.1021/ja00520a010
PDF
Addition of complexed amino radicals to conjugated alkenes
Christopher J. Michejda and Dwane H. Campbell
pp 7687 - 7693; DOI:
10.1021/ja00520a011
PDF
Petroporphyrins. 1. Preliminary characterization of the porphyrins of gilsonite
J. Martin E. Quirke, Geoffrey Eglinton, and James R. Maxwell
pp 7693 - 7697; DOI:
10.1021/ja00520a012
PDF
Selective fluorine-proton nuclear Overhauser effects in 4-trifluoromethylbenzenesulfonyl-.alpha.-chymotrypsin
J. T. Gerig, K. F. S. Luk, and D. C. Roe
pp 7698 - 7704; DOI:
10.1021/ja00520a013
PDF
Crystal and molecular structures of 2,6-cis-dimethylpiperidyl-N-phenylacetamidine and 2,6-cis-dimethylpiperidyl-N-phenyl-2,2-dimethylpropionamidine. An x-ray crystallographic investigation of the C(sp2)-N(piperidyl) bond
Gastone Gilli and Valerio Bertolasi
pp 7704 - 7711; DOI:
10.1021/ja00520a014
PDF
Synthesis and absolute configuration assignments of enantiomeric forms of ifosphamide, sulfosphamide, and trofosphamide
K. Pankiewicz, R. Kinas, W. J. Stec, A. B. Foster, M. Jarman, and Jan M. S. Van Maanen
pp 7712 - 7718; DOI:
10.1021/ja00520a015
PDF
Resolution of triphosphamide
A. E. Wroblewski and J. G. Verkade
pp 7719 - 7720; DOI:
10.1021/ja00520a016
PDF
Electrochemistry in ordered systems. Oxidative electrochemistry of 10-methylphenothiazine in anionic, cationic, and nonionic micellar systems
Gregory L. McIntire and Henry N. Blount
pp 7720 - 7720; DOI:
10.1021/ja00520a017
PDF
Electrochemistry in ordered systems. 1. Oxidative electrochemistry of 10-methylphenothiazine in anionic, cationic, and nonionic micellar systems
Gregory L. McIntire and Henry N. Blount
pp 7720 - 7721; DOI:
10.1021/ja00520a018
PDF
Photoelectrochemical reduction of N,N'-dimethyl-4,4'-bipyridinium in aqueous media at p-type silicon: sustained photogeneration of a species capable of evolving hydrogen
Dana C. Bookbinder, Nathan S. Lewis, Mark G. Bradley, Andrew B. Bocarsly, and Mark S. Wrighton
pp 7721 - 7723; DOI:
10.1021/ja00520a019
PDF
Aldol addition = cycloaddition without cycloadduct formation 2
Johann Mulzer, Gisela Bruentrup, Juergen Finke, and Matthias Zippel
pp 7723 - 7725; DOI:
10.1021/ja00520a020
PDF
Isotopomer differentiation by means of inclusion
Samuel E. Ofodile, Richard M. Kellett, and Norman Obed Smith
pp 7725 - 7726; DOI:
10.1021/ja00520a021
PDF
Synthesis, characterization, and molecular structure of an aluminum pentamethylcyclopentadienyl complex, [.eta.3-(CH3)5C5Al(Cl)CH3]2: an organometallic analog of benzvalene
P. R. Schonberg, R. T. Paine, and C. F. Campana
pp 7726 - 7728; DOI:
10.1021/ja00520a022
PDF
Hydrogen-deuterium exchange: perdeuteriohydridotris(hexamethyldisilylamido)thorium(IV) and -uranium(IV)
Stephen J. Simpson, Howard W. Turner, and Richard Allan Andersen
pp 7728 - 7729; DOI:
10.1021/ja00520a023
PDF
Sitting-atop porphyrin complexes. The structure of the bischloromercury(II) complex of N-tosylaminooctaethylporphyrin
H. J. Callot, B. Chevrier, and R. Weiss
pp 7729 - 7730; DOI:
10.1021/ja00520a024
PDF
Nucleophilic biphenylyl transfer with the tetraphenylborate ion. A new amphophilic reagent
B. R. Reddy and J. S. McKennis
pp 7730 - 7732; DOI:
10.1021/ja00520a025
PDF
Transfer of CIDNP via proton exchange and nuclear Overhauser effect
Joachim Bargon and G. P. Gardini
pp 7732 - 7733; DOI:
10.1021/ja00520a026
PDF
Annelation of 1,2-cyclononadiene with tetrachlorothiophene dioxide. An ene reaction with sulfur dioxide
Maynard S. Raasch and Bruce E. Smart
pp 7733 - 7734; DOI:
10.1021/ja00520a027
PDF
Cadmium-113 NMR of metallothionein: direct evidence for the existence of polynuclear metal binding sites
James D. Otvos and Ian M. Armitage
pp 7734 - 7736; DOI:
10.1021/ja00520a028
PDF
Radicals of isobacteriochlorins: models of siroheme and sirohydrochlorin
P. F. Richardson, C. K. Chang, L. D. Spaulding, and J. Fajer
pp 7736 - 7738; DOI:
10.1021/ja00520a029
PDF
Iridium complexes in alkane dehydrogenation
Robert H. Crabtree, Jean M. Mihelcic, and Jennifer M. Quirk
pp 7738 - 7740; DOI:
10.1021/ja00520a030
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Laser photolysis study of the exciplex between triplet benzil and triethylamine
M. V. Encinas and J. C. Scaiano
pp 7740 - 7741; DOI:
10.1021/ja00520a031
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Hydrogen evolution from the photolysis of alcoholic benzophenone solutions via redox catalysis
Carole K. Graetzel and Michael Graetzel
pp 7741 - 7743; DOI:
10.1021/ja00520a032
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Trimethylsilyl shifts in cyclopropenes
Brian Coleman, Neal D. Conrad, Mary W. Baum, and Maitland Jones
pp 7743 - 7744; DOI:
10.1021/ja00520a033
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Reactions of superoxide in aprotic solvents. A superoxo complex of copper(II) rac-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane
Mario Nappa, Joan S. Valentine, Andrew Miksztal, Harvey J. Schugar, and Stephan S. Isied
pp 7744 - 7746; DOI:
10.1021/ja00520a034
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Chemical generation of excited-state radicals: succinimidoyl
Timothy Clark
pp 7746 - 7747; DOI:
10.1021/ja00520a035
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The carbenoid, CCl3Li, eschews tetrahedral structures
Timothy Clark and Paul von Rague Schleyer
pp 7747 - 7748; DOI:
10.1021/ja00520a036
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